酯类化合物降低原油与二氧化碳体系最小混相压力实验

doi:10.7623/syxb201709008

石油学报 ›› 2017, Vol. 38 ›› Issue (9): 1066-1072.DOI: 10.7623/syxb201709008

酯类化合物降低原油与二氧化碳体系最小混相压力实验

赵跃军^1,2, 宋考平^1,2, 范广娟³, 皮彦夫^1,2, 刘丽¹

1. 东北石油大学石油工程学院黑龙江大庆 163318;
2. 东北石油大学提高油气采收率教育部重点实验室黑龙江大庆 163318;
3. 东北石油大学地球科学学院黑龙江大庆 163318

收稿日期:2016-10-18 修回日期:2017-06-02 出版日期:2017-09-25 发布日期:2017-10-09
通讯作者: 赵跃军,男,1980年9月生,2003年获大庆石油学院学士学位,2009年获大庆石油学院硕士学位,现为东北石油大学石油工程学院讲师,主要从事二氧化碳混相驱、降低二氧化碳混相驱最小混相压力、油藏数值模拟等提高原油采收率理论与技术的工作和研究。Email:fancyzyj@163.com
作者简介:赵跃军,男,1980年9月生,2003年获大庆石油学院学士学位,2009年获大庆石油学院硕士学位,现为东北石油大学石油工程学院讲师,主要从事二氧化碳混相驱、降低二氧化碳混相驱最小混相压力、油藏数值模拟等提高原油采收率理论与技术的工作和研究。Email:fancyzyj@163.com
基金资助:
国家重大科技专项（2011ZX05009，2011ZX05052）和国家自然科学基金项目（No.51404070）资助。

The experiment for reducing the minimum miscible pressure of crude oil and carbon dioxide system with ester compounds

Zhao Yuejun^1,2, Song Kaoping^1,2, Fan Guangjuan³, Pi Yanfu^1,2, Liu Li¹

1. College of Petroleum Engineering, Northeast Petroleum University, Heilongjiang Daqing 163318, China;
2. Key Laboratory for Enhanced Oil and Gas Recovery of the Ministry of Education, Northeast Petroleum University, Heilongjiang Daqing 163318, China;
3. College of Geosciences, Northeast Petroleum University, Heilongjiang Daqing 163318, China

Received:2016-10-18 Revised:2017-06-02 Online:2017-09-25 Published:2017-10-09

摘要/Abstract

摘要：

针对试验区近井地带达到混相驱、远井地带尚未达到混相驱的问题，通过注入油溶性表面活性剂（柠檬酸异丁酯或柠檬酸异戊酯）来降低原油与二氧化碳体系的最小混相压力，该表面活性剂既能够溶于原油中降低原油黏度，又能够溶解在超临界二氧化碳中降低原油与二氧化碳之间的界面张力，从而降低原油与二氧化碳之间的最小混相压力。采用长细管驱替实验的方法，测定了2种油溶性表面活性剂对试验区原油与二氧化碳体系的最小混相压力的影响。实验表明，注入的油溶性表面活性剂能够明显降低试验区原油与二氧化碳体系的最小混相压力，2种表面活性剂降低的最小混相压力值分别为7.2 MPa和6.6 MPa，并且随着表面活性剂注入段塞的增大，测得的原油与二氧化碳体系的最小混相压力逐渐降低，但是降低幅度越来越小，结合表面活性剂制备价格，得到最经济的表面活性剂注入段塞量为0.003 PV，并建议选择柠檬酸异丁酯作为试验区降低最小混相压力的化学试剂。

关键词: 最小混相压力, 超临界二氧化碳, 混相驱, 长细管驱替实验, 提高原油采收率

Abstract:

In the test area, miscible flooding was achieved in the near-wellbore area rather than the far-wellbore area. Aiming at this problem, the oil soluble surfactant (citric acid isobutyl ester or citric acid isopentyl ester) was injected to reduce the minimum miscible pressure of crude oil and carbon dioxide system. This surfactant can not only dissolve in crude oil to reduce the viscosity of crude oil, but also dissolve in supercritical carbon dioxide to reduce the interfacial tension between crude oil and carbon dioxide, thereby reducing the minimum miscible pressure between crude oil and carbon dioxide. The long-slim-tube displacement experiment method was used to measure the influence of two different oil soluble surfactants on the minimum miscible pressure (MMP) of crude oil and carbon dioxide system in the test area. The results showed that the injected oil soluble surfactant was able to obviously reduce the minimum miscible pressure of crude oil and carbon dioxide system, and the MMP reduced by two oil soluble surfactants were 7.2 MPa and 6.6 MPa respectively. Moreover, the measured MMP was reduced gradually with constantly increasing the injected slug of surfactant, but the reduction range became smaller and smaller. The most economical injected slug of surfactant was 0.003 PV by evaluating the cost for surfactant preparation. It was suggested that the citric acid isobutyl ester should be chosen as the chemical reagent to reduce the MMP in the test area.

Key words: minimum miscible pressure, supercritical carbon dioxide, miscible flooding, long-slim-tube displacement experiment, enhanced oil recovery

中图分类号:

TE357.45

赵跃军, 宋考平, 范广娟, 皮彦夫, 刘丽. 酯类化合物降低原油与二氧化碳体系最小混相压力实验[J]. 石油学报, 2017, 38(9): 1066-1072.

Zhao Yuejun, Song Kaoping, Fan Guangjuan, Pi Yanfu, Liu Li. The experiment for reducing the minimum miscible pressure of crude oil and carbon dioxide system with ester compounds[J]. Acta Petrolei Sinica, 2017, 38(9): 1066-1072.

