超低界面张力泡沫体系界面性能

doi:10.7623/syxb201106014

石油学报 ›› 2011, Vol. 32 ›› Issue (6): 1021-1025.DOI: 10.7623/syxb201106014

超低界面张力泡沫体系界面性能

刘宏生

大庆油田有限责任公司勘探开发研究院黑龙江大庆 163712

收稿日期:2011-05-09 修回日期:2011-08-21 出版日期:2011-11-25 发布日期:2012-01-17
通讯作者: 刘宏生
作者简介:刘宏生，男，1979年2月生，2006年获中国石油大学(北京)工学硕士学位，现为大庆油田有限责任公司勘探开发研究院工程师，主要从事泡沫复合驱机理方面的研究。
基金资助:
中国石油天然气股份有限公司科技攻关项目(06011421)资助。

Interface properties of the foam system with ultra-low interfacial tension

LIU Hongsheng

Received:2011-05-09 Revised:2011-08-21 Online:2011-11-25 Published:2012-01-17

摘要/Abstract

摘要：

利用悬挂滴法和鼓气法，研究了发泡剂体系的界面性能和泡沫性能，考察了发泡剂体系中发泡剂(DWS)和聚合物(HPAM)浓度对界面张力、表面扩张模量及泡沫性能的影响。实验结果表明：发泡剂体系中DWS质量分数为0.1%～0.4%，HPAM浓度低于1500 mg/kg 时，与大庆原油可以形成超低界面张力。当发泡剂体系中HPAM浓度较大时，界面张力呈现增大趋势。DWS表面扩张模量随浓度增加而增加，在较低浓度出现极大值，且极大值处表面扩张模量值较大。发泡剂体系中加入HPAM有利于提高DWS的表面扩张模量。发泡剂体系的起泡性和稳泡性随DWS浓度增加而增强。发泡剂体系中HPAM浓度增加，泡沫稳定性增强，但其起泡性降低。

关键词: 泡沫体系, 聚合物, 超低界面张力, 表面扩张模量, 起泡性, 泡沫稳定性

Abstract:

The present paper investigated interface and foam properties of a foaming agent system by hanging drop and air-blowing methods and examined the influence of foaming agent (DWS) and hydrolyzed polyacrylamide (HPAM) concentrations on interfacial tension, surface dilatational modulus and foam properties. The experiment result shows that ultra-low interfacial tension can be formed when the mass fraction of DWS is 0.1%~0.4% and HPAM with a concentration below 1500 mg/kg in a foaming agent system mixed together with Daqing crude oils. Interfacial tension tends to increase when the HPAM concentration in a foaming agent system is high. The surface dilatational modulus of DWS appears to increase with its concentration and reach to the maximum at a lower concentration of DWS. Adding HPAM in a foaming agent system is helpful in enhancing the surface dilatational modulus of DWS. The foamability and foam stability of a foaming agent system increase with the increase of DWS concentration, the increase of the HPAM concentration is helpful to the enhancement of foam stability but reduces foamability correspondingly.

Key words: foam system, polymer, ultra-low interfacial tension, surface dilatational modulus, foamability, foam stability

刘宏生. 超低界面张力泡沫体系界面性能[J]. 石油学报, 2011, 32(6): 1021-1025.

LIU Hongsheng. Interface properties of the foam system with ultra-low interfacial tension[J]. Editorial office of ACTA PETROLEI SINICA, 2011, 32(6): 1021-1025.

参考文献

[1]Bond D C,Holbrook I C.Gas drive oil recovery process[P].US Patent :2866507,1958.

[2]Harwsen J E,Dalland M.Foams for effective gas blockage in the presence of crude oil[R].SPE 20193,1990.

[3]Yang J,Jovancicev V,Ramachandran S.Foam for gas well deliquification[J].Colloids Surfaces A:Physicochem.Eng.Aspects，2007，309(1):177-181.

[4]Li R F,Yan W,Liu S,et al.Foam mobility control for surfactant EOR[R].SPE 113910,2008.

[5]Yu H,Yang B,Xu G,et al.Air foam injection for IOR:From laboratory to field implementation in Zhongyuan Oilfield China[R].SPE 113913,2008.

[6]袁新强,王克亮,陈金凤,等.复合热泡沫体系驱油效果研究[J].石油学报,2010,31(1):87-90.

Yuan Xinqiang,Wang Keliang,Chen Jinfeng,et al.Research on oil-displacement effect of composite hot foam system[J].Acta Petrolei Sinica,2010,31(1):87-90.

[7]刘合,叶鹏,刘岩,等.注氮气泡沫控制水窜技术在油田高含水期的应用[J].石油学报,2010,31(1):91-95.

Liu He,Ye Peng,Liu Yan,et al.Nitrogen foam injection technique and its application in reservoirs with high water cut[J].Acta Petrolei Sinica,2010,31(1):91-95.

[8]张小宁,李根生,黄中伟,等.泡沫钻井液在井筒中的流动与传热[J].石油学报,2010,31(1):133-138.

Zhang Xiaoning,Li Gensheng,Huang Zhongwei,et al.Well bore flow and heat transfer of foam drilling fluid[J].Acta Petrolei Sinica,2010,31(1):133-138.

[9]谈心,孙金声,徐显广,等.油基泡沫钻井流体技术研究[J].石油学报,2010,31(5):829-833.

Tan Xin,Sun Jinsheng,Xu Xianguang,et al.A study on the oil based foam drilling fluid technique[J].Acta Petrolei Sinica,2010,31(5):829-833.

