川东北元坝与河坝地区陆相储层天然气成因

doi:10.7623/syxb201401003

石油学报 ›› 2014, Vol. 35 ›› Issue (1): 26-36.DOI: 10.7623/syxb201401003

川东北元坝与河坝地区陆相储层天然气成因

王万春¹, 张晓宝¹, 刘若冰², 罗厚勇¹, 王国仓¹

1. 中国科学院油气资源研究重点实验室甘肃兰州 730000;
2. 中国石油化工股份有限公司勘探南方分公司四川成都 610041

收稿日期:2013-07-08 修回日期:2013-10-22 出版日期:2014-01-25 发布日期:2013-12-09
通讯作者: 王万春，女，1962年9月生，1984年获兰州大学学士学位，2006年获中国科学院研究生院博士学位，现为中国科学院地质与地球物理研究所兰州油气资源研究中心副研究员，主要从事地球化学研究工作。Email：lgas@lzb.ac.cn
作者简介:王万春，女，1962年9月生，1984年获兰州大学学士学位，2006年获中国科学院研究生院博士学位，现为中国科学院地质与地球物理研究所兰州油气资源研究中心副研究员，主要从事地球化学研究工作。Email：lgas@lzb.ac.cn
基金资助:
国家重点基础研究发展计划（973）项目（2012CB214801）和中国科学院重要方向项目（KZCX2-YW-Q05-03）资助。

Origin of natural gas in terrestrial reservoirs in Yuanba and Heba regions in northeastern Sichuan Basin, China

Wang Wanchun¹, Zhang Xiaobao¹, Liu Ruobing², Luo Houyong¹, Wang Guocang¹

1. Key Laboratory of Petroleum Resources Research, Chinese Academy of Sciences, Lanzhou 730000, China;
2. Sinopec Exploration Southern Company, Chengdu 610041, China

Received:2013-07-08 Revised:2013-10-22 Online:2014-01-25 Published:2013-12-09

摘要/Abstract

摘要： 在川东北地区石油地质背景特征的基础上，探讨了元坝与河坝地区陆相储层天然气的成因。元坝地区侏罗系储层天然气重烃气体含量较高；多数样品甲烷δ¹³C和δD值分别在-42.2‰ ~-34.4‰ 和-208‰ ~-168‰ ，乙烷δ¹³C值在-31.4‰ ~-21.4‰ ，甲烷δ¹³C和δD值之间相关性好；天然气主要来源于侏罗系自流井组或千佛崖组陆相烃源岩。元坝地区须家河组储层天然气重烃气体含量低；甲烷δ¹³C和δD值分别为-31.7‰ ~-29.2‰ 和-170‰ ~-148‰ ，乙烷δ¹³C值在-27.7‰ ~-26.5‰ ；天然气主要来源于元坝地区上三叠统须家河组高—过成熟的腐殖型烃源岩。元坝地区陆相储层天然气成因的主控因素是陆相烃源岩发育及其成熟度。河坝地区陆相储层天然气重烃气体含量变化大；甲烷δ¹³C值大多重于-32‰ ，甲烷δD值分布范围较大，在-186‰ ~-122‰ ，乙烷δ¹³C值在-33.2‰ ~-29.6‰ ；甲烷δD与δ¹³C值之间相关性很差，部分样品甲烷与乙烷的δ¹³C值倒转，表明河坝地区陆相储层天然气成因复杂，有来源于陆相须家河组的天然气，也有来源于海相烃源岩的天然气，以及海相与陆相来源天然气的混合气。河坝地区陆相储层天然气成因的主控因素是海相与陆相多套烃源岩与不同级别断裂。陆相储层天然气中CO₂的δ¹³C值多轻于-12‰ ，属于有机质热分解成因。稀有气体³He/⁴He比值在0.003 3R_a~0.018 1R_a，分布于地壳来源或放射性成因的范围内，表明天然气中没有幔源稀有气体的贡献。

