石油学报 ›› 2005, Vol. 26 ›› Issue (1): 18-26.DOI: 10.7623/syxb200501004

• 地质勘探 • 上一篇    下一篇

鄂尔多斯盆地大气田的烷烃气碳同位素组成特征及其气源对比

戴金星1,2,3, 李剑4, 罗霞4, 张文正5, 胡国艺4, 马成华4, 郭建民5, 葛守国4   

  1. 1. 中国石油勘探开发研究院 北京 100083;
    2. 浙江大学地球科学系 浙江杭州 310027;
    3. 石油大学 资源与信息学院 北京 102200;
    4. 中国石油勘探开发研究院廊坊分院 河北廊坊 065007;
    5. 中国石油长庆油田分公司勘探开发研究院 陕西西安 710021
  • 收稿日期:2004-09-09 出版日期:2005-01-25 发布日期:2010-05-21
  • 作者简介:戴金星,男,1935年生,中国科学院院士,中国石油勘探开发研究院教授级高级工程师,主要从事天然气地质与地球化学研究.E-mail:djx@PetroChina.com.cn
  • 基金资助:
    国家重点基础研究发展规划项目(2001CB209103)"高效天然气藏形成分布规律与凝析、低效气藏经济开发的基础研究"部分成果.

Alkane carbon isotopic composition and gas source in giant gas fields of Ordos Basin

DAI Jin-xing1,2,3, LI Jian4, LUO Xia4, ZHANG Wen-zheng5, HU Guo-yi4, MA Cheng-hua4, GUO Jian-min5, GE Shou-guo4   

  1. 1. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China;
    2. Department of Earth Science, Zhejiang University, Hangzhou 310027, China;
    3. School of Resource and Information Technology, University of Petroleum, Beijing 102200, China;
    4. Langfang Branch Research Institute of Petroleum Exploration and Development, Langfang 065007, China;
    5. Research Institute of Exploration and Development, Changqing Oilfield Company, PetroChina, Xi'an 710021, China
  • Received:2004-09-09 Online:2005-01-25 Published:2010-05-21

摘要: 鄂尔多斯盆地是中国第二大沉积盆地,至2002年底已发现4个储量为1011m3以上的大气田.上古生界与煤系有关的烃源岩形成了苏里格、榆林、乌审旗3个位于碎屑岩中的煤成气大气田,在下古生界奥陶系马家沟组碳酸盐岩中发现了靖边气田(其气源仍存在争议).对4个大气田125个气样烷烃气碳同位素分析成果的研究表明,上古生界大气田烷烃气碳同位素组成较重,数值分布域小,表现了煤成气特征,其δ13CiC413CnC4,各个气田仅发现单项性碳同位素倒转.下古生界靖边气田δ13C1频率主峰值和δ13CB13CT与上古生界具有相似性,也表现出煤成气为主的特征.但靖边气田具有多项性碳同位素倒转,δ13C113C213C3数值分布域大,δ13C2较轻,表现出了以煤成气为主油型气为辅的混合气特征.煤成气和油型气的气源均来自上古生界的石炭-二叠系煤系和太原组含煤地层中有机碳丰度高的石灰岩,否定了有机碳含量约为0.20%的马家沟组碳酸盐岩是油型气烃源岩的结论.

关键词: 碳同位素, 烷烃气, 大气田, 气源对比, 鄂尔多斯盆地

Abstract: The Ordos Basin is the secondary biggest sedimentary basin of China. Four giant gas fields had been proven in the basin, including Sulige, Yulin, Wushenqi and Jingbian gas fields with proven reserves over 100 billion cubic meters for each gas field to the end of 2002. The hydrocarbon source rocks of the Sulige, Yulin and Wushenqi gas fields are coal measures of the Upper Paleozoic. The Jingbian gas field was found in the carbonates of Majiagou Formation in the Ordovician of the Lower Paleozoic. There are still existing arguments about the gas sources of Jingbian gas field. The alkane carbon isotopes analyses of 125 gas samples collected from the above-mentioned four gas fields show that the carbon isotopes of giant gas fields in the Upper Paleozoic are heavy, and the range of values is narrow. The gases are characterized by coal-formed gas. The δ13CiC4 value is bigger than the δ13CnC4 value. Reversal of carbon isotope values in single type appears in the Upper Paleozoic gas fields. In the Lower Paleozoic Jingbian gas field, the δ13C1 dominant peak values, the δ13CB values and the δ13CT values are similar to those in the Upper Paleozoic. However, there are still some different characteristics in Jingbian gas field from other three gas fields. The reversals of carbon isotope values are of multiple types. The values of δ13C113C2 and δ13C3 are ranged widely, and the δ13C2 value is smaller. These characteristics show that the gases are mixed from mainly humic and some sapropelic sources. It is suggested that the humic and sapropelic sources are all from C-P coal measures and the Taiyuan Formation carbonates with a high abundance of organic matter in the Upper Paleozoic rather than the conventional idea suggested that sapropelic gases are mainly from the Majiagou Formation carbonates with the total organic content of 0.20 %.

Key words: carbon isotopes, alkane hydrocarbon gas, giant gas field, gas source correlation, Ordos Basin

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