页岩孔隙度、含油率评价方法现状与研究进展

doi:10.7623/syxb202509013

石油学报 ›› 2025, Vol. 46 ›› Issue (9): 1817-1834.DOI: 10.7623/syxb202509013

• 综述 • 上一篇

页岩孔隙度、含油率评价方法现状与研究进展

王民^1,2, 赵信斌^1,2, 唐育龙^1,2, 李明³, 李进步⁴

1. 山东省深层油气重点实验室山东青岛 266580;
2. 中国石油大学(华东)地球科学与技术学院山东青岛 266580;
3. 重庆科技大学重庆非常规油气开发研究院重庆 401331;
4. 中国科学院广州地球化学研究所深地过程与战略矿产资源全国重点实验室广东广州 510640

收稿日期:2024-09-10 修回日期:2024-12-24 发布日期:2025-10-11
通讯作者: 王民,男,1981年3月生,2010年获东北石油大学博士学位,现为中国石油大学(华东)教授、博士生导师,主要从事致密油气、页岩油气地质与资源评价研究工作。
作者简介:王民,男,1981年3月生,2010年获东北石油大学博士学位,现为中国石油大学(华东)教授、博士生导师,主要从事致密油气、页岩油气地质与资源评价研究工作。Email:wangm@upc.edu.cn
基金资助:
国家自然科学基金面上项目"页岩油储层差异成岩演化过程及其对页岩油富集的影响"(No.42473064)和"页岩微观-宏观润湿性差异及对页岩油赋存与可动性的影响机制研究"(No.42402139)资助。

The current status and research progress of evaluation methods for shale porosity and oil content

Wang Min^1,2, Zhao Xinbin^1,2, Tang Yulong^1,2, Li Ming³, Li Jinbu⁴

1. Shandong Provincial Key Laboratory of Deep Oil and Gas, Shandong Qingdao 266580, China;
2. School of Geosciences, China University of Petroleum (East China), Shandong Qingdao 266580, China;
3. Chongqing Institute of Unconventional Oil and Gas Development, Chongqing University of Science and Technology, Chongqing 401331, China;
4. State Key Laboratory of Deep Earth Processes and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangdong Guangzhou 510640, China

Received:2024-09-10 Revised:2024-12-24 Published:2025-10-11

摘要/Abstract

摘要： 页岩油储层的孔隙度和含油率是储量评价和甜点选区的关键参数。系统梳理了页岩孔隙度、含油率评价方法的现状与研究进展,从方法的基本原理、样品条件、实验关键参数和影响因素等方面进行分析,对不同方法的评价结果开展了对比分析,提出了页岩油储层孔隙度、含油率评价面临的主要问题和研究方向。研究结果表明:气测法和液测法是孔隙度评价常用方法,前者受样品预处理方式与测试参数影响较大,后者受饱和流体性质影响较大,两者均受洗油溶剂和洗油时长影响;核磁共振法评价页岩油储层孔隙度时可以避免气测法和液测法存在的问题,具有无需洗油、样品无损、快速且准确度高的优势;岩石热解法是页岩含油率的常用评价方法,但受样品存放条件和仪器条件影响,烃类容易发生挥发损失,因而轻烃损失校正图版是利用该方法开展有效性评价的关键。核磁共振同样是页岩含油率评价的较好方法,其核心是建立含氢流体的核磁信号识别图版和确立流体核磁共振信号与流体质量的转换关系。另外,对地层原位条件的模拟是页岩油储层孔隙度、含油率评价的重要研究方向。

关键词: 孔隙度, 含油率, 气测法, 液测法, 岩石热解, 核磁共振, 页岩油

Abstract: Porosity and oil content are critical parameters for reserve estimation and sweet spot selection in shale oil reservoirs. This paper systematically reviews the current status and research progress advancements of evaluation methods for shale porosity and oil content, of which the fundamental principles, sample requirements, key experimental parameters, and influencing factors are analyzed. Through comparison and analysis of results from different evaluation methods, primary issues and research directions in the evaluation of porosity and oil content in shale oil reservoirs are proposed. The findings indicate that gas injection porosimetry (GIP)and water injection porosimetry (WIP)methods are commonly used for porosity evaluation. The former is significantly influenced by the sample pretreatment method and testing parameters, whereas the latter shows greater susceptibility to the saturated fluid properties. Both methods are affected by the type of oil washing solvents and the duration of oil washing process. The nuclear magnetic resonance (NMR)method for evaluating shale oil reservoir porosity, which can avoid the limitations of GIP and WIP methods, have the advantages of no need for oil washing, non-destructive sampling, rapid processing, and high accuracy. Rock-Eval pyrolysis is the common method for evaluating oil content in shale. However, as influenced by sample storage conditions and instrument operation conditions, hydrocarbons are easily subject to volatilization loss. Therefore, the correction chart for light hydrocarbon loss is critical for evaluating the effectiveness of the method. Nuclear magnetic resonance is also a good method for evaluating the oil content of shale, with core technical challenges lying in establishing NMR signal identification charts for hydrogen-bearing fluids and quantifying the conversion relationship between fluid NMR signals and fluid mass. Additionally, the simulation of in-situ reservoir conditions emerges as a crucial research direction for improving the evaluation of the porosity and oil content of shale oil reservoirs.

