Research progress of surfactant enhanced oil recovery based on microfluidics technology

doi:10.7623/syxb202203010

Acta Petrolei Sinica ›› 2022, Vol. 43 ›› Issue (3): 432-442,452.DOI: 10.7623/syxb202203010

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Research progress of surfactant enhanced oil recovery based on microfluidics technology

Bao Bo¹, Shi Jiawei¹, Feng Jia¹, Yang Zaiyong², Peng Baoliang³, Zhao Shuangliang^1,2

1. School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
2. College of Chemistry and Chemical Engineering, Guangxi University, Guangxi Nanning 530004, China;
3. PetroChina Research Institute of Petroleum Exploration and Development, Beijing 100083, China

Received:2020-09-01 Revised:2021-10-10 Published:2022-04-06

基于微流控技术的表面活性剂强化驱油研究进展

鲍博¹, 史嘉威¹, 冯嘉¹, 杨再雍², 彭宝亮³, 赵双良^1,2

1. 华东理工大学化工学院上海 200237;
2. 广西大学化学化工学院广西南宁 530004;
3. 中国石油勘探开发研究院北京 100083

通讯作者: 彭宝亮,男,1985年1月生,2014年获华东理工大学博士学位,现为中国石油勘探开发研究院高级工程师,主要从事油气田化学及新材料研究工作。Email:pengbl@petrochina.com.cn;赵双良,男,1979年6月生,2007年获法国里昂高等师范学院博士学位,现为华东理工大学化工学院教授,主要从事微纳界面体系热力学、动力学与界面反应研究工作。Email:szhao@ecust.edu.cn
作者简介:鲍博,男,1986年8月生,2016年获加拿大多伦多大学博士学位,现为华东理工大学化工学院副教授,主要从事微纳流控驱油评价机制研究工作。Email:bbao@ecust.edu.cn
基金资助:
中国石油科技创新基金项目(2019D-5007-0208)和国家自然科学基金项目(No.21808056)资助。

Abstract

Abstract: It is of great scientific significance and engineering value to enable the innovation in EOR evaluation methods for old and unconventional oilfields. Microfluidic based reservoir-on-a-chip technology simply reproduces micro- and nano-pore structure to mimic reservoir porous media and provides direct visualization of multiphase flow, mass transport and phase behaviors of fluids within these confinements. Compared to conventional core flooding tests, microfluidic approaches demonstrate unique advantages of in situ visualization, availability in micro/nano confinement, low sample consumption and time efficacy. Surfactant injection has become one of commonly used chemical flooding approaches due to its excellent performance in mitigating interfacial tensions. In recent years, both academic and industrial community have witnessed a growing trend in research on evaluation of surfactant-based EOR using microfluidics. In this paper, we summarized the up-to-date research progress on microfluidics-based surfactant EOR evaluation, including the typical experimental apparatus, the mechanisms of emulsification and non-emulsification of oil-aqueous multiphase system in micropores and microchannels, and, specific case studies covering a variety of typical reservoirs. The paper aims to provide a systematic overview of microfluidic methods as an important option to investigate the rich physical and chemical mechanisms in surfactant based EOR process.

Key words: microfluidics, chip, surfactant, chemical enhanced oil recovery, emulsification, non-emulsification

摘要： 实现老油田和非常规油田提高采收率评价方法的创新有着重要的科学意义和工程价值。微流控技术可以复现油藏微米、纳米级孔隙结构,并且原位观测微米、纳米级孔隙结构中油藏流体和驱替相流体的流动和相变过程。与传统岩心驱替实验评价方法相比,微流控技术同时具有实时可视化、受限尺度小、样品消耗量少和测量时间短等优点,使之逐步成为研究和筛选驱替剂的有效评价技术方法。得益于优异的界面活性,表面活性剂已成为化学驱中备受关注的一种驱替物质。通过对基于微流控技术的表面活性剂驱油的最新实验研究进行调研,详细介绍了微流控技术研究表面活性剂强化驱油的系统组成,重点分析了表面活性剂乳化体系驱油机理和表面活性剂非乳化体系驱油机理。在表面活性剂乳化驱油体系中,针对不同油藏类型分析了表面活性剂的应用,包括微乳液体系的驱油机理和乳状液体系的驱油机理。在表面活性剂非乳化驱油体系中,详细分析了传统表面活性剂和生物表面活性剂以非乳化作用强化驱油的机理,并对微流控技术在油气田开发领域的应用进行了展望。

