油气储层氧敏性概念、机理与意义

doi:10.7623/syxb202102004

石油学报 ›› 2021, Vol. 42 ›› Issue (2): 186-197.DOI: 10.7623/syxb202102004

油气储层氧敏性概念、机理与意义

游利军, 康毅力, 周洋, 陈强, 程秋洋, 徐洁明, 陈杨

西南石油大学油气藏地质及开发工程国家重点实验室四川成都 610500

收稿日期:2020-02-25 修回日期:2020-12-09 出版日期:2021-02-25 发布日期:2021-02-07
通讯作者: 游利军,男,1976年10月生,2000年获西南石油学院学士学位,2006年获西南石油大学博士学位,现为西南石油大学教授、博士生导师,主要从事储层保护、非常规油气、岩石物理研究与教学工作。
作者简介:游利军,男,1976年10月生,2000年获西南石油学院学士学位,2006年获西南石油大学博士学位,现为西南石油大学教授、博士生导师,主要从事储层保护、非常规油气、岩石物理研究与教学工作。Email:youlj0379@126.com
基金资助:
国家自然科学基金项目“富有机质页岩氧化致裂增渗加速气体传输机理研究”（No.51674209）、非常规油气层保护四川省青年科技创新研究团队项目“页岩气层氧化协同水力压裂减量增渗方法研究”（2021JDTD0017）和四川省科技创新苗子工程培育项目“富有机质页岩自吸氧化液动力学及扩大作用范围方法研究”（2020119）资助。

Concept,mechanism and significance of oxidation sensitivity of oil and gas reservoirs

You Lijun, Kang Yili, Zhou Yang, Chen Qiang, Cheng Qiuyang, Xu Jieming, Chen Yang

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Sichuan Chengdu 610500, China

Received:2020-02-25 Revised:2020-12-09 Online:2021-02-25 Published:2021-02-07

摘要/Abstract

摘要： 储层损害和流体敏感性等概念的提出使油气储层保护成为油气勘探与开发领域的重要研究方向，储层保护技术从系统工程理论出发，研究工程作业与地质对象的适应性问题，为油气田开发提供重要理论支持和技术保障。生烃层中形成的油气会发生滞留或短距离运移、初次运移和二次运移至储集层中，不仅多数油气仍然保留着还原性，而且也将储层岩石还原；源-储一体的非常规油气藏岩石富含有机质组分，且处于还原环境，而在钻完井液漏失、增产改造、注水等过程中大量氧化性流体可能进入油气储层，打破氧化-还原环境。鉴于此，提出了油气储层氧敏性的概念，明确了储层氧敏性的矿物组分与氧敏机理，并开展变氧化-还原电位流体驱替页岩岩心实验。研究结果表明，处于还原环境下油气储层易发生氧敏性，有机质和黄铁矿等还原性矿物组分氧化可改变岩石渗透率；油气储层氧敏性概念的提出为岩心保存、岩心流动实验提出了新要求，为储层损害机理诊断提供了新思路，助推了页岩“人工油气藏”氧化致裂增渗方法的提出。

关键词: 氧敏性, 氧敏矿物, 氧化-还原电位, 有机质, 页岩, 非常规油气

Abstract: With the proposing of the concepts of reservoir damage and fluid sensitivity, reservoir protection has become an important research direction in the field of oil and gas exploration and development. Based on the theory of system engineering, reservoir protection technology investigates the adaptability of engineering operations with geological objects, thus providing great theoretical and technical supports for the development of oil and gas field. Oil and gas formed in the hydrocarbon-generating layer will be retained or migrated a short distance, or migrated into the reservoir by primary migration and secondary migration. Most of oil and gas not only retain reducibility, but also cause the reduction reaction of reservoir rock. The unconventional oil and gas reservoir rocks featured with source-reservoir integration are rich in organic components and remain in a reducing environment. However, a large number of oxidizing fluids may enter the oil and gas reservoirs during the processes of drilling and completion fluid loss, reservoir stimulation, water injection, thus change the redox environment. In view of this, the authors propose the concept of oxidation sensitivity of oil and gas reservoirs, clarify the mineral compositions which are potential to oxidation sensitivity and the mechanism of reservoirs, and conduct an experiment on the displacement of shale cores by variable oxidation-reduction potential fluids. The research results show that oil and gas reservoirs are prone to oxidation sensitivity in a reducing environment. The oxidation of organic matter, pyrite and other reducing mineral components can change rock permeability. The concept of oxidation sensitivity provides new requirements for core preservation and core flow experiments, as well as new ideas for the analysis of reservoir damage mechanisms, and promotes the proposal of oxidation fracturing and permeability enhancing methods of "artificial oil and gas reservoirs" in shales.

