单个油包裹体显微荧光特性与热成熟度评价

doi:10.7623/syxb201403023

石油学报 ›› 2014, Vol. 35 ›› Issue (3): 584-590.DOI: 10.7623/syxb201403023

单个油包裹体显微荧光特性与热成熟度评价

陈红汉

中国地质大学构造与油气资源教育部重点实验室湖北武汉 430074

收稿日期:2013-11-02 修回日期:2014-02-12 出版日期:2014-05-25 发布日期:2014-04-11
通讯作者: 陈红汉，男，1962年9月生，1985年毕业于武汉地质学院，1995年获中国地质大学博士学位，现为中国地质大学（武汉）资源学院石油系系主任、教授、博士生导师，主要从事油气成藏过程研究和流体包裹体系统分析。Email：hhchen@cug.edu.cn
作者简介:陈红汉，男，1962年9月生，1985年毕业于武汉地质学院，1995年获中国地质大学博士学位，现为中国地质大学（武汉）资源学院石油系系主任、教授、博士生导师，主要从事油气成藏过程研究和流体包裹体系统分析。Email：hhchen@cug.edu.cn
基金资助:
国家重点基础研究发展计划（973）项目（2012CB214804）和国家重大科技专项（2008ZX05008-003-30）资助。

Microspectrofluorimetric characterization and thermal maturity assessment of individual oil inclusion

Chen Honghan

Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan 430074, China

Received:2013-11-02 Revised:2014-02-12 Online:2014-05-25 Published:2014-04-11

摘要/Abstract

摘要：

油包裹体是捕获于成岩矿物晶体缺陷或愈合裂纹中的“微观油藏”，携带着丰富的油气成藏过程信息。单个油包裹体显微荧光特性分析成为叠合盆地多源多期复杂成藏过程研究强有力的工具之一。运用单个油包裹体显微荧光分析和结构光纳米显微成像技术，讨论了同一期次油包裹体显微荧光特性的影响因素，认为原油在运聚过程中的化学分馏和捕获过程中的捕获分馏会造成同一期次油包裹体荧光特性在一定范围内波动，但热成熟度仍然是影响单个油包裹体显微荧光特性的主要因素。因此，需要考虑选择性极性吸附、包裹体油裂解和泄漏对单个油包裹体显微荧光热成熟度的影响。最佳的办法是运用结构光成像技术识别出受影响的油包裹体并加以剔除，这样单个油包裹体显微荧光特性参数还是可以应用于热成熟度评价的。

关键词: 单个油包裹体, 显微荧光光谱, 成熟度参数, 叠合盆地, 油气成藏期次

Abstract:

The oil inclusions are micro-reservoirs trapped in crystal defects or healed cracks of diagenetic minerals, carrying considerable information of hydrocarbon migration and accumulation. Microspectrofluorimetric analysis of individual oil inclusions thus becomes one of the powerful tools for researching complex processes of hydrocarbon migration and accumulation with multi-sources and multi-stages in superimposed basins. In this study, microspectrofluorimetry and structured illumination microscopy of individual oil inclusions are applied to investigate factors influencing microspectrofluorimetric characteristics of oil inclusion assemblages (OIAs) formed in the same period. Both chemical fractionation during oil migration-accumulation and trapping fractionation during inclusion trapping cause certain fluctuations in the fluorescence emission of OIAs. However, thermal maturity remains the main controlling factor of the microspectrofluorimetric characteristics of OIAs. Therefore, it is essential for thermal maturity assessments of individual oil inclusions to consider the influences of selective polar adsorption, oil cracking within inclusion, and leakage of oil inclusion on the microspectrofluorimetric characteristics of OIAs. The best approach is using structured illumination microscopy analysis to identify the altered oil inclusions and then exclude them from the following analysis. In this way, the microspectrofluorimetric characteristics of the remaining individual oil inclusions are still suitable for thermal maturity assessment.

Key words: individual oil inclusions, microspectrofluorimetry, thermal maturity, superimposed basin, event of hydrocarbon reservoiring

中图分类号:

TE112.3

陈红汉. 单个油包裹体显微荧光特性与热成熟度评价[J]. 石油学报, 2014, 35(3): 584-590.

Chen Honghan. Microspectrofluorimetric characterization and thermal maturity assessment of individual oil inclusion[J]. ACTA PETROLEI SINICA, 2014, 35(3): 584-590.