关键词: 川东北, 陆相储层, 天然气成因, 碳同位素, 氢同位素, 稀有气体同位素

Abstract: The origin of natural gas in terrestrial reservoirs of Yuanba and Heba regions is investigated by analyzing the geochemical characteristics of natural gases and surveying the regional background of petroleum geology in the northeastern Sichuan Basin, China. Results show that: 1) In Yuanba region, natural gases from the Jurassic clastic rock reservoirs contain high levels of heavy hydrocarbon gases. The δ¹³C and δD values of methane respectively range from -42.2‰ to -34.4‰ and -208‰ to -168‰, whereas the δ¹³C values of ethane range from -31.4‰ to -21.4‰ in most gas samples. There is a strong correlation between the δ¹³C and δD values of methane in gas samples tested, and the gases are mainly originated from terrestrial source rocks of the Jurassic Ziliujing and Qianfoya Formation. Differently, natural gases from the Xujiahe Formation contain low levels of heavy hydrocarbon gases; the δ¹³C and δD values of methane in natural gas samples respectively range from -31.7‰ to -29.2‰ and -170‰ to -148‰, whereas the δ¹³C values of ethane range from -27.7‰ to -26.5‰. The gases are mainly originated from high-to-over-maturity humic terrestrial source rocks of the Upper Triassic Xujiahe Formation. The origin of natural gases is mainly controlled by the development of terrestrial source rocks and their maturity. 2) In Heba region, natural gases from the terrestrial reservoirs contain varying levels of heavy hydrocarbon gases. The δ¹³C values of methane are mostly greater than -32.0‰ and the corresponding δD values widely range from -186‰ to -122‰; the δ¹³C values of ethane range from -33.2‰ to -29.6‰. There is a poor correlation between the δ¹³C and δD values of methane in gas samples. The δ¹³C values of methane and ethane are reversed in a few cases, suggesting the complex origin of the gases that include those from terrestrial source rocks of the Xujiahe Formation and marine source rocks, as well as mixed gases from the above two origins. The development of marine and terrestrial source rocks as well as fractures of various levels is the main factor that controls the origin of natural gases in this region. 3) The δ¹³C values of carbon dioxide in natural gas samples are mostly less than -12‰, indicating that the gases are mainly generated through organic matter decomposition. Noble gas isotopic ratios of helium (³He/⁴He, 0.003 3R_a~0.018 1R_a) are distributed in the range of values for deep crust or radiogenic decay, demonstrating a lack of mantle-derived noble gas in the samples tested.

Key words: northeastern Sichuan Basin, terrestrial reservoir, natural gas genesis, carbon isotope, hydrogen isotope, noble gas isotope

中图分类号:

TE112.111

王万春, 张晓宝, 刘若冰, 罗厚勇, 王国仓. 川东北元坝与河坝地区陆相储层天然气成因[J]. 石油学报, 2014, 35(1): 26-36.

Wang Wanchun, Zhang Xiaobao, Liu Ruobing, Luo Houyong, Wang Guocang. Origin of natural gas in terrestrial reservoirs in Yuanba and Heba regions in northeastern Sichuan Basin, China[J]. ACTA PETROLEI SINICA, 2014, 35(1): 26-36.

参考文献

[1] 马永生. 四川盆地普光超大型气田的形成机制[J].石油学报, 2007, 28(2):9-14.
Ma Yongsheng.Generation mechanism of Puguang Gas Field in Sichuan Basin[J].Acta Petrolei Sinica, 2007, 28(2):9-14.
[2] 马永生, 蔡勋育, 赵培荣, 等.四川盆地大中型天然气田分布特征与勘探方向[J].石油学报, 2010, 31(3):347-354.
Ma Yongsheng, Cai Xunyu, Zhao Peirong, et al.Distribution and further exploration of the large-medium sized gas fields in Sichuan Basin[J].Acta Petrolei Sinica, 2010, 31(3):347-354.

[3] 刘若冰, 郭彤楼, 邵明莉.川东北元坝地区中浅层天然气气源及成因类型[J].天然气工业, 2011, 31(6):34-38.
Liu Ruobing, Guo Tonglou, Shao Mingli.Sources and genetic types of gas in the middle-shallow strata of the Yuanba area, northeastern Sichuan Basin[J].Natural Gas Industry, 2011, 31(6):34-38.
[4] 盘昌林, 刘树根, 马永生, 等.川东北地区中浅层天然气勘探潜力[J].油气地质与采收率, 2011, 18(5):9-13.
Pan Changlin, Liu Shugen, Ma Yongsheng, et al.Exploration potential analysis of natural gas in middle-shallow formations, northeastern Sichuan Basin[J].Petroleum Geology and Recovery Efficiency, 2011, 18(5):9-13.
[5] Dai Jinxing, Li Jian, Luo Xia, et al.Stable carbon isotope compositions and source rock geochemistry of the giant gas accumulations in the Ordos Basin, China[J].Organic Geochemistry, 2005, 36(12):1617-1635.

