插层聚合物凝胶深部液流转向剂的研制与性能评价

doi:10.7623/syxb201401012

石油学报 ›› 2014, Vol. 35 ›› Issue (1): 107-113.DOI: 10.7623/syxb201401012

插层聚合物凝胶深部液流转向剂的研制与性能评价

王洪关^1,2,3, 何顺利¹, 冯爱丽³, 程中疆⁴, 白胤杰³

1. 中国石油大学石油工程学院北京 102249;
2. 北京华油科隆开发公司北京 100011;
3. 中国石油集团科学技术研究院北京 100083;
4. 中国石油新疆油田公司黑油山公司新疆克拉玛依 834000

收稿日期:2013-07-26 修回日期:2013-10-22 出版日期:2014-01-25 发布日期:2013-12-09
通讯作者: 王洪关，男，1969年12月生，1991年毕业于河北工学院，现为北京华油科隆开发公司高级工程师，主要从事油气田开发研究工作。Email：whg@petrochina.com.cn
作者简介:王洪关，男，1969年12月生，1991年毕业于河北工学院，现为北京华油科隆开发公司高级工程师，主要从事油气田开发研究工作。Email：whg@petrochina.com.cn
基金资助:
国家重大科技专项（2011ZX05010-003）资助。

A intercalated polymer gel for deep fluid diversion agent and performance evaluation

Wang Hongguan^1,2,3, He Shunli¹, Feng Aili³, Cheng Zhongjiang⁴, Bai Yinjie³

1. School of Petroleum Engineering, China University of Petroleum, Beijing 102249, China;
2. Beijing Huayou Kelong Development Corporation, Beijing 100011, China;
3. CNPC Research Institute of Science and Technology, Beijing 100083, China,;
4. Heiyoushan Corporation, PetroChina Xinjiang Oilfield Company, Karamay 834000, China

Received:2013-07-26 Revised:2013-10-22 Online:2014-01-25 Published:2013-12-09

摘要/Abstract

摘要： 为了开发出一种新型低成本、高性能的深部液流转向与调驱剂，利用现代插层复合技术，对目前调剖调驱中常用的聚丙烯酰胺进行聚合物合成改性，采用原位聚合合成方法，研制了一种新型插层聚合物凝胶转向剂，其插层聚合物、交联剂和助剂的浓度分别为0.15% ~0.35% 、0.15% ~0.22% 、0.005% ~0.220% ，其成胶时间为6~100 h可调。实验研究表明，该插层聚合物凝胶转向剂具有较好的抗剪切性、与油田水的配伍性、热稳定性及封堵性能，可满足油田条件下的深部调驱和改善水驱开发效果的需要。其与现有的常规聚合物体系相比成本可降低10% ~15% ，表明该体系具有良好的应用前景。

关键词: 插层聚合物凝胶, 转向剂, 交联剂, 凝胶性能, 低成本

Abstract: This study aims to develop a novel cost-effective high-performance deep fluid diversion and profile control-displacement agent. The synthesis and modification of polyacrylamide, a polymer presently commonly used in profile control and oil displacement, is carried out using the modern intercalation compounding technique. A new intercalated polymer gel diversion agent is developed by in situ polymerization. The concentrations of intercalated polymer, cross linker, and additive agent are 0.15% -0.35%, 0.15% -0.22%, and 0.005% -0.22%, respectively; the gelation time is adjustable between 6 h and 100 h. Experiment data show that the obtained intercalated polymer gel type deep fluid diversion agent has good shear resistance, high compatibility with oilfield water, thermal stability, and plugging performance. It can meet the need of depth profile control under field conditions and improve the waterflooding development effect. Compared with the existing polymer system, the proposed polymer system has reduced cost by 10% -15%, indicating its good application prospects.

Key words: Intercalated polymer gel, diversion agent, cross linker, gel property, low cost

中图分类号:

TE357.4

王洪关, 何顺利, 冯爱丽, 程中疆, 白胤杰. 插层聚合物凝胶深部液流转向剂的研制与性能评价[J]. 石油学报, 2014, 35(1): 107-113.

Wang Hongguan, He Shunli, Feng Aili, Cheng Zhongjiang, Bai Yinjie. A intercalated polymer gel for deep fluid diversion agent and performance evaluation[J]. ACTA PETROLEI SINICA, 2014, 35(1): 107-113.

参考文献

[1] 孙赞东, 贾承造, 李相方, 等.非常规油气勘探与开发:上册[M].北京:石油工业出版社, 2011:1-150.
Sun Zandong, Jia Chengzao, Li Xiangfang, et al.Unconventional oil & gas exploration and development:upper volume[M].Beijing:Petroleum Industry Press, 2011:1-150.
[2] 韩大匡.深度开发高含水油田提高采收率问题的探讨[J].石油勘探与开发, 1995, 22(5):47-55.
Han Dakuan.An approach to deep development of high water-cut oil fields to improve oil recovery[J]. Petroleum Explortion & Development, 1995, 22(5):47-55.
[3] 刘玉章, 熊春明, 罗健辉, 等.高含水油田深部液流转向技术研究[J].油田化学, 2006, 23(3):248-251.
Liu Yuzhang, Xiong Chunming, Luo Jianhui, et al.Studies on indepth fluid diverting in oil reservoirs at high water cut stages[J].Oilfield Chemistry, 2006, 23(3)248-251.
[4] 孙丽娜, 李军强.油田深部液流转向技术[J].断块油气田, 2009, 16(3):88-89.
Sun Lina, Li Junqiang.Diversion technique of deep fluid in oilfield[J].Fault-block Oil & Gas Field, 2009, 16(3):88-89.
[5] 马涛.复合吸水颗粒深部液流转向剂注入性研究[J].西南石油大学学报:自然科学版, 2010, 32(4):119-122.
Ma Tao.The study on injection performance of water absorbing particles in-depth fluid diversion agent[J].Journal of Southwest Petroleum University, 2010, 32(4):119-122.
[6] 姚峰, 袁玉锋, 曹全芳.高含水断块交联聚合物堵水调剖研究与应用[J].西南石油学院学报, 2004, 26(5):57-59.
Yao Feng, Yuan Yufeng, Cao Quanfang.Research and application of water plugging and profile control of a crosslinked polymer solution in fault block with high water content[J].Journal of Southwest Petroleum Institute, 2004, 26(5):57-59.
[7] 戚勇, 孟兆松.复合交联聚合物调剖剂的室内实验研究[J].精细石油化工进展, 2010, 11(8):21-23.
Qi Yong, Meng Zhaosong.Laboratory study on compound crosslinking polymer profile control agent[J].Advances in Fine Petrochemicals, 2010, 11(8):21-23.
[8] Chen Junwu, Zhao Yaoming.An efficient preparation method for super absorb entpolymers[J].Journal of Applied polymer Science, 1999, 74(1):119-124.

