自生伊利石K-Ar、Ar-Ar测年技术对比与应用前景展望——以苏里格气田为例

doi:10.7623/syxb201403001

石油学报 ›› 2014, Vol. 35 ›› Issue (3): 407-416.DOI: 10.7623/syxb201403001

• 地质勘探 • 下一篇

自生伊利石K-Ar、Ar-Ar测年技术对比与应用前景展望——以苏里格气田为例

张有瑜^1,2,3, Horst Zwingmann⁴, 刘可禹^1,2,3,4, 罗修泉¹

1. 中国石油勘探开发研究院北京 100083;
2. 中国石油天然气集团公司盆地构造与油气成藏重点实验室北京 100083;
3. 提高石油采收率国家重点实验室北京 100083;
4. Earth Science and Resource Engineering, Commonwealth Scientific and Industrial Research Organization Bentley, Australia P.O.Box 1130

收稿日期:2013-12-07 修回日期:2014-03-12 出版日期:2014-05-25 发布日期:2014-04-11
通讯作者: 张有瑜，男，1955年8月生，1982年获中南大学学士学位，1988年获中国地质大学（北京）硕士学位，现为中国石油勘探开发研究院教授级高级工程师，主要从事油气储层自生伊利石K-Ar、Ar-Ar测年、He、Ar同位素质谱分析、常规K-Ar、Ar-Ar测年和含油气盆地黏土矿物研究。Email：ngms@petrochina.com.cn
作者简介:张有瑜，男，1955年8月生，1982年获中南大学学士学位，1988年获中国地质大学（北京）硕士学位，现为中国石油勘探开发研究院教授级高级工程师，主要从事油气储层自生伊利石K-Ar、Ar-Ar测年、He、Ar同位素质谱分析、常规K-Ar、Ar-Ar测年和含油气盆地黏土矿物研究。Email：ngms@petrochina.com.cn
基金资助:
中国石油天然气股份有限公司科技攻关项目“油气勘探新领域、新理论、新方法、新技术”（2011A-0207）资助。

Perspective on the K/Ar and Ar/Ar geochronology of authigenic illites：a case study from the Sulige gas field, Ordos Basin, China

Zhang Youyu^1,2,3, Horst Zwingmann⁴, Liu Keyu^1,2,3,4, Luo Xiuquan¹

1. PetroChina Research Institute of Petroleum Exploration and Development, Beijing 100083, China;
2. CNPC Key Laboratory of Basin Structure and Hydrocarbon Accumulation, Beijing 100083, China;
3. State Key Laboratory of Enhanced Oil Recovery, Beijing 100083, China;
4. Earth Science and Resource Engineering, Commonwealth Scientific and Industrial Research Organization, Bentley, P.O. Box 1130, Australia

Received:2013-12-07 Revised:2014-03-12 Online:2014-05-25 Published:2014-04-11

摘要/Abstract

摘要：

以苏里格气田为例，对自生伊利石K-Ar法、Ar-Ar法年龄测定的技术特点、应用效果和应用前景进行了系统对比和深入研究。苏里格气田自生伊利石（I/S有序间层）发育较好，主要呈丝状，具有典型的自生成因特征，其K-Ar年龄、未真空封装Ar-Ar总气体年龄和真空封装Ar-Ar总气体年龄分别为141~145 Ma、171~237 Ma和130~152 Ma。K-Ar年龄表明主要为晚侏罗世晚期―早白垩世早期成藏，其分布规律很好地反映了成藏特征和成藏过程；未真空封装Ar-Ar总气体年龄明显偏老，不能代表自生伊利石的形成年龄，更不能反映成藏时代，“³⁹Ar核反冲丢失”现象是导致其偏老的主要原因；真空封装Ar-Ar总气体年龄与K-Ar年龄基本接近，可能反映自生伊利石的形成年龄并代表成藏时代。本次对比研究表明，对于利用自生伊利石同位素测年技术探讨砂岩油气藏成藏时代，K-Ar法测年技术简便快捷、经济成熟、稳定可靠，是第一选择并具有较好的应用前景；未真空封装Ar-Ar法测年技术很难获得理想的年龄数据和较好的应用效果，如果没有其他特殊目的，可以不予考虑；真空封装Ar-Ar法测年技术，如果运用得当，有可能获得相对较好的年龄数据和相对较好的应用效果，但技术复杂、环节多、周期长和费用高等将会严重制约其发展和应用。

关键词: 苏里格气田, 下石盒子组八段砂岩储层, 自生伊利石, K-Ar测年, 未真空封装Ar-Ar测年, 真空封装Ar-Ar测年, ³⁹Ar核反冲丢失, 成藏年代

Abstract:

This paper makes a systematic comparison of and a deep study on the technical features, application prospective and effects of the K-Ar, vacuum-encapsulated Ar-Ar, and non-encapsulated Ar-Ar dating of authigenic illites from petroleum reservoirs by taking the Sulige gas field as an example. Authigenic illite, or the ordered mixed-layer illite/smectite (I/S) is well developed in reservoirs of the Sulige gas field. It is mainly presented in filamentous form, with typical authigenic origin. The corresponding K-Ar ages, vacuum-encapsulated Ar-Ar total gas ages, and non-encapsulated Ar-Ar total gas ages are 141-145 Ma, 130-152 Ma, and 171-237 Ma, respectively. The K-Ar ages indicate that the hydrocarbon accumulations mainly occurred during the period from the late phase of the Late Jurassic to the early phase of the Early Cretaceous, reflecting the accumulation features and processes by their distributions. The non-encapsulated Ar-Ar total gas ages are older due to ³⁹Ar recoil loss, and can't represent the forming ages of authigenic illites, or the accumulation times, both of which may be represented by the vacuum-encapsulated Ar-Ar total gas ages that are basically close to the K-Ar ages. The comparative results show that the K-Ar isotopic dating of authigenic illites is most applicable to exploring the hydrocarbon accumulation time in sandstone, with the advantages of easy-operation, low-cost, celerity and reliability, and better application prospect. The non-encapsulated Ar-Ar dating method will not be adopted unless for some special purposes, due to the difficulties in obtaining desirable age data and achieving good application prospect. The vacuum-encapsulated Ar-Ar dating method may yield reasonable age data if performed properly. However, the complex technical procedures, long analytical duration and high cost present a huge challenge for its development and routine application in studying petroleum reservoir chronology.

Key words: Sulige gas field, sandstone reservoirs of Member 8 of Xiashihezi Formation, authigenic illites, K-Ar dating, vacuum-encapsulated Ar-Ar dating, non-encapsulated Ar-Ar dating, ³⁹Ar recoil loss, accumulation time

中图分类号:

TE122.14

张有瑜, Horst Zwingmann, 刘可禹, 罗修泉. 自生伊利石K-Ar、Ar-Ar测年技术对比与应用前景展望——以苏里格气田为例[J]. 石油学报, 2014, 35(3): 407-416.

Zhang Youyu, Horst Zwingmann, Liu Keyu, Luo Xiuquan. Perspective on the K/Ar and Ar/Ar geochronology of authigenic illites：a case study from the Sulige gas field, Ordos Basin, China[J]. ACTA PETROLEI SINICA, 2014, 35(3): 407-416.