[6] Dai Jinxing, Ni Yunyan, Zou Caineng, et al.Stable carbon isotopes of alkane gases from the Xujiahe coal measures and implication for gas-source correlation in the Sichuan Basin, SW China[J].Organic Geochemistry, 2009, 40(5):638-646.

[7] 朱光有, 张水昌, 梁英波, 等.硫酸盐热化学还原反应对烃类的蚀变作用[J].石油学报, 2005, 26(5):48-52.
Zhu Guangyou, Zhang Shuichang, Liang Yingbo, et al.Alteration of thermochemical sulfate reduction to hydrocarbons[J].Acta Petrolei Sinica, 2005, 26(5):48-52.
[8] 王万春, 刘文汇, 刘全有.浅层混源天然气判识的碳同位素地球化学分析[J].天然气地球科学, 2003, 14(6):469-473.
Wang Wanchun, Liu Wenhui, Liu Quanyou.Analyses of the carbon isotopic geochemistry of the mix-sourced shallow reservoir natural gas identification[J].Natural Gas Geoscience, 2003, 14(6):469-473.
[9] 唐永, 梅廉夫, 肖安成, 等.川东北宣汉—达县地区晚中生代—新生代构造应力场转化及其油气意义[J].石油学报, 2013, 34(1):59-70.
Tang Yong, Mei Lianfu, Xiao Ancheng, et al., Transition of tectonic stress field and hydrocarbon significance of the Late Mesozoic-Cenozoic in Xuanhan-Daxian region, northeastern Sichuan Basin[J].Acta Petrolei Sinica, 2013, 34(1):59-70.
[10] 段金宝, 黄仁春, 程胜辉, 等.川东北元坝地区长兴期—飞仙关期碳酸盐岩台地沉积体系及演化[J].成都理工大学学报:自然科学版, 2008, 35(6):663-668.
Duan Jinbao, Huang Renchun, Cheng Shenghui, et al.Depositional system and the evolution of carbonate rock platform of Changxing-Feixianguan period in Yuanba area of northeast Sichuan, China[J].Journal of Chendu University of Technology:Science & Technology Edition, 2008, 35(6):663-668.
[11] 秦建中, 孟庆强, 付小东.川东北地区海相碳酸盐岩三期成烃成藏过程[J].石油勘探与开发, 2008, 35(5):548-556.
Qin Jianzhong, Meng Qingqiang, Fu Xiaodong.Three hydrocarbon generation and accumulation processes of marine carbonate rocks in northeastern Sichuan Basin, China[J].Petroleum Exploration and Development, 2008, 35(5):548-556.
[12] 张水昌, 朱光有.四川盆地海相天然气富集成藏特征与勘探潜力[J].石油学报, 2006, 27(5):1-8.
Zhang Shuichang, Zhu Guangyou.Gas accumulation characteristics and exploration potential of marine sediments in Sichuan Basin[J].Acta Petrolei Sinica, 2006, 27(5):1-8.
[13] Ma Yongsheng, Zhang Shuichang, Guo Tonglu, et al.Petroleum geology of the Puguang sour gas field in the Sichuan Basin, SW China[J]. Marine and Petroleum Geology, 2008, 25(4/5):357-370.
[14] 王杰, 秦建中, 刘文汇, 等.川东北元坝地区中生代构造与动态热演化史——磷灰石、锆石(U-Th)/He定年分析[J].石油实验地质, 2012, 34(1):19-24.
Wang Jie, Qin Jianzhong, Liu Wenhui, et al.Mesozoic tectonics and dynamic thermal history in Yuanba area of northeastern Sichuan Basin:application of (U-Th)/He dating of apatite and zircon[J].Petroleum Geology and Experiment, 2012, 34(1):19-24.
[15] 印峰, 刘若冰, 王威, 等.四川盆地元坝气田须家河组致密砂岩气地球化学特征及气源分析[J].天然气地球科学, 2013, 24(3):621-627.
Yin Feng, Liu Ruobing, Wang Wei, et al.Geochemical characters of the tight sandstone gas from Xujiahe Formation in Yuanba gas field and its gas Geosource[J].Natural Gas Geoscience, 2013, 24(3):621-627.
[16] 戴建全.川东北元坝地区长兴组-飞仙关组气藏勘探潜力评价[J].成都理工大学学报:自然科学版, 2010, 37(4):419-423.
Dai Jianquan.Exploration potential evaluation of the Changxing-Feixianguan Formation gas pool in Yuanba block of Northeast Sichuan, China[J].Journal of Chengdu University of Technology:Science & Technology Edition, 2010, 37(4):419-423.
[17] 腾格尔, 秦建中, 付小东, 等.川东北地区上二叠统吴家坪组烃源岩评价[J].古地理学报, 2010, 12(3):334-345.
Tenger, Qin Jianzhong, Fu Xiaodong, et al.Hydrocarbon source rocks evaluation of the Upper Permian Wujiaping Formation in northeastern Sichuan area[J].Journal of Palaeogeography, 2010, 12(3):334-345.
[18] 朱扬明, 王积宝, 郝芳, 等.川东宣汉地区天然气地球化学特征及成因[J].地质科学, 2008, 43(3):518-532.
Zhu Yangming, Wang Jibao, Hao Fang, et al.Geochemical characteristics and origin of natural gases from Xuanhan area, eastern Sichuan[J].Chinese Journal of Geology, 2008, 43(3):518-532.
[19] 张元春, 邹华耀, 李平平, 等.川东北元坝地区长兴组流体包裹体特征及油气充注史[J].新疆石油地质, 2010, 31(3):250-251.
Zhang Yuanchun, Zou Huayao, Li Pingping, et al.Fluid inclusion feature and hydrocarbon charge history of Changxing Formation in Yuanba Area in northeastern Sichuan Basin[J].Xinjiang Petroleum Geology, 2010, 31(3):250-251.
[20] Ye Xianren, Tao Mingxin, Yu Cuanao, et al.Helium and neon isotopic compositions in the ophiolites from the Yarlung Zangbo River, Southwestern China:the information from deep mantle[J].Science in China Series D:Earth Sciences, 2007, 50(6):801-812.

