石油学报 ›› 1992, Vol. 13 ›› Issue (S1): 157-164.DOI: 10.7623/syxb1992S1019

• 论文 • 上一篇    下一篇

原油乳状液稳定性研究Ⅰ界面压与乳状液稳定性

李明远, 顾惕人   

  1. 卑尔根大学
  • 出版日期:1992-12-25 发布日期:2013-07-08

INVESTIGATION OF STABILITY OF WATER-IN-CRUDE OIL EMULSIONS Ⅰ.INTERFACIAL PRESSURE AND EMULSION STABILITY

Li Mingyuan, Ciu Tiren   

  1. Dep. of Chemistry, University of Bergen
  • Online:1992-12-25 Published:2013-07-08

摘要: 影响油包水型原油乳状液稳定性的最重要的因素是包在水滴周围的具有一定强度的界面膜的存在.从热力学角度看,加入表而活性剂会降低界面张力,而界面张力越低,乳状液就越稳定这可部分解释表面活性剂能稳定乳状液的原因但彭响乳状液稳定性的更重要的是动力学问题界而膜的强度是影响乳状液稳定性动力学的最重要的因素之一,而界血压则是与界面膜强度密切相关的重要参数通过理论分析和对以胶质、沥青质组分为表而活性剂乳化形成的乳化液稳定性与界面压的研究,证明界面压(而不是界面张力)是度量乳状液稳定性的一个重要参数L当表而活性剂类型一定时.可以用界面压的大小来衡量乳状液稳定性的高低.

关键词: 原油乳状液稳定性, 界面压, 界面膜强度

Abstract: The presence of interfacial film between water and oil phases is the most important factor to affect stability of water-in-crude oil emulsion.From thermodynamics the lower the interfacial tension of water-oil interface,the higher the stability of the emulsion is.Generally,however,the kinetics is uneven more important factor which affects the kinetics of coalesence between droplets.Interfacial pressure is an important parameter for the strength of the interfacial film.The theoretical analysis and investigation of the relation between interfacial pressure and the stability of the emulsions stabilized by the asphaltene and resin fractions show drat it is interfacial pressure Cnot interfacial tension) can be used for evaluating the stability of the emulsions,and for a certain kind of surfaccant,the larger the interfacial pressure,the more stable the emulsion is.