Key words: oxidation sensitivity, oxidation sensitive minerals, redox potential, organic matter, shale, unconventional oil and gas

中图分类号:

TE258

游利军, 康毅力, 周洋, 陈强, 程秋洋, 徐洁明, 陈杨. 油气储层氧敏性概念、机理与意义[J]. 石油学报, 2021, 42(2): 186-197.

You Lijun, Kang Yili, Zhou Yang, Chen Qiang, Cheng Qiuyang, Xu Jieming, Chen Yang. Concept,mechanism and significance of oxidation sensitivity of oil and gas reservoirs[J]. Acta Petrolei Sinica, 2021, 42(2): 186-197.

参考文献

[1] JONES JR F O. Influence of chemical composition of water on clay blocking of permeability[J].Journal of Petroleum Technology,1964,16(4):441-446.
[2] THOMAS R D,WARD D C.Effect of overburden pressure and water saturation on gas permeability of tight sandstone cores[J].Journal of Petroleum Technology,1972,24(2):120-124.
[3] 康毅力,罗平亚,沈守文,等.粘土矿物产状和微结构对地层损害的影响[J].西南石油学院学报,1998,20(2):27-29.
KANG Yili,LUO Pingya,SHEN Shouwen,et al.Influence of clay minerals occurrences and microstructures on formation damage[J].Journal of Southwest Petroleum Institute,1998,20(2):27-29.
[4] 张浩,康毅力,李前贵,等.鄂尔多斯盆地北部致密砂岩气层粘土微结构与流体敏感性[J].钻井液与完井液,2005,22(6):22-25.
ZHANG Hao,KANG Yili,LI Qiangui,et al.Clay microstructure and fluid sensitivity of fine gas sands in the north of Ordos Basin[J].Drilling Fluid & Completion Fluid,2005,22(6):22-25.
[5] 康毅力,吴志均,汪建军,等.碱敏损害是塔里木盆地东河塘构造东河1井减产的主因[J].西南石油学院学报,1997,19(4):14-19.
KANG Yili,WU Zhijun,WANG Jianjun,et al.Alkali sensitivity damage:a critical factor causing drastic decrease in oil production for well Donghe 1 in Tarim Basin[J].Journal of Southwest Petroleum Institute,1997,19(4):14-19.
[6] 李洪建,李海涛,赵敏,等.矿化度梯度注水工艺新技术研究[J].石油钻采工艺,1998,20(6):82-85.
LI Hongjian,LI Haitao,ZHAO Min,et al.Research of new salinity gradient water injection technology[J].Oil Drilling & Production Technology,1998,20(6):82-85.
[7] 贾承造,郑民,张永峰.非常规油气地质学重要理论问题[J].石油学报,2014,35(1):1-10.
JIA Chengzao,ZHENG Min,ZHANG Yongfeng.Four important theoretical issues of unconventional petroleum geology[J].Acta Petrolei Sinica,2014,35(1):1-10.
[8] 邹才能,杨智,王红岩,等.岩进源找油"源找论四川盆地非常规陆相大型页岩油气田[J].地质学报,2019,93(7):1551-1562.
ZOU Caineng,YANG Zhi,WANG Hongyan,et al."Exploring petroleum inside source kitchen":Jurassic unconventional continental giant shale oil & gas field in Sichuan Basin,China[J].Acta Geologica Sinica,2019,93(7):1551-1562.
[9] 邹才能,董大忠,王玉满,等.中国页岩气特征、挑战及前景(二)[J].石油勘探与开发,2016,43(2):166-178.
ZOU Caineng,DONG Dazhong,WANG Yuman,et al.Shale gas in China:characteristics,challenges and prospects (II)[J].Petroleum Exploration and Development,2016,43(2):166-178.
[10] 游利军,杨鹏飞,崔佳,等.页岩气层氧化改造的可行性[J].油气地质与采收率,2017,24(6):79-85.
YOU Lijun,YANG Pengfei,CUI Jia,et al.Feasibility of oxidative stimulation in organic matter-rich shale gas reservoir[J].Petroleum Geology and Recovery Efficiency,2017,24(6):79-85.