Key words: porosity, oil content, gas injection porosimetry method, water injection porosimetry method, Rock-Eval, nuclear magnetic resonance, shale oil

中图分类号:

TE155

王民, 赵信斌, 唐育龙, 李明, 李进步. 页岩孔隙度、含油率评价方法现状与研究进展[J]. 石油学报, 2025, 46(9): 1817-1834.

Wang Min, Zhao Xinbin, Tang Yulong, Li Ming, Li Jinbu. The current status and research progress of evaluation methods for shale porosity and oil content[J]. Acta Petrolei Sinica, 2025, 46(9): 1817-1834.

参考文献

[1] U.S.Energy Information Administration.International energy outlook 2019 with projections to 2050[R].Washington D C:U.S.Energy Information Administration,2019.
[2] 贾承造,王祖纲,姜林,等.中国页岩油勘探开发研究进展与科学技术问题[J].世界石油工业,2024,31(04):1-11.
JIA Chengzao,WANG Zugang,JIANG Lin,et al.Progress and key scientific and technological problems of shale oil exploration and development in China[J].World Petroleum Industry,2024,31(4):1-11.
[3] 钱兴坤,陆如泉,罗良才,等.2023年国内外油气行业发展及2024年展望[J].国际石油经济,2024,32(2):1-13.
QIAN Xingkun,LU Ruquan,LUO Liangcai,et al.Global oil and gas industry in 2023 and outlook for 2024[J].International Petroleum Economics,2024,32(2):1-13.
[4] 邹才能,朱如凯,董大忠,等.页岩油气科技进步、发展战略及政策建议[J].石油学报,2022,43(12):1675-1686.
ZOU Caineng,ZHU Rukai,DONG Dazhong,et al.Scientific and technological progress,development strategy and policy suggestion regarding shale oil and gas[J].Acta Petrolei Sinica,2022,43(12):1675-1686.
[5] 杜金虎,胡素云,庞正炼,等.中国陆相页岩油类型、潜力及前景[J].中国石油勘探,2019,24(5):560-568.
DU Jinhu,HU Suyun,PANG Zhenglian,et al.The types,potentials and prospects of continental shale oil in China[J].China Petroleum Exploration,2019,24(5):560-568.
[6] 余涛,卢双舫,李俊乾,等.东营凹陷页岩油游离资源有利区预测[J].断块油气田,2018,25(1):16-21.
YU Tao,LU Shuangfang,LI Junqian,et al.Prediction for favorable area of shale oil free resources in Dongying sag[J].Fault-Block Oil & Gas Field,2018,25(1):16-21.
[7] 朱日房,张林晔,李政,等.陆相断陷盆地页岩油资源潜力评价——以东营凹陷沙三段下亚段为例[J].油气地质与采收率,2019,26(1):129-136.
ZHU Rifang,ZHANG Linye,LI Zheng,et al.Evaluation of shale oil resource potential in continental rift basin:a case study of Lower Es₃ Member in Dongying sag[J].Petroleum Geology and Recovery Efficiency,2019,26(1):129-136.
[8] 孙超,姚素平.页岩油储层孔隙发育特征及表征方法[J].油气地质与采收率,2019,26(1):153-164.
SUN Chao,YAO Suping.Pore structure and characterization methods of shale oil reservoir[J].Petroleum Geology and Recovery Efficiency,2019,26(1):153-164.
[9] 高铁宁,杨正明,李海波,等.页岩油储层纳米孔隙结构特征[J].中国科技论文,2018,13(21):2461-2467.
GAO Tiening,YANG Zhengming,LI Haibo,et al.Characteristics of pore structure in shale oil reservoir[J].China Sciencepaper,2018,13(21):2461-2467.
[10] 贾承造,庞雄奇,宋岩.论非常规油气成藏机理:油气自封闭作用与分子间作用力[J].石油勘探与开发,2021,48(3):437-452.
JIA Chengzao,PANG Xiongqi,SONG Yan.The mechanism of unconventional hydrocarbon formation:hydrocarbon self-containment and intermolecular forces[J].Petroleum Exploration and Development,2021,48(3):437-452.
[11] 邹才能,杨智,崔景伟,等.页岩油形成机制、地质特征及发展对策[J].石油勘探与开发,2013,40(1):14-26.
ZOU Caineng,YANG Zhi,CUI Jingwei,et al.Formation mechanism,geological characteristics and development strategy of nonmarine shale oil in China[J].Petroleum Exploration and Development,2013,40(1):14-26.
[12] TONG Shaoqing,DONG Yanhui,ZHANG Qian,et al.Quantitative analysis of nanopore structural characteristics of Lower Paleozoic shale,Chongqing (southwestern China):combining FIB-SEM and NMR cryoporometry[J].Energy & Fuels,2017,31(12):13317-13328.
[13] S UN Mengdi,ZHANG Linhao,HU Qinhong,et al.Multiscale connectivity characterization of marine shales in southern China by fluid intrusion, small-angle neutron scattering (SANS),and FIB-SEM[J].Marine and Petroleum Geology,2020,112:104101.
[14] ZHOU Shangwen,YAN Gang,XUE Huaqing,et al.2D and 3D nanopore characterization of gas shale in Longmaxi Formation based on FIB-SEM[J].Marine and Petroleum Geology,2016,73:174-180.
[15] LI Chunxiao,OSTADHASSAN M,GUO Senli,et al.Application of PeakForce tapping mode of atomic force microscope to characterize nanomechanical properties of organic matter of the Bakken Shale[J].Fuel,2018,233:894-910.
[16] SUN Mengdi,YU Bingsong,HU Qinhong,et al.Nanoscale pore characteristics of the Lower Cambrian Niutitang Formation shale:a case study from Well Yuke #1 in the southeast of Chongqing,China[J].International Journal of Coal Geology,2016,154-155:16-29.
