石油学报 ›› 2019, Vol. 40 ›› Issue (2): 207-214.DOI: 10.7623/syxb201902009

• 油田开发 • 上一篇    下一篇

多氢酸酸化反应特征及动力学

高嘉珮1,2, 彭冲3, 牛梦龙4, 郑建刚3, 李亚洲3, 欧阳诗昆3, 李稳宏1,2   

  1. 1. 西北大学化工学院 陕西西安 710069;
    2. 陕西省资源化工应用技术工程研究中心 陕西西安 710069;
    3. 中国石油长庆油田公司第十二采油厂 甘肃合水 745400;
    4. 西安石油大学化学化工学院 陕西西安 710065
  • 收稿日期:2018-01-30 修回日期:2018-10-24 出版日期:2019-02-25 发布日期:2019-03-05
  • 通讯作者: 李稳宏,男,1950年11月生,1976年获西北大学学士学位,现为西北大学化工学院教授、博士生导师,主要从事石油炼制化工领域研究。Email:liwenhong@nwu.edu.cn
  • 作者简介:高嘉珮,女,1994年8月生,2016年获西北大学现代学院学士学位,现为西北大学硕士研究生,主要从事石油开发与油品添加剂研究。Email:2543573218@qq.com

Acidification characteristics and kinetics of multi-hydrogen acid

Gao Jiapei1,2, Peng Chong3, Niu Menglong4, Zheng Jiangang3, Li Yazhou3, Ouyang Shikun3, Li Wenhong1,2   

  1. 1. School of Chemical Engineering, Northwest University, Shaanxi Xi'an 710069, China;
    2. Shaanxi Research Center of Chemical Engineering Technology for Resource Utilization, Shaanxi Xi'an 710069, China;
    3. The Twelfth Oil Extraction Plant of Petrochina Changqing Oilfield Company, Gansu Heshui 745400, China;
    4. College of Chemistry and Chemical Engineering, Xi'an Shiyou University, Shaanxi Xi'an 710065, China
  • Received:2018-01-30 Revised:2018-10-24 Online:2019-02-25 Published:2019-03-05

摘要:

利用自制多氢酸液XS-1进行静态岩粉溶蚀与岩心流动实验,通过SEM、ICP等实验考察了多氢酸的缓速性与预防二次沉淀性能,并研究了多氢酸与岩心反应动力学特性。结果表明,XS-1多氢酸液具有良好的缓速与预防二次沉淀性能,反应后残酸的极限浓度为0.296 1 mol/L,酸液有效作用时间为6~7 h。在该多氢酸体系下岩心渗透率提高至4.15倍,在此条件下以酸岩反应动力学参数模型建立动力学方程,反应速率比同条件下普通酸液小,进一步证明多氢酸具有一定的缓速性。

关键词: 砂岩酸化, 多氢酸, 酸岩反应, 动力学方程, 现场试验

Abstract:

In this study, the self-made multi-hydrogen acid solution XS-1 is used for static rock powder dissolution and core flow experiment. Using SEM and ICP, the retarding property of multi-hydrogen acid and its performance in preventing secondary precipitation are investigated to study the kinetics characteristics of the reaction between multi-hydrogen acid and core. The results show that the multi-hydrogen acid solution XS-1 has a good performance in retardation and secondary precipitation prevention. After reaction, the limit concentration of residual acid is 0.296 1 mol/L and the effective acting time of acid is 6-7 h.The core permeability is increased to 4.15 times in the multi-hydrogen acid system. Under such condition, the kinetics parameter model of acid and rock reaction is applied to establish the kinetic equation; the reaction rate constant is smaller than that of common acid under the same condition, further proving that multi-hydrogen acid has a certain retarding property.

Key words: sandstone acidification, multi-hydrogen acid, acid-rock reaction, kinetic equation, field test

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