[11] 许成元,闫霄鹏,康毅力,等.深层裂缝性储集层封堵层结构失稳机理与强化方法[J].石油勘探与开发,2020,47(2):399-408.
XU Chengyuan,YAN Xiaopeng,KANG Yili,et al.Structural failure mechanism and strengthening method of plugging zone in deep naturally fractured reservoirs[J].Petroleum Exploration and Development,2020,47(2):399-408.
[12] 康毅力,王凯成,许成元,等.深井超深井钻井堵漏材料高温老化性能评价[J].石油学报,2019,40(2):215-223.
KANG Yili,WANG Kaicheng,XU Chengyuan,et al.High-temperature aging property evaluation of lost circulation materials in deep and ultra-deep well drilling[J].Acta Petrolei Sinica,2019,40(2):215-223.
[13] 贾承造,庞雄奇,姜福杰.中国油气资源研究现状与发展方向[J].石油科学通报,2016,1(1):2-23.
JIA Chengzao,PANG Xiongqi,JIANG Fujie.Research status and development directions of hydrocarbon resources in China[J].Petroleum Science Bulletin,2016,1(1):2-23.
[14] BUTKOVSKYI A,FABER A H,WANG Yue,et al.Removal of organic compounds from shale gas flowback water[J].Water Research,2018,138:47-55.
[15] GREGORY K B,VIDIC R D,DZOMBAK D A.Water management challenges associated with the production of shale gas by hydraulic fracturing[J].Elements,2011,7(3):181-186.
[16] PHAN T T,VANKEUREN A N P,HAKALA J A.Role of water-rock interaction in the geochemical evolution of Marcellus Shale produced waters[J].International Journal of Coal Geology,2018,191:95-111.
[17] 辛建荣.缺氧事件及其地质意义[J].地质科技情报,1986,5(4):33-39.
XIN Jianrong.Anoxic events and their geological implications[J].Geological Science and Technology Information,1986,5(4):33-39.
[18] 腾格尔,刘文汇,徐永昌,等.缺氧环境及地球化学判识标志的探讨——以鄂尔多斯盆地为例[J].沉积学报,2004,22(2):365-372.
TONGER,LIU Wenhui,XU Yongchang,et al.The discussion on anoxic environments and its geochemical identifying indices[J].Acta Sedimentologica Sinica,2004,22(2):365-372.
[19] 焦方正.非常规油气之"非常规"再认识[J].石油勘探与开发,2019,46(5):803-810.
JIAO Fangzheng.Re-recognition of "unconventional" in unconventional oil and gas[J].Petroleum Exploration and Development,2019,46(5):803-810.
[20] 袁静,赵澄林.水介质的化学性质和流动方式对深部碎屑岩储层成岩作用的影响[J].石油大学学报:自然科学版,2000,24(1):60-63.
YUAN Jing,ZHAO Chenglin.Influence of chemistry of fluid and circulated convection current on diagenesis of petroclastic rock in deep formation[J].Journal of the University of Petroleum,China:Edition of Natural Science,2000,24(1):60-63.
[21] П.А.列夫苏诺夫,З.И.斯鲁茨柯耶.利用岩石的氧化还原电位,确定含油气层的界限[J].鲁国生,译.石油实验地质,1963(4):21-22.
П А Лев Сунов,,З И Слайцкая.Using the REDOX potential of the rock to dtermine the boundary of the oil-bearing gas layer[J].LU Guosheng Tans.Petroleum Geology & Experiment,1963(4):21-22.
[22] 易定红,王建功,石亚军,等.柴西狮子沟地区渐新统下干柴沟组上段膏盐岩沉积演化特征[J].天然气工业,2017,37(5):1-9.
YI Dinghong,WANG Jiangong,SHI Yajun,et al.Evolution characteristic of gypsum-salt rocks of the upper member of Oligocene Lower Ganchaigou Fm in the Shizigou area,western Qaidam Basin[J].Natural Gas Industry,2017,37(5):1-9.