[17] SIGAL R F.A methodology for blank and conformance corrections for high pressure mercury porosimetry[J].Measurement Science and Technology,2009,20(4):045108.
[18] SUN Jianmeng,DONG Xu,WANG Jinjie,et al.Measurement of total porosity for gas shales by gas injection porosimetry (GIP)method[J].Fuel,2016,186:694-707.
[19] NGUYEN P T M,DO D D,NICHOLSON D.Pore connectivity and hysteresis in gas adsorption:a simple three-pore model[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2013,437:56-68.
[20] PINSON M B,ZHOU Tingtao,JENNINGS H M,et al.Inferring pore connectivity from sorption hysteresis in multiscale porous media[J].Journal of Colloid and Interface Science,2018,532:118-127.
[21] ZHANG Tao,HU Qinhong,TIAN Qiang,et al.Small angle neutron scattering studies of shale oil occurrence status at nanopores[J].Advances in Geo-Energy Research,2024,11(3):230-240.
[22] LI Jinbu,WANG Min,FEI Junsheng,et al.Determination of in situ hydrocarbon contents in shale oil plays.Part 2:two-dimensional nuclear magnetic resonance (2D NMR)as a potential approach to characterize preserved cores[J].Marine and Petroleum Geology,2022,145:105890.
[23] JARVIE D M.Components and processes affecting producibility and commerciality of shale resource systems[J].Geologica Acta,2014,12(4):307-325.
[24] 薛海涛,田善思,王伟明,等.页岩油资源评价关键参数——含油率的校正[J].石油与天然气地质,2016,37(1):15-22.
XUE Haitao,TIAN Shansi,WANG Weiming,et al.Correction of oil content—one key parameter in shale oil resource assessment[J].Oil & Gas Geology,2016,37(1):15-22.
[25] 朱日房,张林晔,李钜源,等.页岩滞留液态烃的定量评价[J].石油学报,2015,36(1):13-18.
ZHU Rifang,ZHANG Linye,LI Juyuan,et al.Quantitative evaluation of residual liquid hydrocarbons in shale[J].Acta Petrolei Sinica,2015,36(1):13-18.
[26] ABRAMS M A,GONG Changrui,GARNIER C,et al.A new thermal extraction protocol to evaluate liquid rich unconventional oil in place and in-situ fluid chemistry[J].Marine and Petroleum Geology,2017,88:659-675.
[27] 张居和,冯子辉,霍秋立,等.一种泥页岩含油量与精细组分同步实验分析方法:202010480222.3[P].2020-09-01.
ZHANG Juhe,FENG Zihui,HUO Qiuli,et al.Synchronous experimental analysis method for oil content and fine components of shale:202010480222.3[P].2020-09-01.
[28] LUFFEL D L.Devonian shale matrix permeability successfully measured on cores and drill cuttings[J].Gas Shales Technology Review,1993,8(2):46-55.
[29] HANDWERGER D A,SUAREZ-RIVERA R,VAUGHN K I,et al.Improved petrophysical core measurements on tight shale reservoirs using retort and crushed samples[R].SPE 147456,2011.
[30] YAO Yanbin,LIU Dameng,XIE Songbin.Quantitative characterization of methane adsorption on coal using a low-field NMR relaxation method[J].International Journal of Coal Geology,2014,131:32-40.
[31] ZHANG Pengfei,LU Shuangfang,LI Junqian.Characterization of pore size distributions of shale oil reservoirs:a case study from Dongying sag,Bohai Bay Basin,China[J].Marine and Petroleum Geology,2019,100:297-308.
[32] 国家市场监督管理总局,国家标准化管理委员会.页岩孔隙度、渗透率和饱和度测定:GB/T 34533—2023[S].北京:中国标准出版社,2023.
State Administration for Market Regulation,National Standardization Administration.Determination of porosity,permeability and saturation of shale:GB/T 34533-2023[S].Beijing:Standards Press of China,2023.
[33] LUFFEL D L,GUIDRY F K.New core analysis methods for measuring reservoir rock properties of Devonian shale[J].Journal of Petroleum Technology,1992,44(11):1184-1190.
[34] 周尚文,董大忠,张介辉,等.页岩气储层孔隙度测试方法关键参数优化[J].天然气工业,2021,41(5):20-29.
ZHOU Shangwen,DONG Dazhong,ZHANG Jiehui,et al.Optimization of key parameters for porosity measurement of shale gas reservoirs[J].Natural Gas Industry,2021,41(5):20-29.
[35] 付永红,蒋裕强,夏国勇,等.海相页岩孔隙度GRI测定方法优化[J].天然气工业,2020,40(10):20-28.
FU Yonghong,JIANG Yuqiang,XIA Guoyong,et al.Optimization of GRI porosity determination method for marine shale[J].Natural Gas Industry,2020,40(10):20-28.
[36] 付永红,蒋裕强,陈虎,等.页岩柱塞样与碎样孔隙度差异性分析与启示[J].石油实验地质,2020,42(2):302-310.
FU Yonghong,JIANG Yuqiang,CHEN Hu,et al.Analysis and enlightenment of porosity differences between shale plug samples and crushed samples[J].Petroleum Geology & Experiment,2020,42(2):302-310.
[37] COMISKY J T,SANTIAGO M,MCCOLLOM B,et al.Sample size effects on the application of mercury injection capillary pressure for determining the storage capacity of tight gas and oil shales[R].SPE 149432,2011.
[38] 孙建孟,宗成林,董旭,等.基于核磁共振的页岩粉碎样品孔隙度研究[J].测井技术,2017,41(5):512-516.