[21] Bernard B B, Brooks J M, Sackett W M.Light hydrocarbons in recent Texas continental shelf and slope sediments[J].Journal of Geophysics Research, 1978, 83(C8):4053-4061.
[22] Faber E, Stahl W.Geochemical surface exploration for hydrocarbons in the North Sea[J].AAPG Bulletin, 1984, 68(3):363-386.
[23] Whiticar M J.A geochemical perspective of natural gas and atmospheric methane[J].Organic Geochemistry, 1989, 16:531-547.
[24] James A T.Correlation of natural gas by use of carbon isotopic distribution between hydrocarbon components[J].AAPG Bulletin, 1983, 67(7):1176-1191.
[25] Berner U, Faber E.Empirical carbon isotope/maturity relationships for gases from algal kerogen and terrigenous organic matter, based on dry, open-system pyrolysis[J].Organic Geochemistry, 1996, 24(10/11):947-955.
[26] 王顺玉, 戴鸿鸣, 王海清, 等.大巴山、米仓山南缘烃源岩特征研究[J].天然气地球科学, 2000, 11(4/5):4-16.
Wang Shunyu, Dai Hongming, Wang Haiqing, et al.Source rock feature of the south of the Dabashan and Mi-Cangshan[J].Natural Gas Geoscience, 2000, 11(4/5):4-16.
[27] 李智武, 刘树根, 罗玉宏, 等.南大巴山前陆冲断带构造样式及变形机制分析[J].大地构造与成矿学, 2006, 30(3):294-304.
Li Zhiwu, Liu Shugen, Luo Yuhong, et al.Structural style and deformational mechanism of southern Dabashan foreland fold-thrust belt in central China[J].Geotectonica et Metallogenia, 2006, 30(3):294-304.
[28] 沈平, 徐永昌.中国陆相成因天然气同位素组成特征[J].地球化学, 1991(2):144-152.
Shen Ping, Xu Yongchang.The isotopic composition of natural gases from continental sediments in China[J].Geochimica, 1991(2):144-152.
[29] Liu Quanyou, Dai jinxing, Li Jian, et al.Hydrogen isotope composition of natural gases from the Tarim Basin and its indication of depositional environments of the source rocks[J].Science in China Series D:Earth Sciences, 2008, 51(2):300-311.