[9] 宋海明, 张宝述, 彭同江, 等.溶液插层法制备聚合物/黏土纳米复合材料的研究进展[J].中国粉体技术, 2007(3):44-48.
Song Haiming, Zhang Baoshu, Peng Tongjiang, et al.Recent advance in research on preparing polymer/clay nano-composites by intercalation of polymer from solution[J].China Powder Science and Technology, 2007(3):44-48.
[10] 汪杰.聚合物/黏土纳米复合材料的研究[J]辽宁化工, 2008, 37(1):36-38.
Wang Jie. Research on polymer/montorillonite nanocomposites[J].Liaoning Chemical Industry, 2008, 37(1):36-38.
[11] 屈沅治, 孙金声, 苏义脑.聚丙烯酰胺类纳米材料的研究进展[J].油田化学, 2006, 23(3):273-276.
Qu Yuanzhi, Sun Jinsheng, Shu Yinao.Advances in acrylamide polymers nanomaterials[J].Oilfield Chemistry, 2006, 23(3):273-276.
[12] 黄明福.聚合物/黏土纳米复合材料研究进展[J].材料工程, 2006(增刊1):433-437.
Wang Mingfu.Progress of Polymer/Clay Nanocomposites[J].Journal of Materials Engineering, 2006(Supplement1):433-437.
[13] 高德玉, RB-海曼, B-托马斯, 等.聚丙烯酰胺/蒙脱土复合材料结构研究[J].高分子材料科学与工程, 2005, 21(4):202-204.
Gao Deyu, Heimann R B, Tomas B, et al.Studies on the structure of poly(acrylamide)-montmorillonite nanocomposite[J]. polymer Materials Science and Engineering, 2005, 21(4):202-204.
[14] Zolfaghari B, Katbab A A, Nabavizadeh J, et al.Preparation and characterization of nanocomposite hydrogels based on polyacrylamide for enhanced oil recovery applications[J].Journal of Applied Polymer Science, 2006, 100(3), 2096-2103.

[15] 戴彩丽, 赵娟, 姜汉桥, 等.低渗透砂岩油藏注入阴阳离子聚合物深部调剖技术研究[J].石油学报, 2010, 31(3):440-444.
Dai Caili, Zhao Juan, Jiang Hanqiao, et al.Alternative injection of anionic and cationic polymers for deep profilecontrol in low-permeability sandbody reservoir[J].Acta Petrolei Sinica, 2010, 31(3):440-444.
[16] 唐孝芬, 吴奇, 刘戈辉, 等.区块整体弱凝胶调驱矿场试验及效果[J].石油学报, 2003, 24(4):58-61.
Tang Xiaofen, Wu Qi, Liu Gehui, et al.Field test on integral modifying and flooding projectin regional reservoir with weak gel[J].Acta Petrolei Sinica, 2003, 24(4):58-61.
[17] 李明远, 郑晓宇, 林梅钦, 等.交联聚合物溶液深部调驱先导试验[J].石油学报, 2002, 23(6):72-76.
Li Mingyuan, Zheng Xiaoyu, Lin Meiqin, et al.Petroleum engineering experiment in situ taking linked polymer solution as in depth profile con-trol agent[J].Acta Petrolei Sinica, 2002, 23(6):72-76.
[18] 于志纲, 贾朝霞.蒙脱土改性的研究进展[J].精细石油化工进展, 2005, 6(8):5-7.
Yu Zhigang, Jia Zhaoxia.Research progress on montmorillonites modification[J].Advances in Fine Petrochemicals, 2005, 6(8):5-7.

插层聚合物凝胶深部液流转向剂的研制与性能评价

A intercalated polymer gel for deep fluid diversion agent and performance evaluation

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 5

编辑推荐

Metrics

本文评价

[1]	张胜传, 陈紫薇, 程运甫, 刘学伟, 付大其, 周震, 李晓娟. 海水基压裂液研制[J]. 石油学报, 2016, 37(S2): 131-136.
[2]	俞然刚, 任文明, 张安. 转向剂形成遮挡层压降的数值计算模型及其应用[J]. 石油学报, 2008, 29(6): 942-945.
[3]	朱怀江, 程杰成, 隋新光, 王平美, 赵庆东, 李宜坤, 刘强, 姚波. 柔性转向剂性能及作用机理研究[J]. 石油学报, 2008, 29(1): 79-83.
[4]	孔柏岭, 宋振宇. 耐温抗盐的低浓度交联聚合物体系研究[J]. 石油学报, 2000, 21(4): 70-74.
[5]	袁士义. 聚合物地下交联调剖数学模型[J]. 石油学报, 1991, 12(1): 49-59.