关键词: 微流控, 芯片, 表面活性剂, 化学强化驱油, 乳化驱油, 非乳化驱油

CLC Number:

TE357.46

Bao Bo, Shi Jiawei, Feng Jia, Yang Zaiyong, Peng Baoliang, Zhao Shuangliang. Research progress of surfactant enhanced oil recovery based on microfluidics technology[J]. Acta Petrolei Sinica, 2022, 43(3): 432-442,452.

鲍博, 史嘉威, 冯嘉, 杨再雍, 彭宝亮, 赵双良. 基于微流控技术的表面活性剂强化驱油研究进展[J]. 石油学报, 2022, 43(3): 432-442,452.

References

[1] VAN POOLLEN H K.Fundamentals of enhanced oil recovery[M].Tulsa:PennWell Books,1980.
[2] 康毅力,田键,罗平亚,等.致密油藏提高采收率技术瓶颈与发展策略[J].石油学报,2020,41(4):467-477.
KANG Yili,TIAN Jian,LUO Pingya,et al.Technical bottlenecks and development strategies of enhancing recovery for tight oil reservoirs[J].Acta Petrolei Sinica,2020,41(4):467-477.
[3] LU Jun,LIYANAGE P J,SOLAIRAJ S,et al.New surfactant developments for chemical enhanced oil recovery[J].Journal of Petroleum Science and Engineering,2014,120:94-101.
[4] HIRASAKI G J,MILLER C A,PUERTO M.Recent advances in surfactant EOR[J].SPE Journal,2011,16(4):889-907.
[5] ALZAHID Y A,MOSTAGHIMI P,WALSH S D C,et al.Flow regimes during surfactant flooding:the influence of phase behaviour[J].Fuel,2019,236:851-860.
[6] 李相方,冯东,张涛,等.毛细管力在非常规油气藏开发中的作用及应用[J].石油学报,2020,41(12):1719-1733.
LI Xiangfang,FENG Dong,ZHANG Tao,et al.The role and its application of capillary force in the development of unconventional oil and gas reservoirs and its application[J].Acta Petrolei Sinica,2020,41(12):1719-1733.
[7] 黄兴,窦亮彬,左雄娣,等.致密油藏裂缝动态渗吸排驱规律[J].石油学报,2021,42(7):924-935.
HUANG Xing,DOU Liangbin,ZUO Xiongdi,et al.Dynamic imbibition and drainage laws of factures in tight reservoirs[J].Acta Petrolei Sinica,2021,42(7):924-935.
[8] 王付勇,曾繁超,赵久玉.低渗透/致密油藏驱替-渗吸数学模型及其应用[J].石油学报,2020,41(11):1396-1405.
WANG Fuyong,ZENG Fanchao,ZHAO Jiuyu.A mathematical model of displacement and imbibition of low-permeability/tight reservoirs and its application[J].Acta Petrolei Sinica,2020,41(11):1396-1405.
[9] CHATENEVER A,CALHOUN JR J C.Visual examinations of fluid behavior in porous media-part I[J].Journal of Petroleum Technology,1952,4(6):149-156.
[10] 郭尚平,黄延章,周娟,等.物理化学渗流:微观机理[M].北京:科学出版社,1990.
GUO Shangping,HUANG Yanzhang,ZHOU Juan,et al.The microscopic mechanism of physical chemistry percolation[M].Beijing:Science Press,1990.
[11] MATTAX C C,KYTE J R.Ever see a water flood[J].Oil and Gas Journal,1961,59(115):115-128.
[12] CHILDRESS G.A microvisual study of initial displacement of residual hydrocarbons[D].Austin:University of Texas,1975.
[13] LENORMAND R,TOUBOUL E,ZARCONE C.Numerical models and experiments on immiscible displacements in porous media[J].Journal of Fluid Mechanics,1988,189:165-187.
[14] JAMALOEI B Y,KHARRAT R.Analysis of microscopic displacement mechanisms of dilute surfactant flooding in oil-wet and water-wet porous media[J].Transport in Porous Media,2010,81(1):1.
[15] BAO B,RIORDON J,XU Y,et al.Direct measurement of the fluid phase diagram[J].Analytical Chemistry,2016,88(14):6986-6989.
[16] 鲍博,赵双良,徐建鸿.基于微纳流控技术的流体相态特性研究进展[J].化工学报,2018,69(11):4530-4541.