[30] Schoell M.The hydrogen and carbon isotopic composition of methane from natural gases of various origins[J].Geochimica et Cosmochimica Acta, 1980, 44(5):649-661.

[31] 王万春.天然气、原油和干酪根的氢同位素地球化学特征[J].沉积学报, 1996, 14(增):131-135.
Wang Wanchun.Geochemical characteristics of hydrogen isotopic compositions of natural gas, oil and kerogen[J].Acta Sedimentologica Sinica, 1996, 14(Supp.):131-135.
[32] 戴金星.我国有机烷烃气的氢同位素的若干特征[J].石油勘探与开发, 1990, 17(5):27-32.
Dai Jinxing.Characteristics of hydrogen isotopes of paraffinic gas in China[J]. Petroleum Exploration and Development, 1990, 17(5):27-32.
[33] 王晓锋, 刘文汇, 徐永昌, 等.塔里木盆地天然气碳、氢同位素地球化学特征[J].石油勘探与开发, 2005, 32(3):55-58.
Wang Xiaofeng, Liu Wenhui, Xu Yongchang, et al.Natural gas carbon and hydrogen isotopic compositions in Tarim Basin, NW China[J].Petroleum Exploration and Development, 2005, 32(3):55-58.
[34] 钱志浩, 曹寅, 张美珍.川东北天然气单体烃氢同位素组成特征[J].海相油气地质, 2008, 13(2):17-21.
Qian Zhihao, Cao Yin, Zhang Meizhen.Feature of hydrogen isotopic composition of individual hydrocarbon in natural methane gas from northeast part of Sichuan[J].Marine Origin Petroleum Geology, 2008, 13(2):17-21.
[35] 汪泽成, 邹才能, 陶士振, 等.大巴山前陆盆地形成及演化与油气勘探潜力分析[J].石油学报, 2004, 25(6):23-28.
Wang Zecheng, Zou Caineng, Tao Shizhen, et al.Analysis on tectonic evolution and exploration potential in Dabashan foreland basin[J].Acta Petrolei Sinica, 2004, 25(6):23-28.
[36] 张水昌, 朱光有, 何坤.硫酸盐热化学还原作用对原油裂解成气和碳酸盐岩储层改造的影响及作用机制[J].岩石学报, 2011, 27(3):809-826.
Zhang Shuichang, Zhu Guangyou, He Kun.The effects of thermochemical sulfate reduction on occurrence of oil-cracking gas and reformation of deep carbonate reservoir and the interaction mechanisms[J].Acta Petrologica Sinica, 2011, 27(3):809-826.
[37] 刚文哲, 高岗, 郝石生, 等.论乙烷碳同位素在天然气成因类型研究中的应用[J].石油实验地质, 1997, 19(2):164-167.
Gang Wenzhe, Gao Gang, Hao Shisheng, et al.Carbon isotope of ethane applied in the analyses of genetic types of natural gas[J].Experimental Petroleum Geology, 1997, 19(2):164-167.
[38] Berner U, Faber E, Scheeder G, et al.Primary cracking of algal and land plant kerogens:kinetic models of isotope variations in methane, ethane and propane[J].Chemical Geology, 1995, 126:233-245.

[39] Huang Difan, Liu Baoquan, Wang Tingdong, et al.Genetic type and maturity of Lower Paleozoic marine hydrocarbon gases in the eastern Tarim Basin[J].Chemical Geology, 1999, 162(1):65-77.