SUN Jianmeng,ZONG Chenglin,DONG Xu,et al.Porosity measurement of crushed shales using NMR[J].Well Logging Technology,2017,41(5):512-516.
[39] SONDERGELD C H,NEWSHAM K E,COMISKY J T,et al.Petrophysical considerations in evaluating and producing shale gas resources[R].SPE 131768,2010.
[40] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.岩心分析方法:GB/T 29172—2012[S].北京:中国标准出版社,2013.
General Administration of Quality Supervision,Inspection and Quarantine of the People’s Republic of China,Standardization Administration of the People’s Republic of China.Practices for core analysis:GB/T 29172-2012[S].Beijing:Standards Press of China,2013.
[41] 林光荣,邵创国,王小林.洗油时间对低渗特低渗储层孔渗的影响[J].特种油气藏,2005,12(3):86-90.
LIN Guangrong,SHAO Chuangguo,WANG Xiaolin.Impact of cleaning time on poroperm of low and extra-low permeability reservoir[J].Special Oil & Gas Reservoirs,2005,12(3):86-87.
[42] DISTEFANO V H,MCFARLANE J,STACK A G,et al.Solvent-pore interactions in the Eagle Ford shale formation[J].Fuel,2019,238:298-311.
[43] YANG Shengyu,QIAO Hongguo,CHENG Bin,et al.Solvent extraction efficiency of an Eocene-aged organic-rich lacustrine shale[J].Marine and Petroleum Geology,2021,126:104941.
[44] DRITS V A,MCCARTY D K.The nature of structure-bonded H2O in illite and leucophyllite from dehydration and dehydroxylation experiments[J].Clays and Clay Minerals,2007,55(1):45-58.
[45] DONG Xu,SUN Jianmeng,LI Jun,et al.Experimental research of gas shale electrical properties by NMR and the combination of imbibition and drainage[J].Journal of Geophysics and Engineering,2015,12(4):610-619.
[46] 姜柏材,郭和坤,沈瑞,等.基于热力学平衡方程的孔隙度实验方法研究[J].科学技术与工程,2016,16(23):150-154.
JIANG Bocai,GUO Hekun,SHEN Rui,et al.Experimental method of porosity based on the thermodynamic equilibrium equation[J]. Science Technology and Engineering,2016,16(23): 150-154.
[47] Su S,Wang L,Li J,et al.Research on porosity characterization methods of shale oil reservoirs in Lianggaoshan Formation,Sichuan Basin[J].Frontiers in Earth Science,2024,11:1325094..
[48] XU Hao,TANG Dazhen,ZHAO Junlong,et al.A precise measurement method for shale porosity with low-field nuclear magnetic resonance:a case study of the Carboniferous-Permian strata in the Linxing area,eastern Ordos Basin,China[J].Fuel,2015,143:47-54.
[49] KATSUBE T J,KAMINENI D C.Effect of alteration on pore structure of crystalline rocks:core samples from Atikokan,Ontario[J].The Canadian Mineralogist,1983,21(4):637-646.
[50] MELNYK T W,SKEET A M M.An improved technique for the determination of rock porosity[J].Canadian Journal of Earth Sciences,1986,23(8):1068-1074.
[51] BARNES K B.A method for determining the effective porosity of a reservoir-rock[M].School of Mineral Industries,1931.
[52] HOWARD J J.Porosimetry measurement of shale fabric and its relationship to illite/smectite diagenesis[J].Clays and Clay Minerals,1991,39(4):355-361.
[53] GAUCHER E,ROBELIN C,MATRAY J M,et al.ANDRA underground research laboratory:interpretation of the mineralogical and geochemical data acquired in the Callovian-Oxfordian Formation by investigative drilling[J].Physics and Chemistry of the Earth,Parts A/B/C,2004,29(1):55-77.
[54] LI Jinbu,WANG Min,SHAO Haoming,et al.Shale porosity measurement by the saturated oil method:removing the contribution from oils dissolved in kerogen[J].Petroleum Science,2023,20(6):3273-3279.
[55] 李俊乾,卢双舫,张鹏飞,等.页岩基质孔隙水定量表征及微观赋存机制[J].石油学报,2020,41(8):979-990.
LI Junqian,LU Shuangfang,ZHANG Pengfei,et al.Quantitative characterization and microscopic occurrence mechanism of pore water in shale matrix[J].Acta Petrolei Sinica,2020,41(8):979-990.
[56] KUILA U,MCCARTY D K,DERKOWSKI A,et al.Total porosity measurement in gas shales by the water immersion porosimetry (WIP)method[J].Fuel,2014,117:1115-1129.
[57] ZHAO Peng,HE Bo,ZHANG Bo,et al.Porosity of gas shale:is the NMR-based measurement reliable?[J].Petroleum Science,2022,19(2):509-517.
[58] KENYON W E.Nuclear magnetic resonance as a petrophysical measurement[J].Nuclear Geophysics,1992,6(2):153-171.
[59] MAI A,KANTZAS A.An evaluation of the application of low field NMR in the characterization of carbonate reservoirs[R].SPE 77401,2002.
[60] Yan W,Sun J,Sun Y,et al.A robust NMR method to measure porosity of low porosity rocks[J].Microporous and Mesoporous Materials,2018,269:113-117.