参考文献

[1] 李士伦,张正卿,冉新权,等.注气提高石油采收率技术[M].成都:四川科学技术出版社,2001.
LI Shilun,ZHANG Zhengqing,RAN Xinquan,et al.The enhanced oil recovery technology by injecting gas[M].Chengdu:Sichuan Science and Technology Press,2001.
[2] STALKUP F I.Carbon dioxide miscible flooding:past,present,and outlook for the future[J].Journal of Petroleum Technology,1978,30(8):1102-1112.
[3] MUNGAN N.Carbon dioxide flooding-fundamentals[J].Journal of Canadian Petroleum Technology,1981,20(1):87-92.
[4] WHORTON L P,BROWNSCOMBE E R,DYES A B.Method for producing oil by means of carbon dioxide:U.S.Patent 2623596[P].1952-12-30.
[5] 秦积舜,韩海水,刘晓蕾.美国CO₂驱油技术应用及启示[J].石油勘探与开发,2015,42(2):209-216.
QIN Jishun,HAN Haishui,LIU Xiaolei.Application and enlightenment of carbon dioxide flooding in the United States of America[J].Petroleum Exploration and Development,2015,42(2):209-216.
[6] 易俊,李凤.二氧化碳驱油安全性研究现状及发展趋势[J].工业安全与环保,2014,40(11):41-43.
YI Jun,LI Feng.Security research status and development trend of carbon dioxide flooding[J].Industrial Safety and Environmental Protection,2014,40(11):41-43.
[7] 李士伦,周守信,杜建芬,等.国内外注气提高石油采收率技术回顾与展望[J].油气地质与采收率,2002,9(2):1-5.
LI Shilun,ZHOU Shouxin,DU Jianfen,et al.Review and prospects for the development of EOR by gas injection at home and abroad[J].Petroleum Geology and Recovery Efficiency,2002,9(2):1-5.
[8] 郝敏,宋永臣.利用CO₂提高石油采收率技术研究现状[J].钻采工艺,2010,33(4):59-63.
HAO Min,SONG Yongchen.Research status of CO₂-EOR[J].Drilling & Production Technology,2010,33(4):59-63.
[9] 韩海水,李实,陈兴隆,等.CO₂对原油烃组分膨胀效应的主控因素[J].石油学报,2016,37(3):392-398.
HAN Haishui,LI Shi,CHEN Xinglong,et al.Main control factors of carbon dioxide on swelling effect of crude hydrocarbon components[J].Acta Petrolei Sinica,2016,37(3):392-398.
[10] 沈平平,廖新维.二氧化碳地质埋存与提高石油采收率技术[M].北京:石油工业出版社,2009.
SHEN Pingping,LIAO Xinwei.The technology of carbon dioxide stored in geological media and enhanced oil recovery[M].Beijing:Petroleum Industry Press,2009.
[11] 周海菲.特低渗透油藏CO₂混相驱实验研究[D].大庆:大庆石油学院,2008.
ZHOU Haifei.Experimental investigation on CO₂ miscible drive in ultra-low permeability reservoirs[D].Daqing:Daqing Petroleum Institute,2008.
[12] 李宾飞,叶金桥,李兆敏,等.高温高压条件下CO₂-原油-水体系相间作用及其对界面张力的影响[J].石油学报,2016,37(10):1265-1272.
LI Binfei,YE Jinqiao,LI Zhaomin,et al.Phase interaction of CO₂-oil-water system and its effect on interfacial tension at high temperature and high pressure[J]. Acta Petrolei Sinica,2016,37(10):1265-1272.
[13] 孙忠新.CO₂驱油效果影响因素研究[D].大庆:大庆石油学院,2009.
SUN Zhongxin.Study on influential factors of displacement efficiency of CO₂ flooding[D].Daqing:Daqing Petroleum Institute,2009.
[14] 郝永卯,陈月明,于会利.CO₂驱最小混相压力的测定与预测[J].油气地质与采收率,2005,12(6):64-66.
HAO Yongmao,CHEN Yueming,YU Huili.Determination and prediction of minimum miscibility pressure in CO₂ flooding[J].Petroleum Geology and Recovery Efficiency,2005,12(6):64-66.
[15] 毛振强,陈凤莲.CO₂混相驱最小混相压力确定方法研究[J].成都理工大学学报:自然科学版,2005,32(1):61-64.
MAO Zhenqiang,CHEN Fenglian.Determination of minimum miscible phase pressure for CO₂ miscible drive[J].Journal of Chengdu University of Technology:Science & Technology Edition,2005,32(1):61-64.
[16] 张广东,李祖友,刘建仪,等.注烃混相驱最小混相压力确定方法研究[J].钻采工艺,2008,31(3):99-102.
ZHANG Guangdong,LI Zuyou,LIU Jianyi,et al.Study on determine methods of minimum miscibility pressure of hydrocarbon injection miscible flooding[J].Drilling & Production Technology,2008,31(3):99-102.
[17] 杨正明,刘学伟,张仲宏,等.致密油藏分段压裂水平井注二氧化碳吞吐物理模拟[J].石油学报,2015,36(6):724-729.
YANG Zhengming,LIU Xuewei,ZHANG Zhonghong,et al.Physical simulation of staged-fracturing horizontal wells using CO₂ huff and puff in tight oil reservoirs[J].Acta Petrolei Sinica,2015,36(6):724-729.
[18] 赵明国,周海菲,王谦.原油与CO₂驱最小混相压力预测方法研究[J].西部探矿工程,2007,19(12):60-62.
ZHAO Mingguo,ZHOU Haifei,WANG Qian.The prediction method research for minimum miscibility pressure in CO₂ flooding[J].West-China Exploration Engineering,2007,19(12):60-62.