[40] Chen Jianfa, Xu Yongchang, Huang Difan.Geochemical characteristics and origin of natural gas in Tarim Basin, China[J].AAPG Bulletin, 2000, 84(5):591-606.
[41] 秦建中, 付小东, 腾格尔.川东北宣汉-达县地区三叠-志留系海相优质烃源层评价[J].石油实验地质, 2008, 30(4):367-374.
Qin Jianzhong, Fu Xiaodong, Tenger.Evolution of the excellent Triassic to Silurian marine hydrocarbon source rocks in Xuanhan-Daxian area of northeast Sichuan Basin[J].Petroleum Geology and Experiment, 2008, 30(4):367-374.
[42] Prinzhofer A, Dos Santos Neto E V, Battani A.Coupled use of carbon isotopes and noble gas isotopes in the Potiguar Basin (Brazil):Fluids migration and mantle influence[J].Marine and Petroleum Geology, 2010, 27(6):1273-1284.

[43] Dai Jinxing, Song Yan, Dai Chunseng, et al.Geochemistry and accumulations of carbon dioxide gases in China[J].AAPG Bulletin, 1996, 80:1615-1626.
[44] Dai Jinxing, Yang Shufeng, Chen Hanlin, et al.Geochemistry and occurrence of inorganic gas accumulations in Chinese sedimentary basins[J].Organic Geochemistry, 2005, 36(12):1664-1688.

[45] Wycherley H, Fleet A, Shaw H.Some observations on the origins of large volumes of carbon dioxide accumulations in sedimentary basins[J].Marine and Petroleum Geology, 1999, 16(6):489-494.

[46] Machel H G.Bacterial and thermochemical sulfate reduction in diagenetic settings?old and new insights[J].Sedimentary Geology, 2001, 140(1):143-175.
[47] Hulston J R, Hilton D R, Kaplan I R.Helium and carbon isotope systematics of natural gases from Taranaki Basin, New Zealand[J].Applied Geochemistry, 2001, 16(4):419-436.

[48] Pan Changchun, Yu Linping, Liu Jinzhong, et al.Chemical and carbon isotopic fractionations of gaseous hydrocarhons during abiogenic oxidation[J].Earth and Planetary Science Letters, 2006, 246:70-89.

[49] Hofmann A W.Chemical differentiation of the Earth:the relationship between mantle, continental crust, and oceanic crust[J].Earth and Planetary Science Letters, 1988, 90(3):297-314.

[50] Ozima M, Zahnle K.Mantle degassing and atmospheric evolution:Noble gas view[J].Geochemical Journal, 1993, 27(4/5):185-200.
[51] Ballentine C J, O’Nions R K, Oxburgh E R, et al.Rare-gas constraints on hydrocarbon accumulation, crustal degassing and groundwater-flow in the Pannonian Basin[J].Earth and Planetary Science Letters, 1991, 105(1/3):229-246.

[52] Liu Wenhui, Xu Yongchang.Significance of helium and argon isotopic composition in natural gas[J].Chinese Science Bulletin, 1993, 38(9):818-821.
[53] 张殿伟, 刘文汇, 郑建京, 等.塔中地区天然气氦、氩同位素地球化学特征[J].石油勘探与开发, 2005, 32(6):38-41.
Zhang Dianwei, Liu Wenhui, Zhen Jianjing, et al.Helium and argon isotopic compositions of natural gases in the Tazhong area, Tarim Basin[J].Petroleum Exploration and Development, 2005, 32(6):38-41.
[54] Ballentine C J, Mazurek M, Gautschi A.Thermal constraints on crustal rare gas release and migration:Evidence from Alpine fluid inclusions[J].Geochimica et Cosmochimica Acta, 1994, 58(20):4333-4348.

[55] Littke R, Krooss B M, Idiz E F.et al.Molecular nitrogen in natural gas accumulations:generation from sedimentary organic matter at high temperature s[J].AAPG Bulletin, 1995, 79(3):410-430.
[56] Krouse H R, Viau C A, Eliuk L S.et al.Chemical and isotopic evidence of thermochemical sulphate reduction by light hydrocarbon gases in deep carbonate reservoirs[J].Nature, 1988, 333(6172):415-419.
[57] 戴金星, 宋岩, 程坤芳, 等.中国含油气盆地有机烷烃气碳同位素特征[J].石油学报, 1993, 14(2):23-31.
Dai Jinxing, Song Yan, Cheng Kunfang, et al.Characteristics of carbon isotopes of organic alkane gases in petroliferous basins of China[J].Acta Petrolei Sinica, 1993, 14(2):23-31.