参考文献

[1] Goldstein R H,Reynolds T J.Systematics of fluid inclusions in diagenetic minerals[M].SEPM Short Course,1994:1-198.
[2] McLimans R K.The application of fluid inclusions to migration of oil and diagenesis in petroleum reservoirs[J].Applied Geochemistry,1987,2(5/6):585-603.
[3] Parnell J,Chen Honghan.Application of fluid inclusion studies to understanding oil charge,Pre-Salt succession,offshore Angola[J].Geological Society of London Special Publications, 2003,207(1):275-283.
[4] Conliffe J,Blamey N F,Feely M,et al.Hydrocarbon migration in the Porcupine Basin,offshore Ireland:evidence from fluid inclusion studies[J].Petroleum Geoscience,2010,16(1):67-76.
[5] Rogers K M,Savard M M.Geochemistry of oil inclusions in sulfide-related calcites-fingerprinting the source of the sulfate-reducing hydrocarbons of the Pb-Zn carbonate-hosted Jubilee deposit of Nova Scotia,Canada[J]. Applied Geochemistry,2002,17(2):69-77.
[6] George S C,Volk H,Dutkiewicz A,et al.Preservation of hydrocarbons and biomarkers in oil trapped inside fluid inclusions for >2 billion years[J]. Geochimica et Cosmochimica Acta,2008,72(3):844-870.
[7] Such? V,Dobes P,S?korová I,et al.Oil-bearing inclusions in vein quartz and calcite and,bitumens in veins:testament to multiple phases of hydrocarbon migration in the Barrandian basin (lower Palaeozoic),Czech Republic[J].Marine and Petroleum Geology,2010,27(1):285-297.
[8] Eadington P J,Lisk M,Krieger F W.Identify oil well sites[J].United States Patent Application,1996,5:543-616.
[9] Alderton D H M,Bevins R E.P-T conditions in the South Wales Coalfield:evidence from coexisting hydrocarbon and aqueous fluid inclusions[J].Journal of the Geological Society,1996,153(2):265-275.
[10] Aplin A C,Macleod G,Larter S R,et al.Combined use of confocal laser scanning microscopy and PVT simulation for estimating the composition and physical properties of petroleum in fluid inclusions[J].Marine and Petroleum Geology,1999,16(2):97-110.
[11] Ping H,Thiéry R,Chen H.Thermodynamic modeling of petroleum inclusions:the prediction of the saturation pressure of crude oils[J].Geofluids,2011,11(3):328-340.
[12] Mark D F,Parnell J,Kelley S P,et al.Dating of multistage fluid flow in sandstones[J].Science,2005,309(5743):2048-2051.
[13] 刘可禹,Bourdet J,张宝收,等.应用流体包裹体研究油气成藏--以塔中奥陶系储集层为例[J].石油勘探与开发,2013,40(2):171-180.
Liu Keyu,Bourdet J,Zhang Baoshou,et al.Hydrocarbon charge history of the Tazhong Ordovician reservoirs,Tarim Basin as revealed from an integrated fluid inclusion study[J].Petroleum Exploration and Development,2013,40(2):171-180.
[14] Riecker R E.Hydrocarbon fluorescence and migration of petroleum[J].AAPG Bulletin,1962,46(1):60-75.
[15] Hagemann H W,Hollerbeach A.The fluorescence behaviour of crude oils with respect to their thermal maturation and degradation[J].Organic Geochemistry,1986,10(1/3):473-480.
[16] Khorasani G K.Novel development in fluorescence microscopy of complex organic mixtures:application in petroleum geochemistry[J].Organic Geochemistry,1987,11(3):157-168.
[17] Burruss R C.Practical aspects of fluorescence microscopy of petroleum fluid inclusions[J].SEPM Short Course,1991,25(1):1-7.
[18] Stasiuk L D,Snowdon L R.Fluorescence micro-spectrometry of synthetic and natural hydrocarbon fluid inclusions:crude oil chemistry,density and application to petroleum migration[J].Applied Geochemistry,1997,12(3):229-241.
[19] Munz I A.Petroleum inclusions in sedimentary basins: systematics,analytical methods and applications[J].Lithos,2001,55(1/4):195-212.
[20] George S C,Ruble T E,Dutkiewicz A,et al.Assessing the maturity of oil trapped in fluid inclusions using molecular geochemistry data and visually-determined fluorescence colours[J].Applied Geochemistry,2001,16(4):451-473.
[21] George S C,Ruble T E,Dutkiewiczc A,et al.Reply to comment by Oxtoby on "Assessing the maturity of oil trapped in fluid inclusions using molecular geochemistry data and visually-determined fluorescence colours"[J].Applied Geochemistry,2002,17(10): 1375-1378.
[22] Oxtoby N H.Comments on:assessing the maturity of oil trapped in fluid inclusions using molecular geochemistry data and visually-determined fluorescence colours[J].Applied Geochemistry,2002,17(10):1371-1374.
[23] Rossi C,Goldstein R H,Marfil R,et al.Diagenetic and oil migration history of the Kimmeridgian Ascla Formation,Maestrat Basin,Spain[J]. Marine and Petroleum Geology,2001,18(3):287-306.
