基于Janus纳米颗粒的水基钻井液润滑抗磨剂

doi:10.7623/syxb202609011

石油学报 ›› 2026, Vol. 47 ›› Issue (9): 1888-1897.DOI: 10.7623/syxb202609011

• 石油工程 • 上一篇

基于Janus纳米颗粒的水基钻井液润滑抗磨剂

宣扬¹, 李大奇¹, 邓师洁¹, 杨昊儒², 肖瑶¹, 梁福鑫²

1. 中石化石油工程技术研究院有限公司北京 102206;
2. 清华大学化学工程系北京 100084

收稿日期:2025-07-30 修回日期:2026-05-20 发布日期:2026-10-14
通讯作者: 李大奇，男，1982年9月生，2012年获西南石油大学油气井工程专业博士学位，现为中石化石油工程技术研究院有限公司研究员，主要从事油田化学领域的研究工作。Email：lidq.sripe@sinopec.com
作者简介:宣扬，男，1984年5月生，2015年获中国石油大学（北京）油气井工程专业博士学位，现为中石化石油工程技术研究院有限公司副研究员，主要从事油田化学领域的研究工作。Email：xuanyang.sripe@sinopec.com
基金资助:
国家科技重大专项（2025ZD1401301）资助。

Janus nanoparticles as lubricant and anti-wear additives in water-based drilling fluid

Xuan Yang¹, Li Daqi¹, Deng Shijie¹, Yang Haoru², Xiao Yao¹, Liang Fuxin²

1. Sinopec Research Institute of Petroleum Engineering Co., Ltd., Beijing 102206, China;
2. Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2025-07-30 Revised:2026-05-20 Published:2026-10-14

摘要/Abstract

摘要： 基于Janus颗粒结构设计及调控方法，将强疏水的聚四氟乙烯（PTFE）与亲水性的氧化硅（SiO₂）相结合，制备了能够在水性介质中良好分散的PTFE@SiO₂ Janus纳米颗粒，考察了Janus纳米颗粒在加重膨润土基浆和水基钻井液体系中高温老化后的润滑抗磨性能。研究结果表明，质量分数为2%的Janus纳米颗粒能够分别降低基浆和钻井液体系的摩擦系数51.3%和36.5%，并且与酯类润滑剂复配后能够起到协同增效作用。此外，Janus纳米颗粒还具有较好的抗磨性能，在高载荷下的磨痕面积明显低于酯类润滑剂。作用机理的分析表明，摩擦过程中Janus颗粒的PTFE端通过分子链易于滑移的特性，形成连续润滑膜，降低摩擦系数，刚性的SiO₂端则起到提高润滑膜强度的作用，保证润滑效能的稳定发挥。独特的“双面神”结构是Janus纳米颗粒兼具优异润滑和抗磨性能的关键。

关键词: Janus纳米颗粒, 聚四氟乙烯, 摩擦, 润滑, 水基钻井液

Abstract: Based on the structural engineering and regulation strategy of Janus nanoparticles, hydrophobic polytetrafluoroethylene (PTFE) and hydrophilic silica (SiO₂) were combined to fabricate PTFE@SiO₂ Janus nanoparticles with excellent dispersibility in aqueous media. The lubrication and anti-wear performance of Janus nanoparticles after high-temperature aging in weighted bentonite-based slurry and water-based drilling fluid systems was systematically investigated. The results show that at a dosage of 2%（mass fraction）, Janus nanoparticles reduce the friction coefficient of the base slurry and drilling fluid systems by 51.3% and 36.5%, respectively, and exhibit a clear synergistic effect when combined with ester-based lubricants. In addition, Janus nanoparticles demonstrate superior anti-wear performance, with significantly smaller wear scar areas under high-load conditions compared with ester lubricants. Mechanistic analysis indicates that, during the friction process, the PTFE side of Janus nanoparticles readily forms a continuous lubricating film owing to the facile slippage of molecular chains, thereby reducing the friction coefficient; the rigid SiO₂ side enhances the mechanical strength of the lubricating film, ensuring stable lubrication performance. Overall, the unique Janus amphiphilic structure is the key to the outstanding lubrication and anti-wear performance of the nanoparticles.

Key words: Janus nanoparticles, polytetrafluoroethylene (PTFE), friction, lubrication, water-based drilling fluid

中图分类号:

TE254

宣扬, 李大奇, 邓师洁, 杨昊儒, 肖瑶, 梁福鑫. 基于Janus纳米颗粒的水基钻井液润滑抗磨剂[J]. 石油学报, 2026, 47(9): 1888-1897.

Xuan Yang, Li Daqi, Deng Shijie, Yang Haoru, Xiao Yao, Liang Fuxin. Janus nanoparticles as lubricant and anti-wear additives in water-based drilling fluid[J]. Acta Petrolei Sinica, 2026, 47(9): 1888-1897.