[23] 王建功,张永庶,李翔,等.柴达木盆地西部渐新统纹理石沉积特征与原位成藏[J].石油学报,2020,41(8):940-959.
WANG Jiangong,ZHANG Yongshu,LI Xiang,et al.Sedimentary characteristics and in-situ accumulation of the Oligocene laminites in the western Qaidam Basin[J].Acta Petrolei Sinica,2020,41(8):940-959.
[24] 张霞,林春明,陈召佑.鄂尔多斯盆地镇泾区块上三叠统延长组砂岩中绿泥石矿物特征[J].地质学报,2011,85(10):1659-1671.
ZHANG Xia,LIN Chunming,CHEN Zhaoyou.Characteristics of chlorite minerals from upper Triassic Yanchang formation in the Zhenjing area,Ordos Basin[J].Acta Geologica Sinica,2011,85(10):1659-1671.
[25] 樊建明,王冲,屈雪峰,等.鄂尔多斯盆地致密油水平井注水吞吐开发实践——以延长组长7油层组为例[J].石油学报,2019,40(6):706-715.
FAN Jianming,WANG Chong,QU Xuefeng,et al.Development and practice of water flooding huff-puff in tight oil horizontal well,Ordos Basin:a case study of Yanchang Formation Chang 7 oil layer[J].Acta Petrolei Sinica,2019,40(6):706-715.
[26] 孙全力,孙晗森,贾趵,等.川西须家河组致密砂岩储层绿泥石成因及其与优质储层关系[J].石油与天然气地质,2012,33(5):751-757.
SUN Quanli,SUN Hansen,JIA Bao,et al.Genesis of chlorites and its relationship with high-quality reservoirs in the Xujiahe Formation tight sandstones,western Sichuan depression[J].Oil & Gas Geology,2012,33(5):751-757.
[27] 王正茂,廖广志,蒲万芬,等.注空气开发中地层原油氧化反应特征[J].石油学报,2018,39(3):314-319.
WANG Zhengmao,LIAO Guangzhi,PU Wanfen,et al.Oxidation reaction features of formation crude oil in air injection development[J].Acta Petrolei Sinica,2018,39(3):314-319.
[28] FRANCOIS R.A study on the regulation of the concentrations of some trace metals (Rb,Sr,Zn,Pb,Cu,V,Cr,Ni,Mn and Mo)in Saanich inlet sediments,British Columbia,Canada[J].Marine Geology,1988,83(1/4):285-308.
[29] YAN Fei,ZHANG Fangfu,BHANDARI N,et al.Adsorption and precipitation of scale inhibitors on shale formations[J].Journal of Petroleum Science and Engineering,2015,136:32-40.
[30] 岳梅,赵峰华,孙红福,等.煤系黄铁矿氧化溶解地球化学动力学研究[J].煤炭学报,2005,30(1):75-79.
YUE Mei,ZHAO Fenghua,SUN Hongfu,et al.The kinetics of oxidation reaction of pyrites from coal-bearing measure[J].Journal of China Coal Society,2005,30(1):75-79.
[31] 冯博,冯其明,卢毅屏.绿泥石与黄铁矿的异相凝聚机理[J].中南大学学报:自然科学版,2015,46(1):14-19.
FENG Bo,FENG Qiming,LU Yiping.Mechanism of hetero-aggregation of chlorite and pyrite[J].Journal of Central South University:Science and Technology,2015,46(1):14-19.
[32] CHERMAK J A,SCHREIBER M E.Mineralogy and trace element geochemistry of gas shales in the United States:environmental implications[J].International Journal of Coal Geology,2014,126:32-44.
[33] 常华进,储雪蕾,冯连君,等.氧化还原敏感微量元素对古海洋沉积环境的指示意义[J].地质论评,2009,55(1):91-99.
CHANG Huajin,CHU Xuelei,FENG Lianjun,et al.Redox sensitive trace elements as paleoenvironments proxies[J].Geological Review,2009,55(1):91-99.