[19] 李松岩,刘己全,李兆敏,等.油藏条件下CO₂乳液稳定性实验[J].石油学报,2015,36(5):584-592.
LI Songyan,LIU Jiquan,LI Zhaomin,et al.An experiment on CO₂ emulsion stability at reservoir conditions[J].Acta Petrolei Sinica,2015,36(5):584-592.
[20] 鞠斌山,秦积舜,李治平,等.二氧化碳-原油体系最小混相压力预测模型[J].石油学报,2012,33(2):274-277.
JU Binshan,QIN Jishun,LI Zhiping,et al.A prediction model for the minimum miscibility pressure of the CO₂-crude oil system[J].Acta Petrolei Sinica,2012,33(2):274-277.
[21] 李孟涛,张英芝,单文文,等.大庆榆树林油田最小混相压力的确定[J].西南石油学院学报,2006,28(4):36-39.
LI Mengtao,ZHANG Yingzhi,SHAN Wenwen,et al.Determination of minimum miscibility pressure in Yushulin oilfield[J].Journal of Southwest Petroleum Institute,2006,28(4):36-39.
[22] 郭建春,曾冀,张然,等.井筒注二氧化碳双重非稳态耦合模型[J].石油学报,2015,36(8):976-982.
GUO Jianchun,ZENG Ji,ZHANG Ran,et al.A dual transient coupling model for wellbore of carbon dioxide injection well[J].Acta Petrolei Sinica,2015,36(8):976-982.
[23] 韩培慧,姜言里,张景存.大庆油田二氧化碳驱油最小混相压力预测[J].油田化学,1989,6(4):309-316.
HAN Peihui,JIANG Yanli,ZHANG Jingcun.Prediction of CO₂ minimum miscibility pressure for daqing petroleum[J].Oilfield Chemistry,1989,6(4):309-316.
[24] YELLIG W F,METCALFE R S.Determination and prediction of CO₂ minimum miscibility pressures (includes associated paper 8876)[J].Journal of Petroleum Technology,1980,32(1):160-168.
[25] GUNDE A C,BERA B,MITRA S K.Investigation of water and CO₂ (carbon dioxide) flooding using micro-CT (micro-computed tomography) images of Berea sandstone core using finite element simulations[J].Energy,2010,35(12):5209-5216.
[26] SONG Zhaojie,LI Zhiping,YU Chunsheng,et al.D-optimal design for rapid assessment model of CO₂ flooding in high water cut oil reservoirs[J].Journal of Natural Gas Science and Engineering,2014,21:764-771.
[27] WU Sha,HE Jia,LI Zunzhao,et al.Studies on the chemical agent system for reducing in the minimal miscibility pressure of CO₂ flooding[J].China Sciencepaper,2015,10(18):2161-2164.
[28] SHOKIR E M E M.CO₂-oil minimum miscibility pressure model for impure and pure CO₂ streams[J].Journal of Petroleum Science and Engineering,2007,58(1/2):173-185.
[29] GHORBANI M,MOMENI A,SAFAVI S,et al.Modified vanishing interfacial tension (VIT) test for CO₂-oil minimum miscibility pressure (MMP) measurement[J].Journal of Natural Gas Science and Engineering,2014,20:92-98.
[30] HAWTHORNE B S,MILLER D J,GORECKI C D,et al.A rapid method for determining CO₂/oil MMP and visual observations of CO₂/oil interactions at reservoir conditions[J].Energy Procedia,2014,63:7724-7731.
[31] 张广东,刘建仪,柳燕丽,等.混相溶剂法降低CO₂驱混相压力研究[J].特种油气藏,2013,20(2):115-117.
ZHANG Guangdong,LIU Jianyi,LIU Yanli,et al.Study on reducing miscibility pressure in CO₂ flooding by miscible solvent[J].Special Oil & Gas Reservoir,2013,20(2):115-117.
[32] 郭平,杨学锋,冉新权.油藏注气最小混相压力研究[M].北京:石油工业出版社,2005.
GUO Ping,YANG Xuefeng,RAN Xinquan.Minimum miscibility pressure study of gas injection in reservoir[M].Beijing:Petroleum Industry Press,2005.
[33] 彭超,刘建仪,张广东,等.降低CO₂驱油最小混相压力新方法[J].重庆科技学院学报:自然科学版,2012,14(1):48-51.
PENG Chao,LIU Jianyi,ZHANG Guangdong,et al.A new method of reducing the miscible-phase pressure of CO₂ flooding[J].Journal of Chongqing University of Science and Technology:Natural Sciences Edition,2012,14(1):48-51.
[34] 陈馥,贺杰,郭平,等.一种用于混相驱降低CO₂与原油间最小混相压力的方法:CN102337874A[P].2012-02-01.
CHEN Fu,HE Jie,GUO Ping,et al.Method for reducing minimum miscible phase pressure between CO₂ and crude oil of miscible phase displacement:CN102337874A[P].2012-02-01.
[35] TORABI F,FIROUZ A,KAVOUSI A,et al.Comparative evaluation of immiscible,near miscible and miscible CO₂ huff-n-puff to enhance oil recovery from a single matrix-fracture system (experimental and simulation studies)[J].Fuel,2012,93:443-453.
[36] 杨学锋.油藏注气最小混相压力研究[D].成都:西南石油学院,2003.
YANG Xuefeng.The minimum miscibility pressure research for injecting gas of oil reservoir[D].Chengdu:Southwest Petroleum University,2003.

