鄂尔多斯盆地临兴地区上古生界泥岩地球化学特征及地质意义

doi:10.7623/syxb201808004

石油学报 ›› 2018, Vol. 39 ›› Issue (8): 876-889.DOI: 10.7623/syxb201808004

鄂尔多斯盆地临兴地区上古生界泥岩地球化学特征及地质意义

师晶^1,2,3, 黄文辉^1,2,3, 吕晨航¹, 崔晓南¹

1. 中国地质大学能源学院北京 100083;
2. 非常规天然气地质评价与开发工程北京市重点实验室北京 100083;
3. 国土资源部页岩气资源战略评价重点实验室北京 100083

收稿日期:2017-12-05 修回日期:2018-05-10 出版日期:2018-08-25 发布日期:2018-09-04
通讯作者: 黄文辉,男,1961年9月生,1982年获淮南矿业学院地质勘探专业学士学位,1997年获德国纽伦堡-埃尔兰根大学地质学专业博士学位,现为中国地质大学(北京)能源学院教授、博士生导师,主要从事油气储层地质学,环境地球化学与煤中金属元素研究。Email:1999011250@cugb.edu.cn
作者简介:师晶,女,1985年10月生,2008年获大庆石油学院资源勘查工程专业学士学位,现为中国地质大学(北京)博士研究生,主要从事储层沉积学研究工作。Email:shijing_5577@163.com
基金资助:
国家自然科学基金重点项目（No.41472136）和国家重点基础研究发展计划（973）项目（2014CB238901）。

Geochemical characteristics and geological significance of the Upper Paleozoic mudstones from Linxing area in Ordos Basin

Shi Jing^1,2,3, Huang Wenhui^1,2,3, Lü Chenhang¹, Cui Xiaonan¹

1. School of Energy Resources, China University of Geosciences, Beijing 100083, China;
2. Beijing Key Laboratory of Unconventional Natural Gas Geological Evaluation and Development Engineering, Beijing 100083, China;
3. Key Laboratory of Strategy Evaluation for Shale Gas, Ministry of Land and Resources, Beijing 100083, China

Received:2017-12-05 Revised:2018-05-10 Online:2018-08-25 Published:2018-09-04

摘要/Abstract

摘要：

利用对沉积环境敏感的元素或者元素组合可以定性或半定量地恢复古沉积环境。通过鄂尔多斯盆地临兴地区上古生界31件泥岩样品的主量元素、微量元素以及稀土元素的分析测试，对沉积水体的古盐度、古气候、古水体氧化还原环境以及古物源特征进行了探讨。结果显示：①Ba元素含量以及Sr/Ba比值的变化特征反映古盐度从上石炭统本溪组和下二叠统太原组到下二叠统山西组、中二叠统石盒子组和上二叠统石千峰组明显降低，沉积环境从海相到陆相变化；②Sr含量、Mn含量、Sr/Cu和FeO/MnO指示上古生界从本溪组到石盒子组沉积期的古气候温暖潮湿，但太原组沉积期存在一段干旱期，石千峰组沉积期为干旱气候；③V/Cr、Ni/Co以及REE等对沉积水体氧化还原环境的指示性较差，通过泥岩颜色和有机质含量可推断上古生界水体由本溪组、太原组以及山西组的还原环境转化为石盒子组和石千峰组的氧化环境；④临兴地区具有明显的轻稀土富集特征，但从本溪组到石千峰组，轻稀土的富集性变差，Ce含量表现为基本正常或轻微负异常，Eu表现为"V"型逐渐变弱的负异常；⑤上古生界的CIA指数显示物源区受到中等-强烈风化。综合稀土元素分析表明，临兴地区的物源来自鄂尔多斯盆地北部的阿拉善-阴山古陆。

关键词: 沉积环境, 物源, 地球化学, 上古生界, 临兴地区, 鄂尔多斯盆地

Abstract:

Paleo-sedimentary environment could be recovered qualitatively or semi-quantitatively by using elements or element associations sensitive to sedimentary environment. Major, trace and rare earth element compositions of 31 mudstone samples were analyzed to investigate the paleo-salinity, paleoclimate, paleo-redox and paleo-provenance characteristics of the Upper Paleozoic sedimentary water mass in Linxing area, Ordos Basin. The change characteristics of Ba content and Sr/Ba ratio reflected the paleo-salinity declined from Upper Carboniferous Benxi Formation and Lower Permian Taiyuan Formation to Lower Permian Shanxi Formation, Middle Permian Shihezi Formation and Upper Permian Shiqianfeng Formation, as well as the sedimentary environment varying from marine to terrestrial facies. Sr content, Mn content, Sr/Cu and FeO/MnO indexes indicated the Upper Paleozoic paleoclimates were humid from Benxi Formation to Shihezi Formation but arid in Taiyuan and Shiqianfeng Formations; V/Cr, Ni/Co, U/Th and REE were poor paleo-redox proxies of sedimentary water environments for Linxing area. Based on colors and organic contents of mudstones, it was deduced that the reducing environment in Benxi, Taiyuan and Shanxi Formations changed to the oxidizing environment in Shihezi and Shiqianfeng Formations. Light rare earth elements were obviously rich in Linxing area, but they became poorer from Benxi Formation to Shiqianfeng Formation with normal or slightly negative Ce anomalies and gradually weakening V-shaped negative Eu anomalies. The CIA values of Upper Paleozoic strata indicated that the provenance area had suffered medium-strong weathering. Furthermore, based on the analyses of REE patterns, Hf-La/Th and ∑REE-La/Yb diagrams, La-Th-Sc, Th-Co-Zr/10 and Th-Sc-Zr/10 discrimination diagrams, it suggested that the provenances of Linxing area were mainly from Alashan-Yinshan archicontinent in the northern Ordos Basin.

Key words: sedimentary environment, provenance, geochemistry, Paleozoic, Linxing area, Ordos Basin

中图分类号:

TE121.3

师晶, 黄文辉, 吕晨航, 崔晓南. 鄂尔多斯盆地临兴地区上古生界泥岩地球化学特征及地质意义[J]. 石油学报, 2018, 39(8): 876-889.

Shi Jing, Huang Wenhui, Lü Chenhang, Cui Xiaonan. Geochemical characteristics and geological significance of the Upper Paleozoic mudstones from Linxing area in Ordos Basin[J]. Acta Petrolei Sinica, 2018, 39(8): 876-889.

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鄂尔多斯盆地临兴地区上古生界泥岩地球化学特征及地质意义

Geochemical characteristics and geological significance of the Upper Paleozoic mudstones from Linxing area in Ordos Basin

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