[61] XIONG Chunming,DING Bin,GENG Xiangfei,et al.Quantitative analysis on distribution of microcosmic residual oil in reservoirs by frozen phase and nuclear magnetic resonance (NMR)technology[J].Journal of Petroleum Science and Engineering,2020,192:107256.
[62] KAUSIK R,MINH C C,ZIELINSKI L,et al.Characterization of gas dynamics in kerogen nanopores by NMR[R].SPE 147198,2011.
[63] WILLIAMSON N H,RÖDING M,GALVOSAS P,et al.Obtaining T₁-T₂ distribution functions from 1-dimensional T₁ and T₂ measurements:the pseudo 2-D relaxation model[J].Journal of Magnetic Resonance,2016,269:186-195.
[64] FLEURY M,ROMERO-SARMIENTO M.Characterization of shales using T₁-T₂ NMR maps[J].Journal of Petroleum Science and Engineering,2016,137:55-62.
[65] KAUSIK R,FELLAH K,RYLANDER E,et al.NMR relaxometry in shale and implications for logging[J].Petrophysics,2016,57(4):339-350.
[66] ALI M R,ANAND V,ABUBAKAR A,et al.Characterizing light versus bound hydrocarbon in a shale reservoir by integrating new two-dimensional NMR and advanced spectroscopy measurements[R].SPE 2457043,2016.
[67] KHATIBI S,OSTADHASSAN M,XIE Z H,et al.NMR relaxometry a new approach to detect geochemical properties of organic matter in tight shales[J].Fuel,2019,235:167-177.
[68] LI Jinbu,HUANG Wenbiao,LU Shuangfang,et al.Nuclear magnetic resonance T₁-T₂ map division method for hydrogen-bearing components in continental shale[J].Energy & Fuels,2018,32(9):9043-9054.
[69] ZHANG Pengfei,LU Shuangfang,LI Junqian,et al.Petrophysical characterization of oil-bearing shales by low-field nuclear magnetic resonance (NMR)[J].Marine and Petroleum Geology,2018,89:775-785.
[70] MUKHAMETDINOVA A,HABINA-SKRZYNIARZ I,KAZAK A,et al.NMR relaxometry interpretation of source rock liquid saturation— A holistic approach[J].Marine and Petroleum Geology,2021,132:105165.
[71] Bloembergen N,Purcell E M,Pound R V.Relaxation effects in nuclear magnetic resonance absorption[J].Physical review,1948,73(7):679.
[72] LIU Bo,BAI Longhui,CHI Yaao,et al.Geochemical characterization and quantitative evaluation of shale oil reservoir by two-dimensional nuclear magnetic resonance and quantitative grain fluorescence on extract:a case study from the Qingshankou Formation in southern Songliao Basin,Northeast China[J].Marine and Petroleum Geology,2019,109:561-573.
[73] TIAN Weichao,LU Shuangfang,ZHANG Jun,et al.NMR characterization of fluid mobility in low-permeability conglomerates:an experimental investigation of spontaneous imbibition and flooding[J].Journal of Petroleum Science and Engineering,2022,214:110483.
[74] 王民,李明,李进步,等.页岩含油率多种测试方法对比[J].石油学报,2022,43(12):1758-1769.
WANG Min,LI Ming,LI Jinbu,et al.Comparative analysis of test methods for shale oil content[J].Acta Petrolei Sinica,2022,43(12):1758-1769.
[75] Wang J,Zhang P,Lu S,et al.In situ fluid content evaluation of shale oil reservoirs:insights from laboratory and wellsite mobile full-diameter core NMR[J].Natural Resources Research,2025:1-18.
[76] ZHANG Pengfei,LU Shuangfang,LI Junqian,et al.Permeability evaluation on oil-window shale based on hydraulic flow unit:a new approach[J].Advances in Geo-Energy Research,2018,2(1):1-13.
[77] SCHMITT M,FERNANDES C P,DA CUNHA NETO J A B,et al.Characterization of pore systems in seal rocks using nitrogen gas adsorption combined with mercury injection capillary pressure techniques[J].Marine and Petroleum Geology,2013,39(1):138-149.
[78] LIU Kouqi,OSTADHASSAN M,ZHOU Jie,et al.Nanoscale pore structure characterization of the Bakken shale in the USA[J].Fuel,2017,209:567-578.
[79] 田华,张水昌,柳少波,等.压汞法和气体吸附法研究富有机质页岩孔隙特征[J].石油学报,2012,33(3):419-427.
TIAN Hua,ZHANG Shuichang,LIU Shaobo,et al.Determination of organic-rich shale pore features by mercury injection and gas adsorption methods[J].Acta Petrolei Sinica,2012,33(3):419-427.
[80] 杨峰,宁正福,孔德涛,等.高压压汞法和氮气吸附法分析页岩孔隙结构[J].天然气地球科学,2013,24(3):450-455.
YANG Feng,NING Zhengfu,KONG Detao,et al.Pore structure of shales from high pressure mercury injection and nitrogen adsorption method[J].Natural Gas Geoscience,2013,24(3):450-455.
[81] BLACH T,RADLINSKI A P,EDWARDS D S,et al.Pore anisotropy in unconventional hydrocarbon source rocks:a small-angle neutron scattering (SANS)study on the Arthur Creek Formation,Georgina Basin,Australia[J].International Journal of Coal Geology,2020,225:103495.