[24] Okubo S.Effects of thermal cracking of hydrocarbons on the homogenization temperature of fluid inclusions from the Niigata oil and gas fields,Japan[J].Applied Geochemistry,2005,20(2):255-260.
[25] 赵艳军,陈红汉.油包裹体荧光颜色及其成熟度关系[J].地球科学——中国地质大学学报,2008,33(1):91-96.
Zhao Yanjun,Chen Honghan.The relationship between fluorescence colors of oil inclusions and their maturities[J].Earth Science:Journal of China University of Geosciences,2008,33(1):91-96.
[26] Bonilla J V,Engel M H.Chemical alteration of crude oils during simulated migration through quartz and clay minerals[J].Organic Geochemistry,1988,13(1/3):503-512.
[27] Brothers L,Engel M H,Kroos B M.The effects of fluid flow through porous media on the distribution of organic compounds in a synthetic crude oils[J].Organic Geochemistry,1991,17(1):11-24.
[28] 张枝焕,邓祖佑,吴水平,等.石油成藏过程中的地球化学变化及控制因素的综合评述[J].高校地质学报,2003,9(3):484-493.
Zhang Zhihuan,Deng Zuyou,Wu Shuiping,et al.Geochemical alteration of hydrocarbon compositions during migration and accumulation and its controlling factors[J].Geological Journal of China Universities,2003,9(3):484-493.
[29] Kuo L.An experimental study of crude oil alteration in reservoir rocks by water washing[J].Organic Geochemistry,1994,21(5):465-479.
[30] Ruiz-Morales Y,Mullins O C.Polycyclic aromatic hydrocarbons of asphaltenes analyzed by molecular orbital calculations with optical spectroscopy[J].Energy & Fuels,2007,21(1):256-265.
[31] Pironon J,Bourdet J.Petroleum and aqueous inclusions from deeply buried reservoirs:experimental simulations and consequences for overpressure estimates[J].Geochimica et Cosmochimica Acta,2008,72(20):4916-4928.
[32] Liu Keyu,Xiao Xianming,Mills D,et al.Cautions in the interpretation of petroleum fluid inclusion data in petroleum system analysis:insight from spectroscopic analyses of natural and synthetic inclusions[J].Journal of Geochemical Exploration, 2009,101(1):62.
[33] Blamey N J F,Ryder A G,Feely M,et al.The application of structured-light illumination microscopy to hydrocarbon-bearing fluid inclusions[J].Geofluids,2008,8(2):102-112.
[34] Bourdet J,Eadington P,Volk H,et al.Chemical changes of fluid inclusion oil trapped during the evolution of an oil reservoir:Jabiru-1A case study (Timor Sea,Australia) [J].Organic Geochemistry,2012,36(1):118-139.
[35] Volk H,Fuentes D,Fuerbach A,et al.First on-line analysis of petroleum from single inclusion using ultrafast laser ablation[J].Organic Geochemistry,2010,41(2):74-77.
[36] Liu Keyu,Eadingtona P,Coghlan D.Fluorescence evidence of polar hydrocarbon interaction on mineral surfaces and implications to alteration of reservoir wettability[J].Journal of Petroleum Science and Engineering,2003,39(3/4):275-285.
[37] Salim A,Sausse J,Pironon J,et al.3D confocal scanning laser microscopy to quantify contact angles in natural Oil-Water mixtures[J].Oil & Gas Science and Technology,2008,63(5):645-655.
[38] 陈勇,葛云锦,周振柱,等.矿物润湿性对储层烃类包裹体形成制约的实验研究[J].地质学报,2011,85(4):569-575.
Chen Yong,Ge Yunjing,Zhou Zhenzhu,et al.Experimental study of the constraint of minerals wettability on hydrocarbon -bearing inclusion forming in reservoir[J].Acta Geologica Sinica,2011,85(4):569-575.
[39] England W,Mackenzie A S,Mann D M,et al.The movement and entrapment of petroleum fluids in the subsurface[J].Journal of the Geological Society,1987,144(2):327-347.
[40] 王铁冠,何发岐,李美俊,等.烷基二苯并噻吩类:示踪油藏充注途径的分子标志物[J].科学通报,2005,50(2):176-182.
Wang Tieguan,He Faqi,Li Meijun et al.Alkyl benzene and thiophene:molecular biomarker tracing the charging paths of hydrocarbon in reservoirsv[J].Chinese Science Bulletin,2005,50(2):176-182.
[41] 余秋华,文志刚,唐友军.塔河油田奥陶系原油芳烃特征及油气运移[J].石油天然气学报, 2010,32(3):161-165.
Yu Qiuhua,Wen Zhigang,Tang Youjun.Aromatic geochemistry characteristics of ordovician oils from northwest of Tahe Oilfield[J].Journal of Oil and Gas Technology,2010,32(3):161-165.
[42] 郑朝阳,柳益群,段毅,等.塔河油田原油芳烃地球化学特征与运移研究[J].西北大学学报:自然科学版,2011,41(4):653-657.
Zheng Chaoyang,Liu Yiqun,Duan Yi,et al.The geochemistry characteristics aromatic compounds and oil and gasmigration of crude oils of the Tahe Oilfield[J].Journal of Northwest University:Natural Science Edition,2011,41(4):653-657.
[43] Chang Y,Huang W.Simulation of the fluorescence evolution of "live" oils from kerogens in a diamond anvil cell:application to inclusion oils in terms of maturity and source[J].Geochimica et Cosmochimica Acta,2008,72(15):3771-3787.