参考文献

[1] 李志昌,路远发,黄圭成.放射性同位素地质学方法与进展[M].武汉:中国地质大学出版社,2004:208-244.
Li Zhichang,Lu Yuanfa,Huang Guicheng.Methods and progresses in the radioactive isotope geology[M].Wuhan:Press of China University of Geosciences,2004:208-244.
[2] Lee M,Aronson J L,Savin S M.K/Ar dating of time of gas emplacement in Rotliegendes sandstone,Netherlands[J].AAPG Bulletin,1985,69(9):1381-1385.
[3] Hamilton P J,Giles M R,Ainsworth P.K-Ar dating of illites in Brent Group reservoirs:a regional perspective[C]//Morton A C,Haszeldine R S,Giles M R et al.Geology of the Brent Group.London:Geological Society of London,1992:377-400.
[4] Emery D,Robinson A.Inorganic geochemistry:application to petroleum geology[M].Oxford:Blackwell Scientific Publications,1993:101-119.
[5] Hamilton P J,Kelly S,Fallick A E.K-Ar dating of illite in hydrocarbon reservoirs[J].Clay Minerals,1989,24(2):215-231.
[6] Hamilton P J.A review of radiometric dating techniques for clay mineral cements in sandstones[M]//Richard H W,Sadoon M.Clay mineral cements in sandstones.Special Publication Number 34 of the International Association of Sedimentologists.Cornwell:Blackwell Publishing,2003:253-287.
[7] 张有瑜,董爱正,罗修泉.油气储层自生伊利石的分离提纯及其K-Ar同位素测年技术研究[J].现代地质,2001,15(3):315-320.
Zhang Youyu,Dong Aizheng,Luo Xiuquan.Separation of authigenic illite in hydrocarbon reservoirs and its K-Ar dating techniques[J].Geoscience,2001,15(3):315-320.
[8] 张有瑜,罗修泉,宋健.油气储层中自生伊利石K-Ar同位素年代学研究若干问题的初步探讨[J].现代地质,2002,16(4):403-407.
Zhang Youyu,Luo Xiuquan,Song Jian.Discussions on K-Ar isotopic geochronological studies of authigenic illites in hydrocarbon reservoirs[J].Geoscience,2002,16(4):403-407.
[9] Zhang Youyu,Zwingmann H,Liu Keyu,et al.Hydrocarbon charge history of the Silurian bituminous sandstone reservoirs in the Tazhong uplift,Tarim Basin,China[J].AAPG Bulletin, 2011,95(3):395-412.
[10] 张有瑜,罗修泉.油气储层自生伊利石分离提纯微孔滤膜真空抽滤装置与技术[J].石油实验地质,2011,33(6):671-676.
Zhang Youyu,Luo Xiuquan.A vacuum filtrating device and technique to separate authigenic illites from sandstone reservoirs with microporous membrane[J].Petroleum Geology and Experiment,2011,33(6):671-676.
[11] 张有瑜,罗修泉.塔里木盆地哈6井石炭-志留系砂岩自生伊利石K-Ar、Ar-Ar测年与成藏时代[J]. 石油学报,2012,33(5):748-757.
Zhang Youyu,Luo Xiuquan.K-Ar and Ar-Ar dating of authigenic illite and hydrocarbon accumulation history of Carboniferous-Silurian sandstone reservoirs in Well Ha 6,Tarim Basin[J].Acta Petrolei Sinica,2012,33(5):748-757.
[12] 黄道军,刘新社,张清,等.自生伊利石K-Ar测年技术在鄂尔多斯盆地油气成藏时期研究中的初步应用[J].低渗透油气田,2004,9(4):37-39.
Huang Daojun,Liu Xinshe,Zhang Qing,et al.Application of K-Ar dating technique to determination of timing of oil/gas entrapment in Ordos Basin[J].Low Permeability Oil & Gas Fields,2004,9(4):37-39.
[13] 张忠民,周瑾,邬兴威.东海盆地西湖凹陷中央背斜带油气运移期次及成藏[J].石油实验地质,2006,28(1):30-33.
Zhang Zhongmin,Zhou Jin,Wu Xingwei.Oil and gas migration periods and accumulation process in Central Anticlinal zone in the Xihu sag,the East China Sea Basin[J].Petroleum Geology and Experiment,2006,28(1):30-33.
[14] 刘四兵,沈忠民,吕正祥,等.川西坳陷中段须二段天然气成藏年代探讨[J].成都理工大学学报:自然科学版, 2009,36(5):523-530.
Liu Sibing,Shen Zhongmin,Lü Zhengxiang,et al.Research on the geochronology of forming the gas pools of Member 2 of Xujiahe Formation in the middle West Sichuan depression,China[J].Journal of Chengdu University of Technology:Science & Technology Edition,2009,36(5):523-530.
[15] McDougall I,Harrison T M.Geochronology and thermochronology by the ⁴⁰Ar/³⁹Ar method[M].2nd ed.New York,Oxford:Oxford University Press,1999:269.
[16] Renne P R,Sharp W D,Denio A L,et al.⁴⁰Ar/³⁹Ar dating into the historical realm:Calibration against Pliny the Younger[J].Science,1997,277(5330):1279-1280.
[17] Hess J C,Lippolt H J.Kinetics of Ar isotopes during neutron irradiation:³⁹Ar loss from minerals as a source of error in ⁴⁰Ar/³⁹Ar dating[J].Chemical Geology:Isotope Geoscience Section,1986,59(4):223-236.