BAO Bo,ZHAO Shuangliang,XU Jianhong.Progress in studying fluid phase behaviours with micro-and nano-fluidic technology[J].CIESC Journal,2018,69(11):4530-4541.
[17] BAO Bo,ZANDAVI S H,LI Huawei,et al.Bubble nucleation and growth in nanochannels[J].Physical Chemistry Chemical Physics, 2017,19(12):8223-8229.
[18] BAO Bo,RIORDON J,MOSTOWFI F,et al.Microfluidic and nanofluidic phase behaviour characterization for industrial CO₂,oil and gas[J]. Lab on a Chip,2017,17(16):2740-2759.
[19] BAO Bo,SANDERS A,REN G,et al.Rapid microfluidic analysis of thermal foam stability at 250 degrees Celsius[R].SPE 188895,2017.
[20] BAO Bo,ZHAO Shuangliang.A review of experimental nanofluidic studies on shale fluid phase and transport behaviors[J].Journal of Natural Gas Science and Engineering,2020,86:103745.
[21] 李俊键,苏航,姜汉桥,等.微流控模型在油气田开发中的应用[J].石油科学通报,2018,3(3):284-301.
LI Junjian,SU Hang,JIANG Hanqiao,et al.Application of microfluidic models in oil and gas field development[J].Petroleum Science Bulletin,2018,3(3):284-301.
[22] GAO Kexin,CUI Rubing,FAN Yiqiang,et al.Low-cost pyrophyllite-based microfluidic device for the study of enhanced oil recovery[J].Micro & Nano Letters,2019,14(13):1349-1354.
[23] QI Zhenbang,XU Lining,XU Yi,et al.Disposable silicon-glass microfluidic devices:precise,robust and cheap[J].Lab on a Chip,2018,18(24):3872-3880.
[24] WEGNER J,GANZER L.Rock-on-a-chip devices for high p,T conditions and wettability control for the screening of EOR chemicals[R].SPE 185820,2017:14.
[25] LEE H,LEE S G,DOYLE P S.Photopatterned oil-reservoir micromodels with tailored wetting properties[J].Lab on a Chip,2015,15(14):3047-3055.
[26] YUN W,CHANG S,COGSWELL D A,et al.Toward reservoir-on-a-chip:rapid performance evaluation of enhanced oil recovery surfactants for carbonate reservoirs using a calcite-coated micromodel[J].Scientific Reports,2020,10(1):782.
[27] ZHANG Y Q,SANATI-NEZHAD A,HEJAZI S H.Geo-material surface modification of microchips using layer-by-layer (LbL)assembly for subsurface energy and environmental applications[J].Lab on a Chip,2018,18(2):285-295.
[28] YU Fuwei,JIANG Hanqiao,XU Fei,et al.New insights into flow physics in the EOR process based on 2.5 D reservoir micromodels[J].Journal of Petroleum Science and Engineering,2019,181:106214.
[29] 史胜龙,汪庐山,靳彦欣,等.乳状液体系在驱油和调剖堵水中的应用进展[J].油田化学,2014,31(1):141-145.
SHI Shenglong,WANG Lushan,JIN Yanxin,et al.Application progress and developmental tendency of emulsion system used in flooding,profile control and water plugging[J].Oilfield Chemistry,2014,31(1):141-145.
[30] XU Ke,LIANG Tianbo,ZHU Peixi,et al.A 2.5-D glass micromodel for investigation of multi-phase flow in porous media[J].Lab on a Chip,2017,17(4):640-646.
[31] 郭华.微乳液驱油技术强化石油采收率的研究进展[J].山东化工,2016,45(9):63-65.
GUO Hua.Review of the microemulsion flooding to enhanced oil recovery[J].Shandong Chemical Industry,2016,45(9):63-65.