[82] BAHADUR J,RUPPERT L F,PIPICH V,et al.Porosity of the Marcellus Shale:a contrast matching small-angle neutron scattering study[J].International Journal of Coal Geology,2018,188:156-164.
[83] Yang R,He S,Hu Q,et al.Applying SANS technique to characterize nano-scale pore structure of Longmaxi shale,Sichuan Basin (China)[J].Fuel,2017,197:91-99.
[84] BAHADUR J,RADLINSKI A P,MELNICHENKO Y B,et al.Small-angle and ultrasmall-angle neutron scattering (SANS/USANS)study of New Albany Shale:a treatise on microporosity[J].Energy & Fuels,2015,29(2):567-576.
[85] SUN Mengdi,YU Bingsong,HU Qinhong,et al.Pore structure characterization of organic-rich Niutitang shale from China:small angle neutron scattering (SANS)study[J].International Journal of Coal Geology,2018,186:115-125.
[86] BERNARD S,HORSFIELD B,SCHULZ H M,et al.Geochemical evolution of organic-rich shales with increasing maturity:a STXM and TEM study of the Posidonia Shale (Lower Toarcian,northern Germany)[J].Marine and Petroleum Geology,2012,31(1):70-89.
[87] CHALMERS G R,BUSTIN R M,POWER I M.Characterization of gas shale pore systems by porosimetry,pycnometry,surface area,and field emission scanning electron microscopy/transmission electron microscopy image analyses:examples from the Barnett,Woodford,Haynesville,Marcellus,and Doig units[J].AAPG Bulletin,2012,96(6):1099-1119.
[88] WANG Pengfei,JIANG Zhenxue,CHEN Lei,et al.Pore structure characterization for the Longmaxi and Niutitang shales in the Upper Yangtze platform,South China:evidence from focused ion beam-He ion microscopy,nano-computerized tomography and gas adsorption analysis[J].Marine and Petroleum Geology,2016,77:1323-1337.
[89] KLAVER J,DESBOIS G,LITTKE R,et al.BIB-SEM pore characterization of mature and post mature Posidonia shale samples from the Hils area,Germany[J].International Journal of Coal Geology,2016,158:78-89.
[90] KLAVER J,DESBOIS G,URAI J L,et al.BIB-SEM study of the pore space morphology in early mature Posidonia Shale from the Hils area,Germany[J].International Journal of Coal Geology,2012,103:12-25.
[91] LOUCKS R G,REED R M,RUPPEL S C,et al.Morphology,genesis,and distribution of nanometer-scale pores in siliceous mudstones of the Mississippian Barnett Shale[J].Journal of Sedimentary Research,2009,79(12):848-861.
[92] TIAN Shansi,BOWEN L,LIU Bo,et al.A method for automatic shale porosity quantification using an Edge-Threshold Automatic Processing (ETAP)technique[J].Fuel,2021,304:121319.
[93] ARBELÁEZ P,MAIRE M,FOWLKES C,et al.Contour detection and hierarchical image segmentation[J].IEEE Transactions on Pattern Analysis and Machine Intelligence,2011,33(5):898-916.
[94] ZHANG Ming,ZHANG Ling,CHENG H D.A neutrosophic approach to image segmentation based on watershed method[J].Signal Processing,2010,90(5):1510-1517.
[95] OUSSEINI TINNI A.Pore connectivity and hydrocarbon storage in shale reservoirs[D].Norman:University of Oklahoma,2015.
[96] GANNAWAY G.NMR investigation of pore structure in gas shales[R].SPE 173474,2014.
[97] ZHANG Pengfei,LI Junqian,LU Shuangfang,et al.A precise porosity measurement method for oil-bearing micro/nano porous shales using low-field nuclear magnetic resonance (LF-NMR)[J].Journal of Nanoscience and Nanotechnology,2017,17(9):6827-6835.
[98] SANG Qian,ZHANG Shaojie,LI Yajun,et al.Determination of organic and inorganic hydrocarbon saturations and effective porosities in shale using vacuum-imbibition method[J].International Journal of Coal Geology,2018,200:123-134.
[99] BHANDARI A R,FLEMINGS P B,RAMIRO-RAMIREZ S,et al.Gas and liquid permeability measurements in Wolfcamp samples[J].Fuel,2019,236:1026-1036.
[100] ZHANG Shaojie,LI Yinghui,PU Hui.Studies of the storage and transport of water and oil in organic-rich shale using vacuum imbibition method[J].Fuel,2020,266:117096.
[101] 蒋裕强,付永红,谢军,等.海相页岩气储层评价发展趋势与综合评价体系[J].天然气工业,2019,39(10):1-9.
JIANG Yuqiang,FU Yonghong,XIE Jun,et al.Development trend of marine shale gas reservoir evaluation and a suitable comprehensive evaluation system[J].Natural Gas Industry,2019,39(10):1-9.
[102] LI Jinbu,LU Shuangfang,CHEN Guohui,et al.A new method for measuring shale porosity with low-field nuclear magnetic resonance considering non-fluid signals[J].Marine and Petroleum Geology,2019,102:535-543.