[10]Fruhner H,Wantke K D,Lunkenheimer K.Relationship between surface dilational properties and foam stability[J].Colloids and Surfaces A,2000,162(1):193-202.

[11]Bhattacharyya A,Monroy F,Langevin D, et al.Surface rheology and foam stability of mixed surfactant-polyelectrolyte solutions[J].Langmuir,2000,16(23):8727-8732.

[12]Rusanov A I,Krotov V V,Nekrasov A G.Extremes of some foam properties and elasticity of thin foam films near the critical micelle concentration[J].Langmuir,2004,20(4):1511-1516.

[13]Stubenrauch C,Miller R.Stability of foam films and surface rheology:An oscillating bubble study at low frequencies[J].J.Phys.Chem.B,2004,108(20):6412-6421.

[14]Young H K,Kalman K,Wasan D T.Dynamic film and interfacial tensions in emulsion and foam systems[J].J.Colloid Interface Sci.,1997,187(1):29-44.

[15]Thodoris D K,Margaritis K.Investigation of the oscillating bubble technique for the determination of interfacial dilatational properties[J].Colloids and Surfaces.A,1999,156(1):49-64.

[16]Tommy H,Luben A.A novel fast technique for measuring dynamic surface and interfacial tension of surfactant solutions at constant interfacial area[J].J.Colloid Interface Sci.,1999,219(1):99-109.

[17]Cecilio C S,Juan M R P.Interfacial,foaming and emulsifying characteristics of sodium caseinate as influenced by protein concentration in solution[J].Food Hydrocolloids,2005,19(3):407-416.

[18]Lucassen J,Tempel M D.Longitudinal waves on visco-elastic surfaces[J].J.Colloid Interface Sci.,1972,41(3):491-498.

超低界面张力泡沫体系界面性能

Interface properties of the foam system with ultra-low interfacial tension

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	程杰成, 周泉, 周万富, 王庆国, 施伟光. 低初黏可控聚合物凝胶在油藏深部优势渗流通道的封堵方法及应用[J]. 石油学报, 2020, 41(8): 969-978.
[2]	刘静, 夏军勇, 刘玺, 吴飞鹏, 蒲春生. 低频波对泡沫稳定性协同强化效应[J]. 石油学报, 2020, 41(5): 584-591.
[3]	王成文, 王桓, 薛毓铖, 杨乐, 王瑞和, 靳建洲, 李勇. 高密度水泥浆高温沉降稳定调控热增黏聚合物研制与性能[J]. 石油学报, 2020, 41(11): 1416-1424.
[4]	暴丹, 邱正松, 叶链, 钟汉毅, 赵欣, 邱维清, 王宝田, 郭保雨. 热致形状记忆“智能”型堵漏剂的制备与特性实验[J]. 石油学报, 2020, 41(1): 106-115.
[5]	李杰训, 赵忠山, 李学军, 王梓栋, 李娜. 大庆油田聚合物驱配注工艺技术[J]. 石油学报, 2019, 40(9): 1104-1115.
[6]	彭志刚, 张健, 冯茜, 郑勇, 刘欢, 焦利宾. 环境响应型聚合物对水泥石抗CO₂腐蚀性能的影响[J]. 石油学报, 2018, 39(6): 703-711.
[7]	徐加放, 丁廷稷, 张瑞, 张振越, 顾甜甜, 程远方, 王志远. 水基钻井液低温流变性调控用温敏聚合物研制及性能评价[J]. 石油学报, 2018, 39(5): 597-603.
[8]	朱焱, 高文彬, 李瑞升, 李宜强, 袁靖舒, 孔德彬, 刘吉雨, 岳增存. 变流度聚合物驱提高采收率作用规律及应用效果[J]. 石油学报, 2018, 39(2): 189-200,246.
[9]	谭锋奇, 许长福, 王晓光, 陈玉琨, 程宏杰, 张记刚, 彭寿昌. 砾岩油藏水驱与聚合物驱微观渗流机理差异[J]. 石油学报, 2016, 37(11): 1414-1427.
[10]	邱正松, 毛惠, 谢彬强, 王在明, 邢韦亮, 沈忠厚, 汪胜武, 巨波. 抗高温钻井液增黏剂的研制及应用[J]. 石油学报, 2015, 36(1): 106-113.
[11]	杨菲, 郭拥军, 张新民, 罗平亚. 聚驱后缔合聚合物三元复合驱提高采收率技术[J]. 石油学报, 2014, 35(5): 908-913.
[12]	毛惠, 邱正松, 沈忠厚, 黄维安, 钟汉毅. 疏水缔合聚合物/纳米二氧化硅降滤失剂的研制及作用机理[J]. 石油学报, 2014, 35(4): 771-778.
[13]	乐建君, 刘芳, 张继元, 柏璐璐, 王蕊, 刘晓波, 侯兆伟, 伍晓林. 聚合物驱后油藏激活内源微生物驱油现场试验[J]. 石油学报, 2014, 35(1): 99-106.
[14]	王洪关, 何顺利, 冯爱丽, 程中疆, 白胤杰. 插层聚合物凝胶深部液流转向剂的研制与性能评价[J]. 石油学报, 2014, 35(1): 107-113.
[15]	李光辉, 张贵才, 葛际江, 周帅, 刘月亮. 阳离子微球与部分水解聚丙烯酰胺的絮凝作用[J]. 石油学报, 2013, 34(6): 1157-1162.