酯类化合物降低原油与二氧化碳体系最小混相压力实验

The experiment for reducing the minimum miscible pressure of crude oil and carbon dioxide system with ester compounds

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	宋兆杰, 邓森, 宋宜磊, 刘勇, 鲜成钢, 张江, 韩啸, 曹胜, 付兰清, 崔焕琦. 大庆油田古龙页岩油-CO₂高压相态及传质规律[J]. 石油学报, 2024, 45(2): 390-402.
[2]	魏兵, 钟梦颖, 赵金洲, 王典林, Kadet Valeriy, 游君昱. 微-纳米受限空间原油-天然气最小混相压力预测方法[J]. 石油学报, 2022, 43(11): 1604-1613.
[3]	贺振国, 李根生, 王海柱, 田守嶒, 沈忠厚, 邵尚奇, 刘新云. 超临界二氧化碳射流中的颗粒跟随及影响因素[J]. 石油学报, 2017, 38(4): 475-484.
[4]	侯磊, 孙宝江, 蒋廷学, Geng Xueyu, 王志远, 李庆超. 支撑剂在超临界二氧化碳中的跟随性计算[J]. 石油学报, 2016, 37(8): 1061-1068.
[5]	郭建春, 曾冀. 超临界二氧化碳压裂井筒非稳态温度-压力耦合模型[J]. 石油学报, 2015, 36(2): 203-209.
[6]	孙小辉, 孙宝江, 王志远. 超临界CO₂压裂裂缝温度场模型[J]. 石油学报, 2015, 36(12): 1586-1592.
[7]	程宇雄, 李根生, 沈忠厚, 王海柱, 李敬彬. 超临界二氧化碳射流冲击压力参数影响规律[J]. 石油学报, 2014, 35(4): 765-770.
[8]	鞠斌山　秦积舜　李治平　陈兴隆. 二氧化碳-原油体系最小混相压力预测模型[J]. 石油学报, 2012, 33(2): 274-277.
[9]	魏浩光岳湘安赵永攀何建华. 特低渗透油藏天然气非混相驱实验[J]. 石油学报, 2011, 32(2): 307-310.
[10]	汤勇杜志敏孙雷刘伟陈祖华. CO₂在地层水中溶解对驱油过程的影响[J]. 石油学报, 2011, 32(2): 311-314.
[11]	李良川王在明邱正松杨胜来. 超临界二氧化碳钻井流体携岩特性实验[J]. 石油学报, 2011, 32(2): 355-359.
[12]	沈平平, 黄磊. 二氧化碳—原油多相多组分渗流机理研究[J]. 石油学报, 2009, 30(2): 247-251.
[13]	彭宝仔, 罗虎, 陈光进, 孙长宇. 用界面张力法测定CO₂与原油的最小混相压力[J]. 石油学报, 2007, 28(3): 93-95.
[14]	林波, 蒲万芬, 赵金洲, 刁素, 宋丹, 张晶, 周明. 利用就地CO₂技术提高原油采收率[J]. 石油学报, 2007, 28(2): 98-101.
[15]	郭万奎, 石成方, 万新德, 李蔚, 石梅. 大庆油田聚合物驱后微生物调剖先导性现场试验研究[J]. 石油学报, 2006, 27(S1): 86-90.