[103] SUN Mengdi,YU Bingsong,HU Qinhong,et al.Pore characteristics of Longmaxi shale gas reservoir in the northwest of Guizhou,China:investigations using small-angle neutron scattering (SANS),helium pycnometry,and gas sorption isotherm[J].International Journal of Coal Geology,2017,171:61-68.
[104] PERRY S E,WALLS J,HINTZMAN T.Comparing and contrasting analytically quantified porosity and pore size distributions in the Wolfcamp Formation from SEM imaging,nuclear magnetic resonance (NMR),and crushed rock core analysis[C]//Proceedings of the AAPG Annual Convention and Exhibition.Houston:AAPG,2017.
[105] LI Junliang,WANG Min,WANG Min,et al.Shale primary porosimetry based on 2D nuclear magnetic resonance of T₁-T₂[J].Energy Geoscience,2024,5(3):100270.
[106] CHEN Zhuoheng,JIANG Chunqing.A revised method for organic porosity estimation in shale reservoirs using Rock-Eval data:example from Duvernay Formation in the Western Canada Sedimentary Basin[J].AAPG Bulletin,2016,100(3):405-422.
[107] LI Jinbu,JIANG Chunqing,WANG Min,et al.Determination of in situ hydrocarbon contents in shale oil plays.Part 1:is routine Rock-Eval analysis reliable for quantifying the hydrocarbon contents of preserved shale cores?[J].Organic Geochemistry,2022,170:104449.
[108] BORDENAVE M L.Applied petroleum geochemistry[M].Paris:Editions Technips,1993.
[109] 宋国奇,张林晔,卢双舫,等.页岩油资源评价技术方法及其应用[J].地学前缘,2013,20(4):221-228.
SONG Guoqi,ZHANG Linye,LU Shuangfang,et al.Resource evaluation method for shale oil and its application[J].Earth Science Frontiers,2013,20(4):221-228.
[110] JIANG Chunqing,CHEN Zhuoheng,MORT A,et al.Hydrocarbon evaporative loss from shale core samples as revealed by Rock-Eval and thermal desorption-gas chromatography analysis:its geochemical and geological implications[J].Marine and Petroleum Geology,2016,70:294-303.
[111] CHEN Junqing,PANG Xiongqi,PANG Hong,et al.Hydrocarbon evaporative loss evaluation of lacustrine shale oil based on mass balance method:Permian Lucaogou Formation in Jimusaer depression,Junggar Basin[J].Marine and Petroleum Geology,2018,91:422-431.
[112] WANG Min,TIAN Shansi,CHEN Guohui,et al.Correction method of light hydrocarbons losing and heavy hydrocarbon handling for residual hydrocarbon (S₁)from shale[J].Acta Geologica Sinica,2014,88(6):1792-1797.
[113] JARVIE D M.Shale resource systems for oil and gas:part I—shale-gas resource systems[M]//BREYER J A.Shale reservoirs-giant resources for the 21st Century.Oklahoma:AAPG,2012:69-87.
[114] 王安乔,郑保明.热解色谱分析参数的校正[J].石油实验地质,1987,9(4):342-350.
WANG Anqiao,ZHENG Baoming.Calibration of analytic parameters for pyrolytic chromatography[J].Experimental Petroleum Geology,1987,9(4):342-350.
[115] 谌卓恒,黎茂稳,姜春庆,等.页岩油的资源潜力及流动性评价方法——以西加拿大盆地上泥盆统Duvernay页岩为例[J].石油与天然气地质,2019,40(3):459-468.
CHEN Zhuoheng,LI Maowen,JIANG Chunqing,et al.Shale oil resource potential and its mobility assessment:a case study of Upper Devonian Duvernay shale in western Canada sedimentary basin[J].Oil & Gas Geology,2019,40(3):459-468.
[116] LI Jinbu,WANG Min,CHEN Zhuoheng,et al.Evaluating the total oil yield using a single routine Rock-Eval experiment on as-received shales[J].Journal of Analytical and Applied Pyrolysis,2019,144:104707.
[117] LI Zheng,ZOU Yanrong,XU Xingyou,et al.Adsorption of mudstone source rock for shale oil—Experiments,model and a case study[J].Organic Geochemistry,2016,92:55-62.
[118] CAO Huairen,ZOU Yanrong,LEI Yan,et al.Shale oil assessment for the Songliao Basin,northeastern China,using oil generation-sorption method[J].Energy & Fuels,2017,31(5):4826-4842.
[119] 李进步,王民,卢双舫,等.页岩吸附油定量评价模型——以松辽盆地北部白垩系青山口组一段为例[J].石油勘探与开发,2023,50(5):990-1002.
LI Jinbu,WANG Min,LU Shuangfang,et al.Quantitative evaluation model of shale oil adsorption:a case study of the first Member of Cretaceous Qingshankou Formation in northern Songliao Basin,NE China[J].Petroleum Exploration and Development,2023,50(5):990-1002.
[120] DEAN E W,STARK D D.A convenient method for the determination of water in petroleum and other organic emulsions[J].Industrial & Engineering Chemistry,1920,12(5):486-490.
[121] Luffel D L.Devonian shale matrix permeability successfully measured on cores and drill cuttings[J].Gas Shales Technology Review, 1993,8(2):46-55.
[122] 包友书.渤海湾盆地东营凹陷古近系页岩油主要赋存空间探索[J].石油实验地质,2018,40(4):479-484.
