石油学报 ›› 1984, Vol. 5 ›› Issue (2): 107-117.DOI: 10.7623/syxb198402014

• 论文 • 上一篇    

抚顺油页岩热分解过程的热重法研究

杨继涛, 陈廷蕤   

  1. 华东石油学院
  • 收稿日期:1988-01-03 出版日期:1984-04-25 发布日期:2013-07-08

THERMOGRAVIMETRIC STUDY ON THE PYROLYSIS OF FUSHUN OIL SHALE

Yang Jitao, Chen Tingrui   

  1. East China Petroleum Institute
  • Received:1988-01-03 Online:1984-04-25 Published:2013-07-08

摘要: 采用线性升温速率6.8k/min的热重装置,在惰性气(氮)流量100ml/min的条件下,考察了粒度<0.075mm,0.3~0.5mm,0.75~1.0mm及1.5~2.0mm的两种抚顺页岩的非等温热分解过程.根据试验得出的热重曲线,失重速率-温度曲线及转化率-温度曲线,获得了抚顺页岩的初始分解温度及失重速率峰值温度等动力学特征值,并确定,粒度小于2.0mm的抚顺富矿页岩(铝甑产油率9.8%)及贫矿页岩(铝甑产油率3.9%)的主要热解生油阶段分别为400~500℃及400~520℃.

Abstract: Nonisothermal pyrolysis of two kinds of Fushun oil shale with particle asize 0.075mm,0.3-0.5mm,0.75-1.0mm and 1.5-2.0mm has been in-vestigated at the flow rate of 100ml/min in inert stream(nitrogen) by thermogravimetric analyzer with linear heating rate 6.8K/min.The characteristic values of pyrolytic kinetics of Fushun shales,their initial temperature of py-rolysis and the temperature at the maximum rate of weight loss etc.are obtained from the thermogravimetric curves,the rate of weight loss vs.tempe-rature curves and the conversion vs.temperature curves derived from experiments.It has been found that shale oil is mainly formed during pyrolysis of rich oil shale(9.8% oil yield of Fisher Assay) and poor oil shale(3.9% oil yield of Fisher Assay) with particle size 2.0mm in the temperature regions 400-500℃ and 400-520℃ respectively.Processing of thermogravimetric data reveals that the pyrolytic reactions of the two Fushun oil shales are both of the first order,but with different activation energy E and pre-expo-nential factor A in different temperature regions during pyrolysis.This is different from what was described in general terms as global first order reactions for oil shale pyrolysis by other authors in the past.The kinetic parameters for pyrolysis of the two Fushun oil shales with different particle sizes were calculated by means of least square curve fitting,and the influen-ce of particle size on pyrolysis was also discussed.