参考文献

[1] 汪海阁,夏焱,丁吉平,等. 中石油深层煤岩气钻完井工程技术现状及展望[J].石油学报,2025,46(8):1576-1588.
WANG Haige,XIA Yan,DING Jiping,et al.Current status and prospect of CNPC’s deep coal-rock gas drilling and completion engineering technologies[J].Acta Petrolei Sinica,2025,46(8):1576-1588.
[2] 孙金声,杨景斌,吕开河,等.致密油气钻井液技术研究现状与展望[J].石油学报,2025,46(1):279-288.
SUN Jinsheng,YANG Jingbin,Lü Kaihe,et al.Research status and prospects of drilling fluid technology for tight oil and gas[J].Acta Petrolei Sinica,2025,46(1):279-288.
[3] 李勇,黄盟,雷征东,等.中国陆相页岩油地质—工程一体化差异化开发对策[J].石油学报,2026,47(2):437-454.
LI Yong,HUANG Meng,LEI Zhengdong,et al.Differentiated geoscience-engineering integrated development strategies for continental shale oil in China[J].Acta Petrolei Sinica,2026,47(2):437-454.
[4] 陈雨飞,张辉,李军,等.长水平段水平井岩屑床阻力模型及实验[J].石油学报,2025,46(11):2174-2186.
CHEN Yufei,ZHANG Hui,LI Jun,et al.Frictional resistance model of cuttings bed and experiment for long horizontal section wells[J].Acta Petrolei Sinica,2025,46(11):2174-2186.
[5] 屈沅治,张蝶,兰雅婧,等.水基钻井液用多元协同纳米润滑剂的研究进展[J].材料导报,2025,39(2):23090016.
QU Yuanzhi,ZHANG Die,LAN Yajing,et al.Research progress of multivariate synergistic nanolubricants for water-based drilling fluids[J].Materials Reports,2025,39(2):23090016.
[6] 张勤,倪华峰,王清臣.长庆致密气田超长水平段钻井降摩减阻技术[J].石油钻采工艺,2022,44(6):671-677.
ZHANG Qin,NI Huafeng,WANG Qingchen.Drag reduction technology for ultra-long horizontal drilling in the Changqing tight gas reservoir[J].Oil Drilling & Production Technology,2022,44(6):671-677.
[7] 钱晓琳,宣扬,林永学,等.钻井液环保润滑剂SMLUB-E的研制及应用[J].石油钻探技术,2020,48(1):34-39.
QIAN Xiaolin,XUAN Yang,LIN Yongxue,et al.Development and application of an environmental-friendly drilling fluid lubricant SMLUB-E[J].Petroleum Drilling Techniques,2020,48(1):34-39.
[8] MCGUIGGAN P M.The boundary lubrication properties of model esters[J].Tribology Letters,2001,11(1):49-53.
[9] YUE Luo,MENG Yan,ZHOU Xue,et al.Tribological characteristics and degradation mechanism of typical synthetic lubricants from room temperature to 300 ℃[J].Tribology International,2024,198:109865.
[10] BISWAS S K,VIJAYAN K.Friction and wear of PTFE：a review[J].Wear,1992,158(1/2):193-211.
[11] ONODERA T,PARK M,SOUMA K,et al.Transfer-film Formation mechanism of polytetrafluoroethylene:a computational chemistry approach[J].The Journal of Physical Chemistry C,2013,117(20):10464-10472.
[12] XU Qiang,ZHANG Jie,LI Xin,et al.How polytetrafluoroethylene lubricates iron:an atomistic view by reactive molecular dynamics[J].ACS Applied Materials & Interfaces,2022 14(4):6239-6250.
[13] BI Zhuming,MUELLER D W.Friction predication on pin-to-plate interface of PTFE material and steel[J].Friction,2019,7(3):268-281.
[14] WANG Na,WANG Honggang,REN Junfang,et al.High-efficient and environmental-friendly PTFE@SiO₂ core-shell additive with excellent AW/EP properties in PAO6[J].Tribology International,2021,158:106930.
[15] SAINI V,BIJWE J,SETH S,et al.Interfacial interaction of PTFE sub-micron particles in oil with steel surfaces as excellent extreme-pressure additive[J].Journal of Molecular Liquids,2021,325:115238.
[16] SHARMA V,TIMMONS R,ERDEMIR A,et al.Plasma-functionalized polytetrafluoroethylene nanoparticles for improved wear in lubricated contact[J].ACS Applied Materials & Interfaces,2017,9(30):25631-25641.
[17] HARRIS K L,PITENIS A A,GREGORY SAWYER W,et al.PTFE Tribology and the role of mechanochemistry in the development of protective surface films[J].Macromolecules,2015,48(11):3739-3745.
[18] DE GENNES P G.Soft matter (Nobel lecture)[J].Angewandte Chemie International Edition,1992,31(7):842-845.
[19] LIANG Fuxin,ZHANG Chengliang,YANG Zhenzhong.Rational design and synthesis of Janus composites[J].Advanced Materials,2014,26(40):6944-6949.
[20] LIU Yanfei,HE Hailing,YANG Meng,et al.Novel concept of nano-additive design:PTFE@silica Janus nanoparticles for water lubrication[J].Friction,2024,12(2):258-270.

基于Janus纳米颗粒的水基钻井液润滑抗磨剂

Janus nanoparticles as lubricant and anti-wear additives in water-based drilling fluid

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