[32] PAL S,MUSHTAQ M,BANAT F,et al.Review of surfactant-assisted chemical enhanced oil recovery for carbonate reservoirs:challenges and future perspectives[J].Petroleum Science,2018,15(1):77-102.
[33] HOWE A M M,CLARKE A,MITCHELL J,et al.Visualising surfactant EOR in core plugs and micromodels[R].SPE 174643,2015.
[34] BROENS M,UNSAL E.Emulsification kinetics during quasi-miscible flow in dead-end pores[J].Advances in Water Resources,2018,113:13-22.
[35] UNSAL E,BROENS M,ARMSTRONG R T.Pore scale dynamics of microemulsion formation[J].Langmuir,2016,32(28):7096-7108.
[36] UNSAL E,BROENS M,BUIJSE M,et al.Visualization of in situ microemulsion phase[R].SPE 174651,2015.
[37] TAGAVIFAR M,XU Ke,JANG S H,et al.Spontaneous and flow-driven interfacial phase change:dynamics of microemulsion formation at the pore scale[J].Langmuir,2017,33(45):13077-13086.
[38] RUSCHAK K J,MILLER C A.Spontaneous emulsification in ternary systems with mass transfer[J].Journal of Industrial and Engineering Chemistry,1972,11(4):534-540.
[39] MILLER C A.Spontaneous emulsification produced by diffusion-a review[J]. Colloids and Surfaces,1988,29(1):89-102.
[40] 罗莉涛,廖广志,刘卫东,等.Marangoni对流启动残余油微观机理[J].石油学报,2015,36(9):1127-1134.
LUO Litao,LIAO Guangzhi,LIU Weidong,et al.Micromechanism of residual oil mobilization by Marangoni convection[J].Acta Petrolei Sinica,2015,36(9):1127-1134.
[41] 李爱芬.油层物理学[M].3版.东营:中国石油大学出版社,2011.
LI Aifen.Reservoir physics[M].3rd ed.Dongying:China University of Petroleum Press,2011.
[42] GUILLEN V R,CARVALHO M S,ALVARADO V.Pore scale and macroscopic displacement mechanisms in emulsion flooding[J].Transport in Porous Media,2012,94(1):197-206.
[43] KARAMBEIGI M S,ABBASSI R,ROAYAEI E,et al.Emulsion flooding for enhanced oil recovery:interactive optimization of phase behavior,microvisual and core-flood experiments[J].Journal of Industrial and Engineering Chemistry,2015,29:382-391.
[44] COBOS S,CARVALHO M S,ALVARADO V.Flow of oil-water emulsions through a constricted capillary[J].International Journal of Multiphase Flow,2009,35(6):507-515.
[45] MCAULIFFE C D.Crude-oil-water emulsions to improve fluid flow in an oil reservoir[J].Journal of Petroleum Technology,1973:25(6):721-726.
[46] MCAULIFFE C D.Oil-in-water emulsions and their flow properties in porous media[J].Journal of Petroleum Technology,1973,25(6):727-733.
[47] SOO R,RADKE C J.Flow mechanism of dilute,stable emulsions in porous media[J].Journal of Industrial and Engineering Chemistry,1984,23(3):342-347.
[48] 蒲春生,郑恒,杨兆平,等.水平井分段体积压裂复杂裂缝形成机制研究现状与发展趋势[J].石油学报,2020,41(12):1734-1743.
PU Chunsheng,ZHENG Heng,YANG Zhaoping,et al.Research status and development trend of the formation mechanism of complex fractures by staged volume fracturing in horizontal wells[J].Acta Petrolei Sinica,2020,41(12):1734-1743.
[49] REN G,ABEDINI A,YANG H,et al.Visualization of flowback aid mechanisms utilizing a microfluidic pore-scale device[R].SPE 199269,2020.
[50] 梁天博,马实英,魏东亚,等.低渗透油藏水锁机理与助排表面活性剂的优选原则[J].石油学报,2020,41(6):745-752.