[34] TISSOT B P,WELTE D H.Petroleum formation and occurrence[M].2nd ed.Berlin Heidelberg:Springer-Verlag,1984.
[35] 李娟,于炳松,郭峰.黔北地区下寒武统底部黑色页岩沉积环境条件与源区构造背景分析[J].沉积学报,2013,31(1):20-31.
LI Juan,YU Bingsong,GUO Feng.Depositional setting and tectonic background analysis on Lower Cambrian black shales in the North of Guizhou Province[J].Acta Sedimentologica Sinica,2013,31(1):20-31.
[36] 贾承造.论非常规油气对经典石油天然气地质学理论的突破及意义[J].石油勘探与开发,2017,44(1):1-11.
JIA Chengzao.Breakthrough and significance of unconventional oil and gas to classical petroleum geological theory[J].Petroleum Exploration and Development,2017,44(1):1-11.
[37] YEN T F,WEN C S.Electrolytic recovery from bituminous materials:US,4045313[P].1977-08-03.
[38] 杨秋水,陆绍信,王廷芬.黄县油页岩氧化制取有机酸的探索[J].石油学报(石油加工),1986,2(3):89-98.
YANG Qiushui,LU Shaoxin,WANG Tingfen.Investigation on oxidation of Huangxian oil shale for producing organic acids[J].Acta Petrolei Sinica (Petroleum Processing Section),1986,2(3):89-98.
[39] 豆联栋.富有机质页岩储层的氧敏性及实验评价方法研究[D].成都:西南石油大学,2019.
DOU Liandong.Study on oxygen sensitivity and experimental evaluation method of organic shale reservoirs[D].Chengdu:Southwest Petroleum University,2019.
[40] 周洋.富有机质页岩氧化增渗作用评价实验研究[D].成都:西南石油大学,2020.
ZHOU Yang.Experimental study on evaluation of oxidative stimulation of organic-rich shale[D].Chengdu:Southwest Petroleum University,2020.
[41] YOU Lijun,ZHOU Yang,KANG Yili,et al.Experimental evaluation of oxidation sensitivity in organic-rich shale reservoir[J].Journal of Petroleum Science and Engineering,2020,192:107-230.
[42] 关小旭.川东龙马溪组页岩储层损害机理与控制方法研究[D].成都:成都理工大学,2016.
GUAN Xiaoxu.Study of the mechanism and control methods of formation damage for Longmaxi shale formation in eastern Sichuan[D].Chengdu:Chengdu University of Technology,2016.
[43] LOUCKS R G,REED R M,RUPPEL S C,et al.Morphology,genesis,and distribution of nanometer-scale pores in siliceous mudstones of the Mississippian Barnett Shale[J].Journal of Sedimentary Research,2009,79(12):848-861.
[44] JEW A D,DUSTIN M K,HARRISON A L,et al.Impact of organics and carbonates on the oxidation and precipitation of iron during hydraulic fracturing of shale[J].Energy & Fuels,2017,31(4):3643-3658.
[45] SIMATE G S,NDLOVU S.Acid mine drainage:challenges and opportunities[J].Journal of Environmental Chemical Engineering,2014,2(3):1785-1803.
[46] ZOLFAGHARI A,DEHGHANPOUR H,NOEL M,et al.Laboratory and field analysis of flowback water from gas shales[J].Journal of Unconventional Oil and Gas Resources,2016,14:113-127.
[47] ZHANG Lifu,TICE M,HASCAKIR B.A laboratory study of the impact of reinjecting flowback fluids on formation damage in the Marcellus Shale[J].SPE Journal,2020,25(2):1-12.
[48] 游利军,康毅力,陈强,等.氧化爆裂提高页岩气采收率的前景[J].天然气工业,2017,37(5):53-61.