BAO Youshu.Effective reservoir spaces of Paleogene shale oil in the Dongying depression,Bohai Bay Basin[J].Petroleum Geology & Experiment,2018,40(4):479-484.
[123] 付金华,李士祥,牛小兵,等.鄂尔多斯盆地三叠系长7段页岩油地质特征与勘探实践[J].石油勘探与开发,2020,47(5):870-883.
FU Jinhua,LI Shixiang,NIU Xiaobing,et al.Geological characteristics and exploration of shale oil in Chang 7 Member of Triassic Yanchang Formation,Ordos Basin,NW China[J].Petroleum Exploration and Development,2020,47(5):870-883.
[124] 靳军,王子强,孟皓锦,等.准噶尔盆地致密油岩心洗油技术探讨——以吉木萨尔凹陷芦草沟组致密油为例[J].岩性油气藏,2016,28(6):103-108.
JIN Jun,WANG Ziqiang,MENG Haojin,et al.Washing oil methods of cores from tight reservoirs in Junggar Basin:a case study of Lucaogou Formation in Jimsar sag[J].Lithologic Reservoirs,2016,28(6):103-108.
[125] LIU Yong,YAO Yanbin,LIU Dameng,et al.Shale pore size classification:an NMR fluid typing method[J].Marine and Petroleum Geology,2018,96:591-601.
[126] CUI Jiangfeng,CHENG Long.A theoretical study of the occurrence state of shale oil based on the pore sizes of mixed Gaussian distribution[J].Fuel,2017,206:564-571.
[127] WANG Junjie,LU Shuangfang,ZHANG Pengfei,et al.Characterization of shale oil and water micro-occurrence based on a novel method for fluid identification by NMR T₂ spectrum[J].Fuel,2024,374:132426.
[128] LI Jinbu,JIANG Chunqing,WANG Min,et al.Adsorbed and free hydrocarbons in unconventional shale reservoir:a new insight from NMR T₁-T₂ maps[J].Marine and Petroleum Geology,2020,116:104311.
[129] HANDWERGER D A,WILLBERG D,PAGELS M,et al.Reconciling retort versus Dean Stark measurements on tight shales[R].SPE 159976,2012.
[130] NA J G,IM C H,CHUNG S H,et al.Effect of oil shale retorting temperature on shale oil yield and properties[J].Fuel,2012,95:131-135.
[131] DE ARAU ＇ JO J H,DA SILVA N F,ACCHAR W,et al.Thermal decomposition of illite[J].Materials Research,2004,7(2):359-361.
[132] 张作祥,刘玉,曲斌,等.岩心油水饱和度乙醇萃取分析法:201611027182.7[P].2017-05-31.
ZHANG Zuoxiang,LIU Yu,QU Bin,et al.Core oil-water saturation analyzing method based on ethanol extraction:201611027182.7[P].2017-05-31.
[133] 刘超,卢双舫,薛海涛.变系数ΔlogR方法及其在泥页岩有机质评价中的应用[J].地球物理学进展,2014,29(1):312-317.
LIU Chao,LU Shuangfang,XUE Haitao.Variable-coefficient ΔlogR model and its application in shale organic evaluation[J].Progress in Geophysics,2014,29(1):312-317.
[134] CHEN Huangye,FIRDAUS G,HEIDARI Z.Impact of anisotropic nature of organic-rich source rocks on electrical resistivity measurements[R].SPWLA 2014,2014.
[135] CLENNELL M B,JOSH M,ESTEBAN L,et al.The influence of pyrite on rock electrical properties:a case study from NW Australian gas reservoirs[R].SPWLA 2010-97081,2010.
[136] KETHIREDDY N,HEIDARI Z,CHEN Huangye.Quantifying the effect of kerogen on electrical resistivity measurements in organic-rich source rocks[R].SPWLA 2013-NN,2013.
[137] 刘国强.非常规油气勘探测井评价技术的挑战与对策[J].石油勘探与开发,2021,48(5):891-902.
LIU Guoqiang.Challenges and countermeasures of log evaluation in unconventional petroleum exploration[J].Petroleum Exploration and Development,2021,48(5):891-902.
[138] 陈龙川,张兆谦,郑建东,等.核磁共振测井在古龙页岩油评价中的应用[J].测井技术,2024,48(1):110-116.
CHEN Longchuan,ZHANG Zhaoqian,ZHENG Jiandong,et al.Application of NMR logging in the evaluation of Gulong shale oil[J].Well Logging Technology,2024,48(1):110-116.
[139] QIAO Lu,YANG Shengyu,HU Qinhong,et al.An integrated Convolutional Neural Network prediction framework for in situ shale oil content based on conventional logging data[J].Journal of the Geological Society,2024,181(6):jgs2023-218.
[140] GU Mingxuan,XIE Ranhong,JIN Guowen,et al.Quantitative evaluation for fluid components on 2D NMR spectrum using blind source separation[J].Journal of Magnetic Resonance,2021,332:107079.
[141] ZHANG Hong,HUANG Haiping,LI Zheng,et al.Comparative study between sequential solvent-extraction and multiple isothermal stages pyrolysis:a case study on Eocene Shahejie Formation shales,Dongying depression,East China[J].Fuel,2020,263:116591.
[142] LIU Yazhou,ZENG Jianhui,YANG Guangqing,et al.An innovative method for the characterization of oil content in lacustrine shale-oil systems:a case study from the Middle Permian Lucaogou Formation in the Jimusaer sag,Junggar Basin[J].Marine and Petroleum Geology,2021,130:105112.

页岩孔隙度、含油率评价方法现状与研究进展

The current status and research progress of evaluation methods for shale porosity and oil content

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