川东北元坝与河坝地区陆相储层天然气成因

Origin of natural gas in terrestrial reservoirs in Yuanba and Heba regions in northeastern Sichuan Basin, China

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	罗胜元, 陈孝红, 刘安, 李海, 孙冲. 中扬子宜昌地区下寒武统水井沱组页岩现场解吸气特征及地质意义[J]. 石油学报, 2019, 40(8): 941-955.
[2]	杨海风, 王德英, 高雁飞, 王军, 李正宇, 钱赓. 渤海湾盆地盆缘洼陷新近系天然气成因与油气差异富集机理——以黄河口凹陷东洼为例[J]. 石油学报, 2019, 40(5): 509-518.
[3]	陈建平, 魏军, 倪云燕, 陈建军, 邓春萍, 田多文, 胡健, 黄振凯, 张蒂嘉, 韩永科. 酒西坳陷原油地球化学特征与成熟度分类[J]. 石油学报, 2018, 39(5): 491-503.
[4]	刘景东, 蒋有录, 张园园, 徐田武, 慕小水, 万涛. 东濮凹陷古近系致密砂岩气成因与充注差异[J]. 石油学报, 2017, 38(9): 1010-1020.
[5]	庄新兵, 顾忆, 邵志兵, 尤东华, 丁勇, 万旸璐. 塔里木盆地地温场对油气成藏过程的控制作用——以古城墟隆起为例[J]. 石油学报, 2017, 38(5): 502-511.
[6]	肖飞, 汪建国, 吴和源, 王培玺, 赵宗举, 田建章, 姜在兴, 宋春刚, 田然, 郭增强. 华北地区中北部寒武系层序地层格架[J]. 石油学报, 2017, 38(10): 1144-1157,1167.
[7]	国建英, 付立新, 肖鑫, 王东良, 李剑, 张璐, 肖敦清, 谢增业, 柳晓萱, 王金友. 黄骅坳陷大港探区高含H₂S天然气地球化学特征及成因[J]. 石油学报, 2016, 37(S2): 31-38.
[8]	李军, 赵靖舟, 王大兴, 孙六一, 任军峰, 武春英, 吴伟涛, 赵子龙, 曲付涛. 鄂尔多斯盆地中央古隆起东侧奥陶系中组合天然气成因与来源[J]. 石油学报, 2016, 37(7): 821-831.
[9]	秦华, 范小军, 刘明, 郝景宇, 梁波. 焦石坝地区龙马溪组页岩解吸气地球化学特征及地质意义[J]. 石油学报, 2016, 37(7): 846-854.
[10]	宋振响, 顾忆, 路清华, 周卓明, 李贶. 松辽盆地梨树断陷天然气成因类型及勘探方向[J]. 石油学报, 2016, 37(5): 622-630.
[11]	陈建平, 王绪龙, 邓春萍, 赵喆, 倪云燕, 孙永革, 杨海波, 王汇彤, 梁狄刚. 准噶尔盆地南缘油气生成与分布规律——典型油藏油源解剖与原油分布规律[J]. 石油学报, 2016, 37(4): 415-429.
[12]	王自翔, 王永莉, 吴保祥, 孙则朋, 汪亘, 徐亮, 朱深圳, 孙丽娜. 川西北低成熟沥青产气特征及生烃动力学应用[J]. 石油学报, 2016, 37(3): 339-347.
[13]	吴超, 陈小锋, 王磊. 钻井液密度窗口随钻预测理论及其工程应用[J]. 石油学报, 2016, 37(3): 399-405.
[14]	陈建平, 王绪龙, 邓春萍, 赵喆, 倪云燕, 孙永革, 杨海波, 王汇彤, 梁狄刚. 准噶尔盆地南缘油气生成与分布规律——典型类型原油油源对比[J]. 石油学报, 2016, 37(2): 160-171.
[15]	吴伟, 罗超, 张鉴, 刘文平. 油型气乙烷碳同位素演化规律与成因[J]. 石油学报, 2016, 37(12): 1463-1471.