石油学报 ›› 1981, Vol. 2 ›› Issue (3): 93-102.DOI: 10.7623/syxb198103011

• 石油炼制 • 上一篇    下一篇

碳氢化合物对镍铬合金高温燃烧腐蚀的研究

侯祥麟1, 林风2, 杨怡生2, 詹永厚2, 冉国朋2, 李秀珍2   

  1. 1. 石油工业部;
    2. 石油化工研究院
  • 收稿日期:1980-10-20 出版日期:1981-07-25 发布日期:2013-07-08

INVESTIGATION OF HIGH TEMPERATURE CORROSION OF Ni-Cr ALLOY BY THE BURNING HYDROCARBONS

Hou Xiangling1, Lin Feng2, Yang Yisheng2, Zhan Yonghou2, Ran Guopeng2, Li Xiuzhen2   

  1. 1. The Ministry of Petroleum Industry, The People's Republic of China;
    2. Petroleum Chemical Research Institute
  • Received:1980-10-20 Online:1981-07-25 Published:2013-07-08

摘要: 烃类燃料燃烧过程中引起合金腐蚀的原因,一般都认为是硫或重金属如钒等所造成的。五十年代后期我们在试验喷气燃料的燃烧性能时,发现有些喷气燃料引起镍铬合金的燃烧室一次燃烧区严重坑点腐蚀(图1、2)。通过深入探讨,证明腐蚀不是硫或重金属等杂质所引起的,而是烃类本身造成的。某些喷气燃料不引起镍铬合金燃烧坑点腐蚀,是因为燃料中的杂质有抑制腐蚀作用。由此找到了加入添加物以抑制腐蚀的途径。

Abstract: In the operation of aviation gas turbine engines using some hydrocarbon fuels, pitting corrosion on heat resistant Ni-Cr alloy parts in the combustion chamber has been observed.Experiments indicate that the pitting corrosion is not caused by impurities in the fuel but by the hydrocarbons. Investigation of the effect of various gas components on the heat resistant Ni-Cr alloys and nickel, of the carbon deposits formed on the alloy surface and of the changes in alloy composition of the attacked parts reveals that the bulk alloy is attacked by the burning hydrocarbons containing methane and carbon monoxide through carburization of the alloy which give rise to the precipitation of chromium carbides and the formation of nickelrich spots. As a consequence of the catalytic action of nickel on hydrocarbons, dehydrocondensation reactions take place and the corroded surface is readily covered with carbon by graphitizing action. It is theorized that pitting corrosion of the Ni-Cr alloys occur through these processes. It can be inhibited by the addition of some sulfur, arsenic or selenium compounds into the fuels to hinder the undesired catalytic dehydrocondensation reactions.