[18] Clauer N,Zwingmann H,Liewig N,et al.Comparative ⁴⁰Ar/³⁹Ar and K/Ar dating of illite-type clay minerals:A tentative explanation for age identities and differences[J].Earth-Science Reviews,2012,115(1/2):76-96.
[19] 王龙樟,戴橦谟,彭平安.气藏储层自生伊利石⁴⁰Ar/³⁹Ar法定年的实验研究[J].科学通报,2004,49(增刊1):81-85.
Wang Longzhang,Dai Tongmo,Peng Ping'an.Experimental studies on ⁴⁰Ar/³⁹Ar dating of authigenic illites in gas reservoirs[J].Chinese Science Bulletin,2004,49(Supplement 1):81-85.
[20] 王龙樟,戴橦谟,彭平安.自生伊利石⁴⁰Ar/³⁹Ar法定年技术及气藏成藏期的确定[J].地球科学:中国地质大学学报,2005,30(1):78-82.
Wang Longzhang,Dai Tongmo,Peng Ping'an.⁴⁰Ar/³⁹Ar dating of diagenetic illites and its application in timing gas emplacement in gas reservoirs[J].Earth Science:Journal of China University of Geosciences,2005,30(1):78-82.
[21] 陈义才,王波,张胜,等.苏里格地区盒八段天然气充注成藏机理与成藏模式探讨[J].石油天然气学报:江汉石油学报,2010,32(4):7-11.
Chen Yicai,Wang Bo,Zhang Sheng,et al.The discussion of mechanism and pattern of hydrocarbon accumulation of gas-filling in Sulige region of the 8 Member of Xiashihezi Formation[J].Journal of Oil and Gas Technology:J.JPI,2010,32(4):7-11.
[22] 林良彪,蔺宏斌,侯明才,等.鄂尔多斯盆地苏里格气田上古生界天然气地球化学及成藏特征[J].沉积与特提斯地质,2009,29(2):77-82.
Lin Liangbiao,Lin Hongbin,Hou Mingcai,et al.Geochemistry and accumulation of the Upper Palaeozoic natural gas in the Sulige gas field,Ordos Basin[J].Sedimentary Geology and Tethyan Geology,2009,29(2):77-82.
[23] 刘新社,周立发,侯云东.运用流体包裹体研究鄂尔多斯盆地上古生界天然气成藏[J].石油学报,2007,28(6):37-42.
Liu Xinshe,Zhou Lifa,Hou Yundong.Study of gas charging in the Upper Paleozoic of Ordos Basin using fluid inclusion[J].Acta Petrolei Sinica,2007,28(6):37-42.
[24] 张文忠,郭彦如,汤达祯,等.苏里格气田上古生界储层流体包裹体特征及成藏期次划分[J].石油学报,2009,30(5):685-691.
Zhang Wenzhong,Guo Yanru,Tang Dazhen,et al.Characteristics of fluid inclusions and determination of gas accumulation period in the Upper Paleozoic reservoirs of Sulige Gas Field[J].Acta Petrolei Sinica,2009,30(5):685-691.
[25] 许怀先,李新景.K-Ar法年龄测定报告[R].北京:中国石油勘探开发研究院实验中心,2003.
Xu Huaixian,Li Xinjing.K-Ar dating report[R].Beijing:Laboratory Center,PetroChina Research Institute of Petroleum Exploration and Development,2003.
[26] Turner G,Cadogan P H.Possible effects of ³⁹Ar recoil in ⁴⁰Ar/³⁹Ar dating[J].Geochimica et Cosmochimica Acta,1974,38(Supplement 5):1601-1615.
[27] Foland K A,Hubacher F A,Arehart G B.⁴⁰Ar-³⁹Ar dating of very fine-grained samples:an encapsulated vial procedure to overcome the problem of ³⁹Ar recoil loss[J].Chemical Geology:Isotope Geoscience Section,1992,102(1/4):269-276.
[28] Onstott T C,Mueller P J,Vrolijk P J,et al.Laser ⁴⁰Ar/³⁹Ar microprobe analyses of fine-grained illite[J].Geochimica et Cosmochimica Acta,1997,61(18):3851-3861.
[29] Dong Hailiang,Hall C M,Peacor D R,et al.Mechanisms of argon retention in clays revealed by laser ⁴⁰Ar-³⁹Ar dating[J].Science,1995,267(5196):355-359.
[30] Yun Jianbing,Shi Hesheng,Zhu Junzhang,et al.Dating petroleum emplacement by illite ⁴⁰Ar-³⁹Ar laser stepwise heating[J].AAPG Bulletin,2010,94(6):759-771.
[31] Clauer N,Jourdan F,Zwingmann H.Dating petroleum emplacement by illite ⁴⁰Ar-³⁹Ar laser stepwise heating:discussion[J].AAPG Bulletin,2011,95(12):2107-2111.
[32] Kunk M J,Brusewitz A M.³⁹Ar recoil in an I/S clay from the Ordovician "big bentonite bed" at Kinnekulle,Sweden[J].Geological Society of America Bulletin,1987,19:230.
[33] 张彦,陈文,陈克龙,等.成岩混层(I/S)Ar-Ar年龄谱型及³⁹Ar核反冲丢失机理研究——以浙江长兴地区P-T界线粘土岩为例[J].地质论评,2006,52(4):556-561.
Zhang Yan,Chen Wen,Chen Kelong,et al.Study on the Ar-Ar age spectrum of diagenetic I/S and the mechanism of ³⁹Ar recoil loss:examples from the clay minerals of P-T boundary in Changxing,Zhejiang Province[J].Geological Review,2006,52(4):556-561.
[34] Renne P R,Knight K B,Nomade S,et al.Application of deuteron-deuteron (D-D)fusion neutrons to ⁴⁰Ar/³⁹Ar geochronology[J].Applied Radiation and Isotopes,2005,62(1):25-32.

自生伊利石K-Ar、Ar-Ar测年技术对比与应用前景展望——以苏里格气田为例

Perspective on the K/Ar and Ar/Ar geochronology of authigenic illites：a case study from the Sulige gas field, Ordos Basin, China

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