YOU Lijun,KANG Yili,CHEN Qiang,et al.Prospect of shale gas recovery enhancement by oxidation-induced rock burst[J].Natural Gas Industry,2017,37(5):53-61.
[49] 张小龙,黄勇,熊涛,等.川南地区五峰-龙马溪组页岩沉积环境及风化作用对页岩含气性指标的影响[J].兰州大学学报:自然科学版,2016,52(2):161-166.
ZHANG Xiaolong,HUANG Yong,XIONG Tao,et al.Depositional environment of Wufeng-Longmaxi formation shale in southern Sichuan Basin and effect of the weathering on shale gas index[J].Journal of Lanzhou University:Natural Science,2016,52(2):161-166.
[50] YOU Lijun,CHEN Qiang,KANG Yili,et al.Evaluation of formation damage using microstructure fractal in shale reservoirs[J].Fractals,2015,23(1):1540008.
[51] 游利军,周洋,康毅力,等.氧化性入井液对富有机质页岩渗透率的影响[J].油气藏评价与开发,2020,10(1):56-63.
YOU Lijun,ZHOU Yang,KANG Yili,et al.Effect of oxidizing working fluid on permeability of organic-rich shale[J].Reservoir Evaluation and Development,2020,10(1):56-63.
[52] 邹才能,丁云宏,卢拥军,等."人工油气藏"理论、技术及实践[J].石油勘探与开发,2017,44(1):144-154.
ZOU Caineng,DING Yunhong,LU Yongjun,et al.Concept,technology and practice of "man-made reservoirs" development[J].Petroleum Exploration and Development,2017,44(1):144-154.
[53] CHEN Qiang,KANG Yili,YOU Lijun,et al.Change in composition and pore structure of Longmaxi black shale during oxidative dissolution[J].International Journal of Coal Geology,2017,172:95-111.
[54] CHEN Qiang,YOU Lijun,KANG Yili,et al.Gypsum-crystallization-induced fracturing during shale-fluid reactions and application for shale stimulation[J].Energy & Fuels,2018,32(10):10367-10381.
[55] LI Jing,ZHOU Shixin,LI Yuanju,et al.Effect of organic matter on pore structure of mature lacustrine organic-rich shale:a case study of the Triassic Yanchang shale,Ordos Basin,China[J].Fuel,2016,185:421-431.
[56] 李继岩,王永诗,刘传虎,等.热液流体活动及其对碳酸盐岩储集层改造定量评价——以渤海湾盆地东营凹陷西部下古生界为例[J].石油勘探与开发,2016,43(3):359-366.
LI Jiyan,WANG Yongshi,LIU Chuanhu,et al.Hydrothermal fluid activity and the quantitative evaluation of its impact on carbonate reservoirs:a case study of the Lower Paleozoic in the west of Dongying Sag,Bohai Bay Basin,East China[J].Petroleum Exploration and Development,2016,43(3):359-366.
[57] 游利军,康毅力.热处理对致密岩石物理性质的影响[J].地球物理学进展,2009,24(5):1850-1854.
YOU Lijun,KANG Yili.Effects of thermal treatment on physical property of tight rocks[J].Progress in Geophysics,2009,24(5):1850-1854.
[58] YOU Lijun,CHENG Qiuyang,KANG Yili,et al.Imbibition of oxidative fluid into organic-rich shale:implication for oxidizing stimulation[J].Energy & Fuels,2018,32(10):10457-10468.
[59] 康毅力,田键,罗平亚,等.致密油藏提高采收率技术瓶颈与发展策略[J].石油学报,2020,41(4):467-477.
KANG Yili,TIAN Jian,LUO Pingya,et al.Technical bottlenecks and development strategies of enhancing recovery for tight oil reservoirs[J].Acta Petrolei Sinica,2020,41(4):467-477.