单个油包裹体显微荧光特性与热成熟度评价

Microspectrofluorimetric characterization and thermal maturity assessment of individual oil inclusion

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	付锁堂, 马达德, 陈琰, 张国卿, 伍坤宇. 柴达木盆地油气勘探新进展[J]. 石油学报, 2016, 37(S1): 1-10.
[2]	熊万林陈红汉云　露李慧莉丰　勇吴　悠苏　奥 . 塔中隆起北坡顺托果勒区块志留系储层油气充注历史——以顺9井流体包裹体分析为例[J]. 石油学报, 2013, 34(2): 239-246.
[3]	冯志强孙国昕蒙启安冯子辉. 海拉尔盆地贝中次凹——残留型叠合小断陷盆地油气勘探的成功案例[J]. 石油学报, 2011, 32(4): 551-563.
[4]	何登发李德生童晓光. 中国多旋回叠合盆地立体勘探论[J]. 石油学报, 2010, 31(5): 695-709.
[5]	张厚福徐兆辉王露. 油气藏研究的发展趋势预测[J]. 石油学报, 2010, 31(1): 165-172.
[6]	康德江, 马行陟. 中国西部叠合盆地构造强度定量表征及其应用[J]. 石油学报, 2009, 30(5): 642-647.
[7]	庞雄奇, 高剑波, 吕修祥, 孟庆洋, 王英民, 姜振学, 刘洛夫. 塔里木盆地“多元复合—过程叠加”成藏模式及其应用[J]. 石油学报, 2008, 29(2): 159-166,172.
[8]	王传刚, 胡宗全, 许化政, 周新科. 叠合盆地老烃源岩系油气勘探前景评价方法——以南华北周口坳陷上古生界为例[J]. 石油学报, 2008, 29(1): 10-15,22.
[9]	马立桥, 董庸, 屠小龙, 孙凤霞, 夏九峰, 杨兰英. 中国南方海相油气勘探前景[J]. 石油学报, 2007, 28(3): 1-7.
[10]	刘池洋. 叠合盆地特征及油气赋存条件[J]. 石油学报, 2007, 28(1): 1-7.
[11]	黄龙威. 东濮凹陷西斜坡地区原油成熟度研究[J]. 石油学报, 2006, 27(5): 51-55.
[12]	何登发, 贾承造, 周新源, 石昕, 王招明, 皮学军, 张朝军. 多旋回叠合盆地构造控油原理[J]. 石油学报, 2005, 26(3): 1-9.
[13]	赵文智, 张光亚, 王红军. 石油地质理论新进展及其在拓展勘探领域中的意义[J]. 石油学报, 2005, 26(1): 1-7,12.
[14]	赵文智, 何登发. 中国含油气系统的基本特征与勘探对策[J]. 石油学报, 2002, 23(6): 1-11.
[15]	赵宗举, 朱琰, 王根海, 徐云俊, 冯加良. 叠合盆地油气系统研究方法——以中国南方中、古生界为例[J]. 石油学报, 2002, 23(1): 11-18.