LIANG Tianbo,MA Shiying,WEI Dongya,et al.Water blocking mechanism of low-permeability reservoirs and screening principle of flowback surfactants[J].Acta Petrolei Sinica,2020,41(6):745-752.
[51] LIANG Tianbo,XU Ke,LU Jun,et al.Evaluating the performance of surfactants in enhancing flowback and permeability after hydraulic fracturing through a microfluidic model[J].SPE Journal,2020,25(1):268-287.
[52] YU Fuwei,JIANG Hanqiao,FAN Zhen,et al.Formation and flow behaviors of in situ emulsions in heavy oil reservoirs[J].Energy & Fuels, 2019,33(7):5961-5970.
[53] ZHAO Benzhong,MACMINN C W,JUANES R.Wettability control on multiphase flow in patterned microfluidics[J].Proceedings of the National Academy of Sciences of the United States of America,2016,113(37):10251-10256.
[54] CIEPLAK M,ROBBINS M O.Influence of contact angle on quasistatic fluid invasion of porous media[J].Physical Review B,1990,41(16):11508.
[55] 王大威,刘永建,杨振宇,等.脂肽生物表面活性剂在微生物采油中的应用[J].石油学报,2008,29(1):111-115.
WANG Dawei,LIU Yongjian,YANG Zhenyu,et al.Application of surfactin in microbial enhanced oil recovery[J].Acta Petrolei Sinica,2008,29(1):111-115.
[56] SEO S,MASTIANI M,MOSAVATI B,et al.Performance evaluation of environmentally benign nonionic biosurfactant for enhanced oil recovery[J].Fuel,2018,234:48-55.
[57] NEGM N A,AHMED S A,BADR E A,et al.Synthesis and evaluation of nonionic surfactants derived from tannic acid as corrosion inhibitors for carbon steel in acidic medium[J].Journal of Surfactants and Detergents,2015,18(6):989-1001.
[58] AHMADI M A,ARABSAHEBI Y,SHADIZADEH S R,et al.Preliminary evaluation of mulberry leaf-derived surfactant on interfacial tension in an oil-aqueous system:EOR application[J].Fuel,2014,117:749-755.
[59] RAVI S G,SHADIZADEH S R,MOGHADDASI J.Core flooding tests to investigate the effects of IFT reduction and wettability alteration on oil recovery:using mulberry leaf extract[J].Petroleum Science and Technology,2015,33(3):257-264.
[60] MOSLEMIZADEH A,DEHKORDI A F,BARNAJI M J,et al.Novel bio-based surfactant for chemical enhanced oil recovery in montmorillonite rich reservoirs:adsorption behavior,interaction impact,and oil recovery studies[J].Chemical Engineering Research and Design,2016,109:18-31.

Research progress of surfactant enhanced oil recovery based on microfluidics technology

基于微流控技术的表面活性剂强化驱油研究进展

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[13]	HE Jiangchuan　LIAO Guangzhi　WANG Zhengmao. Oilfield development strategy and replacement techniques [J]. Editorial office of ACTA PETROLEI SINICA, 2012, 33(3): 519-525.
[14]	LIU Weidong SUN Chunliu SUN Linghui ZHU Weiyao. Surfactant partition of the ASP flooding system in oil/water phase [J]. Editorial office of ACTA PETROLEI SINICA, 2011, 32(6): 1017-1020.
[15]	ZHANG Liming ZHANG Kai LI Xiaofan Mojtaba Ghadiri Ali Hassanpour. Electrostatic movement characteristics of droplets in a highly electric field [J]. Editorial office of ACTA PETROLEI SINICA, 2011, 32(3): 524-528.