油气储层氧敏性概念、机理与意义

Concept,mechanism and significance of oxidation sensitivity of oil and gas reservoirs

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	金之钧, 王冠平, 刘光祥, 高波, 刘全有, 王红亮, 梁新平, 王濡岳. 中国陆相页岩油研究进展与关键科学问题[J]. 石油学报, 2021, 42(7): 821-835.
[2]	李国欣, 吴志宇, 李桢, 陈强, 鲜成刚, 刘合. 陆相源内非常规石油甜点优选与水平井立体开发技术实践 ——以鄂尔多斯盆地延长组7段为例[J]. 石油学报, 2021, 42(6): 736-750.
[3]	付锁堂, 金之钧, 付金华, 李士祥, 杨伟伟. 鄂尔多斯盆地延长组7段从致密油到页岩油认识的转变及勘探开发意义[J]. 石油学报, 2021, 42(5): 561-569.
[4]	糜利栋. 基于产气剖面的页岩气离散裂缝网络反演方法[J]. 石油学报, 2021, 42(4): 481-491.
[5]	张建国, 姜在兴, 刘立安, 袁方, 冯路尧, 李长昇. 渤海湾盆地沾化凹陷沙河街组三段下亚段细粒沉积岩岩相特征与沉积演化[J]. 石油学报, 2021, 42(3): 293-306.
[6]	赵贤正, 蒲秀刚, 周立宏, 金凤鸣, 韩国猛, 时战楠, 韩文中, 丁娱娇, 张伟, 王国娜, 刘学伟, 汪虎. 深盆湖相区页岩油富集理论、勘探技术及前景——以渤海湾盆地黄骅坳陷古近系为例[J]. 石油学报, 2021, 42(2): 143-162.
[7]	何骁, 吴建发, 雍锐, 赵圣贤, 周小金, 张洞君, 张德良, 钟成旭. 四川盆地长宁—威远区块海相页岩气田成藏条件及勘探开发关键技术[J]. 石油学报, 2021, 42(2): 259-272.
[8]	匡立春, 侯连华, 杨智, 吴松涛. 陆相页岩油储层评价关键参数及方法[J]. 石油学报, 2021, 42(1): 1-14.
[9]	梁兴, 徐政语, 张介辉, 张朝, 李兆丰, 蒋佩, 蒋立伟, 朱斗星, 刘臣. 浅层页岩气高效勘探开发关键技术——以昭通国家级页岩气示范区太阳背斜区为例[J]. 石油学报, 2020, 41(9): 1033-1048.
[10]	陈浩, 周涛, 樊怀才, 张鉴, 杨胜来. 页岩储层人工裂缝岩样制备方法及应力敏感性[J]. 石油学报, 2020, 41(9): 1117-1126.
[11]	周立宏, 韩国猛, 马建英, 陈长伟, 杨飞, 张莉华, 周可佳, 陈双清, 杨帆, 董越崎, 周静. 歧口凹陷西南缘沙河街组一段下亚段古环境特征与沉积模式[J]. 石油学报, 2020, 41(8): 903-917.
[12]	李俊乾, 卢双舫, 张鹏飞, 李文镖, 荆铁亚, 冯文俊. 页岩基质孔隙水定量表征及微观赋存机制[J]. 石油学报, 2020, 41(8): 979-990.
[13]	付锁堂, 付金华, 牛小兵, 李士祥, 吴志宇, 周新平, 刘江艳. 庆城油田成藏条件及勘探开发关键技术[J]. 石油学报, 2020, 41(7): 777-795.
[14]	赵贤正, 周立宏, 蒲秀刚, 时战楠, 韩国猛, 吴佳朋, 韩文中, 张伟, 高欢欢, 马建英, 汪虎. 歧口凹陷歧北次凹沙河街组三段页岩油地质特征与勘探突破[J]. 石油学报, 2020, 41(6): 643-657.
[15]	罗文彬, 马中良, 郑伦举, 谭静强, 王张虎, 宁传祥. 海相页岩成岩-成烃过程中孔隙结构的演变——来自热模拟实验的启示[J]. 石油学报, 2020, 41(5): 540-552.